Le beach-rock de Temae (île de Moorea - Polynésie française) : signification géomorphologique et processus diagénétiques

Les beach-rocks de Temae (Moorea, Polynésie française) présentent un premier stade de cimentation lié à l'activité cyanobactérienne. Un réseau filamenteux microbien superficiel suffit à bloquer le sédiment et à lancer le processus d'induration. Ces observations viennent confirmer les résultats obtenus récemment dans les Cyclades, montrant par là que les paramètres climatiques et hydrodynamiques sont loin d'être les seuls pour expliquer la naissance d'un beach-roc

A latitude-dependent wind model for Mira's cometary head

We present a 3D numerical simulation of the recently discovered cometary structure produced as Mira travels through the galactic ISM. In our simulation, we consider that Mira ejects a steady, latitude-dependent wind, which interacts with a homogeneous, streaming environment. The axisymmetry of the problem is broken by the lack of alignment between the direction of the relative motion of the environment and the polar axis of the latitude-dependent wind. With this model, we are able to produce a cometary head with a ``double bow shock'' which agrees well with the structure of the head of Mira's comet. We therefore conclude that a time-dependence in the ejected wind is not required for reproducing the observed double bow shock.Comment: 4 pages, 4 figures, accepted for publication in ApJ

Optical Turbulence Measurements and Models for Mount John University Observatory

Site measurements were collected at Mount John University Observatory in 2005 and 2007 using a purpose-built scintillation detection and ranging system. $C_n^2(h)$ profiling indicates a weak layer located at 12 - 14 km above sea level and strong low altitude turbulence extending up to 5 km. During calm weather conditions, an additional layer was detected at 6 - 8 km above sea level. $V(h)$ profiling suggests that tropopause layer velocities are nominally 12 - 30 m/s, and near-ground velocities range between 2 -- 20 m/s, dependent on weather. Little seasonal variation was detected in either $C_n^2(h)$ and $V(h)$ profiles. The average coherence length, $r_0$, was found to be $7 \pm 1$ cm for the full profile at a wavelength of 589 nm. The average isoplanatic angle, $\theta_0$, was $1.0 \pm 0.1$ arcsec. The mean turbulence altitude, $\bar{h_0}$, was found to be $2.0\pm0.7$ km above sea level. No average in the Greenwood frequency, $f_G$, could be established due to the gaps present in the \vw\s profiles obtained. A modified Hufnagel-Valley model was developed to describe the $C_n^2(h)$ profiles at Mount John, which estimates $r_0$ at 6 cm and $\theta_0$ at 0.9 arcsec. A series of $V(h)$ models were developed, based on the Greenwood wind model with an additional peak located at low altitudes. Using the $C_n^2(h)$ model and the suggested $V(h)$ model for moderate ground wind speeds, $f_G$ is estimated at 79 Hz.Comment: 14 pages; accepted for publication in PAS

Pbx(OH)y cluster formation and anomalous thermal behaviour in STI framework-type zeolites

For the first time, the structural investigation of a Pb-exchanged zeolite (Pb13.4(OH)10Al17.4Si54.6O144 ∙38H2O) with STI framework type, revealed a highly unusual and intriguing sudden volume increase under continuous heating. Understanding the fundamental mechanisms leading to such an unusual behaviour is essential for technological applications and interpretation of chemical bonding in zeolites. The dehydration was tracked in situ from 25 to 450 °C by single crystal X-ray diffraction, infrared and X-ray absorption spectroscopy. Further interpretation of the experimental observations was supported by ab initio molecular dynamics simulations. Initially, Pb-STI unit-cell volume contracts (ΔV = -3.5%) from 25 to 100°C. This agrees with the trend observed in STI zeolites. Surprisingly, at 125°C, the framework expanded (ΔV = +2%), adopting a configuration, which resembles that of the room temperature structure. Upon heating, the structure loses H2O but no de-hydroxylation occurred. The key mechanism leading to the sudden volume increase was found to be the formation of Pbx(OH)y clusters, which prevent the shrinking of the channels, rupture of the tetrahedral bonds and occlusion of the pores. This zeolite has therefore an increased thermal stability with respect to other STI metal-exchanged zeolites, with important consequences on its applications

Time series prediction via aggregation : an oracle bound including numerical cost

We address the problem of forecasting a time series meeting the Causal Bernoulli Shift model, using a parametric set of predictors. The aggregation technique provides a predictor with well established and quite satisfying theoretical properties expressed by an oracle inequality for the prediction risk. The numerical computation of the aggregated predictor usually relies on a Markov chain Monte Carlo method whose convergence should be evaluated. In particular, it is crucial to bound the number of simulations needed to achieve a numerical precision of the same order as the prediction risk. In this direction we present a fairly general result which can be seen as an oracle inequality including the numerical cost of the predictor computation. The numerical cost appears by letting the oracle inequality depend on the number of simulations required in the Monte Carlo approximation. Some numerical experiments are then carried out to support our findings