2,374 research outputs found

    OH+^+ emission from cometary knots in planetary nebulae

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    We model the molecular emission from cometary knots in planetary nebulae (PNe) using a combination of photoionization and photodissociation region (PDR) codes, for a range of central star properties and gas densities. Without the inclusion of ionizing extreme ultraviolet (EUV) radiation, our models require central star temperatures T∗T_* to be near the upper limit of the range investigated in order to match observed H2_2 and OH+^+ surface brightnesses consistent with observations - with the addition of EUV flux, our models reproduce observed OH+^+ surface brightnesses for T∗≥100 kKT_* \ge 100 \, {\rm kK}. For T∗<80 kKT_* < 80 \, {\rm kK}, the predicted OH+^+ surface brightness is much lower, consistent with the non-detection of this molecule in PNe with such central star temperatures. Our predicted level of H2_2 emission is somewhat weaker than commonly observed in PNe, which may be resolved by the inclusion of shock heating or fluorescence due to UV photons. Some of our models also predict ArH+^+ and HeH+^+ rotational line emission above detection thresholds, despite neither molecule having been detected in PNe, although the inclusion of photodissociation by EUV photons, which is neglected by our models, would be expected to reduce their detectability.Comment: Accepted by MNRAS, 11 pages, 15 figures. Author accepted manuscript. Accepted on 24/04/18. Deposited on 27/04/1

    Modelling the ArH+^+ emission from the Crab Nebula

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    We have performed combined photoionization and photodissociation region (PDR) modelling of a Crab Nebula filament subjected to the synchrotron radiation from the central pulsar wind nebula, and to a high flux of charged particles; a greatly enhanced cosmic ray ionization rate over the standard interstellar value, ζ0\zeta_0, is required to account for the lack of detected [C I] emission in published Herschel SPIRE FTS observations of the Crab Nebula. The observed line surface brightness ratios of the OH+^+ and ArH+^+ transitions seen in the SPIRE FTS frequency range can only be explained with both a high cosmic ray ionization rate and a reduced ArH+^+ dissociative recombination rate compared to that used by previous authors, although consistent with experimental upper limits. We find that the ArH+^+/OH+^+ line strengths and the observed H2_2 vibration-rotation emission can be reproduced by model filaments with nH=2×104n_{\rm{H}} = 2 \times 10^4 cm−3^{-3}, ζ=107ζ0\zeta = 10^7 \zeta_0 and visual extinctions within the range found for dusty globules in the Crab Nebula, although far-infrared emission from [O I] and [C II] is higher than the observational constraints. Models with nH=1900n_{\rm{H}} = 1900 cm−3^{-3} underpredict the H2_2 surface brightness, but agree with the ArH+^+ and OH+^+ surface brightnesses and predict [O I] and [C II] line ratios consistent with observations. These models predict HeH+^+ rotational emission above detection thresholds, but consideration of the formation timescale suggests that the abundance of this molecule in the Crab Nebula should be lower than the equilibrium values obtained in our analysis.Comment: Accepted by MNRAS. Author accepted manuscript. Accepted on 05/09/2017. Deposited on 05/09/1

    CHMY 221.01: Organic Chemistry I

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    CHMY 420.01: Chemoformatics

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    CHMY 224.00: Organic Chemistry II Laboratory

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    CHMY 465,01: Organic Spectroscopy

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    CHMY 465.01: Organic Spectroscopy

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    CHMY 411.01: Advanced Organic Chemistry

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    CHMY 221.01: Organic Chemistry I

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    CHMY 224.00: Organic Chemistry II Lab

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