7 research outputs found
Thermodynamic analysis of ceramics production in Sassuolo (Italy) from a sustainability viewpoint
'Perceived benefits of littoral wetlands in Uganda: a focus on the Nabugabo wetlands
Wetlands, commonly called swamps in
Uganda, are estimated to cover about 13% of the total
land surface area (about 30,000 km2) of the country
and represent a considerable ecological, social and
economic value. In 1989, the Ugandan government
formerly recognised that wetlands need to be conserved
and contribute considerably to the National
economy and rural livelihood. The present analysis is
focused on the Nabugabo wetland ecosystem.
Located in Central Uganda, it is an important part
of the extensive system of wetlands that surround
Lake Victoria. The Nabugabo wetland is a source of
important resources that are basic to the local
economy, including fishing, water utilization, agriculture,
livestock, wetland plants for construction and
more recently, tourism. Investment in the area is low
and a large percentage of the local community
depends on the wetland resources for basic sustenance
needs. After achieving Ramsar status,
demarcation and conservation activities were initiated
by the local and national leaders. However, these conservation efforts have provoked conflicts between
the land owners and the policy makers, in particular
to the demarcation of areas for conservation In the
present analysis, we examine the benefits, perceived
by local leaders and community members, of the
wetland and its services, as well as views towards its
conservation and management. The results show that
differences between the community leaders and
member exist regarding the perceived benefits of
the wetlands. Tourism, while providing some opportunities
for local persons is not always viewed
positively. Conservation activities are viewed positively
but some questions remain as to whether such
efforts help or hinder the local population, in
particular regarding access to basic resources
Water-protein and ligand-protein interactions as determined by selective NMR relaxation studies
Abstract
Water-macromolecules and ligand-macromolecules interactions were investigated considering the effects induced by the presence of a macromolecule on both the water and the ligand NMR selective (R1SE) and non-selective (R1NS) spin-lattice relaxation rates. The results obtained from the solvent studies were used to describe the solvent dynamics at the macromolecule-solvent interface. On the other hand, ligand R1SE and (R1NS) analysis allowed the definition of the “affinity index”, [A]LT, an index related to the extent of the macromolecule-ligand recognition process
Solution structure of folic acid. Molecular Mechanics and NMR investigation
he structure of folic acid in solution was investigated by nuclear magnetic resonance (NMR) and theoretical calculations. Dynamical
information and geometrical constraints were obtained by carbon-13 relaxation study, homo-nuclear NOESY spectra and hetero-nuclear 1H–13C NOE experiments. This set of experimental data was used for the molecular mechanics and molecular dynamic calculations. The
accuracy of the final structure was established by the RNMR
factor, which was calculated comparing the experimental NOESY cross-peaks
intensities and the corresponding values simulated by using the complete relaxation matrix analysis (CORMA) approac
Spectroscopic investigation of the conformational properties and self-association behaviour of natural compounds in solution
The conformational properties and self-association behaviour of rifaximin and rifaximin OR (Open Ring) were investigated in solution by NMR and IR spectroscopy. The dependence of proton chemical shift on concentration and temperature were analysed to study the self-association process. IR spectra of rifaximin and rifaximin OR were also used at different concentrations to investigate the entity of specific inter- and intra:molecular interactions.
Although similar in structure the two molecules had different chemical properties in solution. This could be of some interest in view of the biological importance of this class of antibiotic molecules
X-ray Tomography Unveils the Construction Technique of Un-Montu’s Egyptian Coffin (Early 26th Dynasty)
The Bologna Archaeological Museum, in cooperation with prestigious Italian universities, institutions, and independent scholars, recently began a vast investigation programme on a group of Egyptian coffins of Theban provenance dating to the first millennium BC, primarily the 25th–26th Dynasty (c. 746–525 BC). Herein, we present the results of the multidisciplinary investigation carried out on one of these coffins before its restoration intervention: the anthropoid wooden coffin of Un-Montu (Inv. MCABo EG1960). The integration of radiocarbon dating, wood species identification, and CT imaging enabled a deep understanding of the coffin’s wooden structure. In particular, we discuss the results of the tomographic investigation performed in situ. The use of a transportable X-ray facility largely reduced the risks associated with the transfer of the large object (1.80 cm tall) out of the museum without compromising image quality. Thanks to the 3D tomographic imaging, the coffin revealed the secrets of its construction technique, from the rational use of wood to the employment of canvas (incamottatura), from the use of dowels to the assembly procedure
Spatial and seasonal changes in optical properties of autochthonous and allochthonous chromophoric dissolved organic matter in a stratified mountain lake
In this study, we present results on seasonal and spatial changes in CDOM absorption and fluorescence
(fCDOM) in a deep mountain lake (Salto Lake, Italy). A novel approach was used to describe the shape
of CDOM absorption between 250–700 nm (distribution of the spectral slope, S(l)) and a new
fluorescence ratio is used to distinguish between humic and amino acid-like components. Solar
ultraviolet irradiance, dissolved organic carbon (DOC), DOM fluorescence and absorption
measurements were analysed and compared to other physicochemical parameters. We show that in the
UV-exposed mixed layer: (i) fluorescence by autochthonous amino acid-like CDOM, (ii) values of S(l)
across UV-C and UV-B wavebands increased during the summer months, whereas (i) average molar
absorption coefficient and (ii) fluorescence by allochthonous humic CDOM decreased. In the
unexposed deep layer of the water column (and in the entire water column in winter), humic-like
CDOM presented high values of molar absorption coefficients and low values of S(l). UV attenuation
coefficients correlated with both chlorophyll a concentrations and CDOM absorption. In agreement
with changes in CDOM, minimal values in UV attenuation were found in summer. The S(l) curve was
used as a signature of the mixture between photobleached and algal-derived CDOM with respect to the
unexposed chromophoric dissolved compounds in this thermal stratified lake. Furthermore, S(l) curves
were useful to distinguish between low and high molecular weight CDOM