Palladium, platinum, and gold distribution in serpentinite seamounts in the Mariana and Izu-Bonin forearcs: evidence from Leg 125 fluids and serpentinites

Palladium, platinum, and gold were analyzed for 20 interstitial water samples from Leg 125. No Pd or Pt was detected in fluids from serpentinite muds from Conical Seamount in the Mariana forearc, indicating that low-temperature seawater-peridotite interaction does not mobilize these elements into the serpentinizing fluids to levels above 0.10 parts per billion (ppb) in solution. However, Au may be mobilized in high pH solutions. In contrast, fluids from vitric-rich clays on the flanks of the Torishima Seamount in the Izu-Bonin forearc have Pd values of between 4.0 and 11.8 nmol/L, Pt values between 2.3 and 5.0 nmol/L and Au values between 126.9 and 1116.9 pmol/L. The precious metals are mobilized, and possibly adsorbed onto clay mineral surfaces, during diagenesis and burial of the volcanic-rich clays. Desorption during squeezing of the sediments may produce the enhanced precious metal concentrations in the analyzed fluids. The metals are mobilized in the fluids probably as neutral hydroxide, bisulfide, and ammonia complexes. Pt/Pd ratios are between 0.42 and 2.33, which is much lower than many of the potential sources for Pt and Pd but is consistent with the greater solubility of Pd compared with Pt in most natural low-temperature fluids

Palladium, platinum, and gold distribution in serpentinite seamounts in the Mariana and Izu-Bonin forearcs: evidence from Leg 125 fluids and serpentinites

Palladium, platinum, and gold were analyzed for 20 interstitial water samples from Leg 125. No Pd or Pt was detected in fluids from serpentinite muds from Conical Seamount in the Mariana forearc, indicating that low-temperature seawater-peridotite interaction does not mobilize these elements into the serpentinizing fluids to levels above 0.10 parts per billion (ppb) in solution. However, Au may be mobilized in high pH solutions. In contrast, fluids from vitric-rich clays on the flanks of the Torishima Seamount in the Izu-Bonin forearc have Pd values of between 4.0 and 11.8 nmol/L, Pt values between 2.3 and 5.0 nmol/L and Au values between 126.9 and 1116.9 pmol/L. The precious metals are mobilized, and possibly adsorbed onto clay mineral surfaces, during diagenesis and burial of the volcanic-rich clays. Desorption during squeezing of the sediments may produce the enhanced precious metal concentrations in the analyzed fluids. The metals are mobilized in the fluids probably as neutral hydroxide, bisulfide, and ammonia complexes. Pt/Pd ratios are between 0.42 and 2.33, which is much lower than many of the potential sources for Pt and Pd but is consistent with the greater solubility of Pd compared with Pt in most natural low-temperature fluids

Searching for Very High Energy Emission from Pulsars Using the High Altitude Water Cherenkov (HAWC) Observatory

There are currently over 160 known gamma-ray pulsars. While most of them are detected only from space, at least two are now seen also from the ground. MAGIC and VERITAS have measured the gamma ray pulsed emission of the Crab pulsar up to hundreds of GeV and more recently MAGIC has reported emission at $\sim2$ TeV. Furthermore, in the Southern Hemisphere, H.E.S.S. has detected the Vela pulsar above 30 GeV. In addition, non-pulsed TeV emission coincident with pulsars has been detected by many groups, including the Milagro Collaboration. These GeV-TeV observations open the possibility of searching for very-high-energy (VHE, > 100GeV) pulsations from gamma-rays pulsars in the HAWC field of view.Comment: Presented at the 34th International Cosmic Ray Conference (ICRC2015), The Hague, The Netherlands. See arXiv:1508.03327 for all HAWC contribution

Diisopropylamide and TMP turbo-grignard reagents : a structural rationale for their contrasting reactivities

A neutral dimeric molecule in crystal form, the diisopropylamido turbo-Grignard reagent "(iPr2N)MgCl⋅LiCl" (see structure; blue N, red O, green Mg, yellow Cl, black C) separates into several charged ate species in dynamic exchange with each other in THF solution as determined by a combination of EXSY and DOSY NMR studies

Magnetocaloric effect in integrable spin-s chains

We study the magnetocaloric effect for the integrable antiferromagnetic high-spin chain. We present an exact computation of the Gr\"uneisen parameter, which is closely related to the magnetocaloric effect, for the quantum spin-s chain on the thermodynamical limit by means of Bethe ansatz techniques and the quantum transfer matrix approach. We have also calculated the entropy S and the isentropes in the (H,T) plane. We have been able to identify the quantum critical points H_c^{(s)}=2/(s+1/2) looking at the isentropes and/or the characteristic behaviour of the Gr\"uneisen parameter.Comment: 6 pages, 3 figure

The Bristol Hearth Tax 1662-1673

This is the proof version. The final version is available from Bristol Record Society via the link in this record Archived with permission of the Bristol Record SocietyBristol Record Society's publications vol. 7

Quantum spin chains of Temperley-Lieb type: periodic boundary conditions, spectral multiplicities and finite temperature

We determine the spectra of a class of quantum spin chains of Temperley-Lieb type by utilizing the concept of Temperley-Lieb equivalence with the S=1/2 XXZ chain as a reference system. We consider open boundary conditions and in particular periodic boundary conditions. For both types of boundaries the identification with XXZ spectra is performed within isomorphic representations of the underlying Temperley-Lieb algebra. For open boundaries the spectra of these models differ from the spectrum of the associated XXZ chain only in the multiplicities of the eigenvalues. The periodic case is rather different. Here we show how the spectrum is obtained sector-wise from the spectra of globally twisted XXZ chains. As a spin-off, we obtain a compact formula for the degeneracy of the momentum operator eigenvalues. Our representation theoretical results allow for the study of the thermodynamics by establishing a TL-equivalence at finite temperature and finite field.Comment: 29 pages, LaTeX, two references added, redundant figures remove

Conditional Mass Functions and Merger Rates of Dark Matter Halos in the Ellipsoidal Collapse Model

Analytic models based on spherical and ellipsoidal gravitational collapse have been used to derive the mass functions of dark matter halos and their progenitors (the conditional mass function). The ellipsoidal model generally provides a better match to simulation results, but there has been no simple analytic expression in this model for the conditional mass function that is accurate for small time steps, a limit that is important for generating halo merger trees and computing halo merger rates. We remedy the situation by deriving accurate analytic formulae for the first-crossing distribution, the conditional mass function, and the halo merger rate in the ellipsoidal collapse model in the limit of small look-back times. We show that our formulae provide a closer match to the Millennium simulation results than those in the spherical collapse model and the ellipsoidal model of Sheth & Tormen (2002).Comment: 5 pages, 3 figures, accepted by MNRAS letter

Detection of oxygen and carbon in the hydrodynamically escaping atmosphere of the extrasolar planet HD209458b

Four transits of the planet orbiting the star HD209458 were observed with the STIS spectrograph on board HST. The wavelength domain (1180-1710A) includes HI as well as CI, CII, CIV, NV, OI, SI, SiII, SiIII and SiIV lines. During the transits, absorptions are detected in HI, OI and CII (5+/-2%, 13+/-4.5% and 7.5+/-3.5%, respectively). No absorptions are detected for other lines. The 5% mean absorption over the whole HI Lyman alpha line is consistent with the previous detection at higher resolution (Vidal-Madjar et al. 2003). The absorption depths in OI and CII show that oxygen and carbon are present in the extended upper atmosphere of HD209458b. These species must be carried out up to the Roche lobe and beyond, most likely in a state of hydrodynamic escape.Comment: 6 pages, 4 figures, 1 table, submitted to ApJ Letters, revised version with slightly revisited absorption depth estimate

Detection of functional PTEN lipid phosphatase protein and enzyme activity in squamous cell carcinomas of the head andeck, despite loss of heterozygosity at this locus

The human tumour suppressor gene PTEN located at 10q23 is mutated in a variety of tumour types particularly metastatic cases and in the germline of some individuals with Cowdens cancer predisposition syndrome. We have assessed the status of PTEN and associated pathways in cell lines derived from 19 squamous cell carcinomas of the head and neck. Loss of heterozygosity is evident at, or close to the PTEN gene in 5 cases, however there were no mutations in the remaining alleles. Furthermore by Western analysis PTEN protein levels are normal in all of these SCC-HN tumours and cell lines. To assess the possibility that PTEN may be inactivated by another mechanism, we characterized lipid phosphatase levels and from a specific PIP3 biochemical assay it is clear that PTEN is functionally active in all 19 human SCCs. Our data strongly suggest the possibility that a tumour suppressor gene associated with development of SCC-HN, other than PTEN, is located in this chromosomal region. This gene does not appear to be MXI-1, which has been implicated in some other human tumour types. PTEN is an important negative regulator of PI3Kinase, of which subunit alpha is frequently amplified in SCC-HN. To examine the possibility that PI3K is upregulated by amplification in this tumour set we assessed the phosphorylation status of Akt, a downstream target of PI3K. In all cases there is no detectable increase in Akt phosphorylation. Therefore there is no detectable defect in the PI3K pathway in SCC-HN suggesting that the reason for 3q26.3 over-representation may be due to genes other than PI3K110α. © 2001 Cancer Research Campaign http://www.bjcancer.co