Excimer emission in Indium Vapour

An excimer band extending between 271 and 284 nm in indium vapor is reported which is the result of a two-photon resonant ionization of indium vapor excited by a dye laser tuned to the 6 2S1/2-5 2P1/2 atomic transition. The observations were made both in quartz cells and in a heat pipe oven at temperatures between 943 and 1223 K in the presence of He, Ne and Ar buffer gases. The excimer state giving rise to the emission occurs at an energy which can be correlated with the In(7 2S1/2) and In(5 2P1/2) separated atom states. No structure other than a degradation to the blue is apparent in the spectrum

Energy pooling collision cross-section measurements in Indium: the In(6S1/2) + In(6S1/2) In(n P) + In(5P3/2) process

The quantitative investigation of the energy pooling collision (EPC) process between resonantly laser excited In atoms is reported. The process is studied in a laser induced fluorescence (LIF) experiment where the nP populations, with n=11, 10 and 9, are monitored. The population mechanism for these levels is verified via a temporal analysis of the fluorescence signals. This is possible in In due to the strongly reduced self trapping of the resonant radiation. The cross section for energy pooling collision to these nP levels has been derived by considering the Rydberg character of these levels

Light-induced diffusion and desorption of alkali metals in a siloxane film: theory and experiment

The light-induced desorption and diffusion of alkali-metal atoms in organic films are interesting fields of investigation. An impressive demonstration is given by the recently observed light-induced atomic desorption ~LIAD! effect, where a huge alkali-metal atom desorption from siloxane films, previously exposed to atomic vapors, is induced by weak and nonresonant light. In this paper, experimental data and a one-dimensional theoretical model of the effect are presented. The model gives a good description of the vapor density dynamics by taking into account both the atomic diffusion inside the coating and the surface desorption. General equations are reported and discussed within the limits of experimental interest. The potential barrier at the vapor-surface interface and the activation energy for Rb in (poly)dimethylsiloxane have been determined