70,181 research outputs found
Wave packet transmission of Bloch electron manipulated by magnetic field
We study the phenomenon of wave packet revivals of Bloch electrons and
explore how to control them by a magnetic field for quantum information
transfer. It is showed that the single electron system can be modulated into a
linear dispersion regime by the "quantized" flux and then an electronic wave
packet with the components localized in this regime can be transferred without
spreading. This feature can be utilized to perform the high-fidelity transfer
of quantum information encoded in the polarization of the spin. Beyond the
linear approximation, the re-localization and self-interference occur as the
novel phenomena of quantum coherence.Comment: 6 pages, 5 figures, new content adde
Quantum state swapping via qubit network with Hubbard interaction
We study the quantum state transfer (QST) in a class of qubit network with
on-site interaction, which is described by the generalized Hubbard model with
engineered couplings. It is proved that the system of two electrons with
opposite spins in this quantum network of sites can be rigorously reduced
into one dimensional engineered single Bloch electron models with central
potential barrier. With this observation we find that such system can perform a
perfect QST, the quantum swapping between two distant electrons with opposite
spins. Numerical results show such QST and the resonant-tunnelling for the
optimal on-site interaction strengths.Comment: 4 pages, 3 figure
THEORETICAL STUDIES OF BILIPROTEIN CHROMOPHORES AND RELATED BILE PIGMENTS BY MOLECULAR ORBITAL AND RAMACHANDRAN TYPE CALCULATIONS
Ramachandran calculations have been used to gain insight into steric hindrance in bile
pigments related to biliprotein chromophores. The high optical activity of denatured phycocyanin, as
compared to phycoerythrin, has been related to the asymmetric substitution at ring A, which shifts the
equilibrium towards the P-helical form of the chromophore. Geometric effects on the electronic structures
and transitions have then been studied by molecular orbital calculations for several conjugation
systems including the chromophores of phycocyanin. phytochrome P,, cations, cation radicals and
tautomeric forms. For these different chromophores some general trends can be deduced. For instance,
for a given change in the gross shape (e.g. either unfolding of the molecule from a cyclic-helical to a fully
extended geometry, or upon out-of-plane twists of the pyrrole ring A) of the molecules under study, the
predicted absorption spectra all change in a simikar way. Nonetheless, there are characteristic distinctions
between the different n-systems, both in the transition energies and the charge distribution, which
can be related to their known differences in spectroscopic properties and their reactivity
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