Monitoring Corrosion Products on Metal Artefacts by Linear Sweep Voltammetry (LSV)

Metallic surfaces are highly sensitive to their surroundings, and prone to react with airborne pollutants to form complex layers. Electrochemical techniques have the possibility of simultaneously identifying different electroactive compounds [1]. The high sensitivity of Linear Sweep Voltammetry (LSV) allows the detection of extremely thin surface films before they became visible. LSV leads to reduction peaks, which can identify the compounds within the “tarnishing” layer and also its relative abundance [1, 2]. The potentialities of this and others electrochemical techniques has been well demonstrated in several recent works and they seem to be promising and non-invasive tools, even for in situ investigations on the metallic artifacts from cultural heritage. This communication presents data showing the application of the technique to silver and sterling silver coupons exposed, during periods of 1 and 12 months, in the Treasure Room in the Museum (inside showcases) and near the Holy Altar of the Chapel, of Porto Cathedral (Portugal). The influence of various conditions: the atmosphere (Museum and Chapel), exposure time (1 and 12 months) and season (spring, summer, autumn and winter) have been analysed. The LSV spectra of blank polished samples as well as samples covered with thin films of silver sulphide and of silver chloride, formed under controlled conditions, respectively: (i) H2S, 1000 ppm, RH= 53% ± 2, T= 21 ºC ± 1, over periods of 24, 48 and 72 h) and (ii) 3.5% of NaCl, RH=41% periods of 5 h, have been used as references. Concerning the nature of the products developed on the surface during the exposure, data has revealed that the tarnishing layers have a complex nature and are not composed only by silver sulphide. It happens even that silver sulphide is a relative minor component in the tarnish layer. Peaks corresponding to silver chloride and silver oxides were well visible. Small peaks assigned to silver sulphide were identified on the samples exposed in the Chapel. For the 12 months exposures both peaks have increased in size with the peak assigned to chloride being much higher in the case of the Chapel. The seasonal influence, even for the 1 month exposures, was particularly notable on those samples with exposures started in winter with well visible effects on the chloride peak on the tarnish layer of the samples exposed in the Chapel. Obviously, that to obtain analytical information electrochemical techniques can be complemented with spectroscopic techniques, namely, X- ray photon spectroscopy (XPS), laser induced breakdown spectroscopy (LIBS), x-rays fluorescence spectroscopy, among others. [1] A. Doménech-Carbó, M.T. Doménech-Carbó, V. Costa (2009), Electrochemical Methods in Archaeometry, Conservation and Restoration, Berlin: F. Scholz. [2] V. Costa, M. Dubus (2007), Impact of the environmental conditions on the conservation of metal artifacts: an evaluation using electrochemical techniques, in National Museum of Denmark, Museum Microclimates, Copenhagen: T. Padfield and K. Borchersen, 63-65

The Apparently Normal Galaxy Hosts for Two Luminous Quasars

HST images (with WFPC2) of PHL~909\ ($z = 0.171$) and PG~0052$+$251\ ($z = 0.155$) show that these luminous radio-quiet quasars each occur in an apparently normal host galaxy. The host galaxy of PHL~909 is an elliptical galaxy ($\sim$ E4) and the host of PG~0052$+$251 is a spiral ($\sim$~Sb). Both host galaxies are several tenths of a magnitude brighter than $L^*$, the characteristic Schechter luminosity of field galaxies. The images of PHL~909 and PG~0052$+$251, when compared with HST images of other objects in our sample of 20 luminous, small-redshift ($z \leq 0.30$) quasars, show that luminous quasars occur in a variety of environments. The local environments of the luminous quasars range from luminous ellipticals, to apparently normal host galaxies, to complex systems of interacting components, to faint (and as yet undetected) hosts. The bright HII regions of the host galaxy of PG~0052$+$251 provide an opportunity to measure directly the metallicity of the host of a luminous quasar, to establish an upper limit to the mass of the nuclear AGN (i.e., the putative black hole source), and to test stringently the cosmological hypothesisthat the galaxy and the quasar are both at the distance indicated by the quasar redshift.Comment: 32 pages, LaTeX file. Seven postscript figures available from anonymous ftp to ftp://eku.sns.ias.edu/pub/sofia/ as phlpgfg1.ps, phlpgfg2.ps, phlpgfg3.ps, phlpgfg4.ps, phlpgfg5.ps, phlpgfg6a.ps, phlpgfg6b.ps, phlpgfg7.ps. To appear in ApJ, February 1, 199

Application of the Covariant Spectator Theory to the study of heavy and heavy-light mesons

As an application of the Covariant Spectator Theory (CST) we calculate the spectrum of heavy-light and heavy-heavy mesons using covariant versions of a linear confining potential, a one- gluon exchange, and a constant interaction. The CST equations possess the correct one-body limit and are therefore well-suited to describe mesons in which one quark is much heavier than the other. We find a good fit to the mass spectrum of heavy-light and heavy-heavy mesons with just three parameters (apart from the quark masses). Remarkably, the fit parameters are nearly unchanged when we fit to experimental pseudoscalar states only or to the whole spectrum. Because pseudoscalar states are insensitive to spin-orbit interactions and do not determine spin-spin interactions separately from central interactions, this result suggests that it is the covariance of the kernel that correctly predicts the spin-dependent quark-antiquark interaction