Phytochemical constituents of Cadaba Trifoliata Roxb. root extract

Cadaba trifoliata Roxb is belongs to the family Capparaceae, important medicinal plant of Indian medicinal plants. The methanol, ethanol, ethyl acetate and aqueous extracts along with dry powder of root were screened for the presence of phytochemicals. The phytochemical constituents were analyzed by qualitative and GC-MS method. Preliminary studies showed that the presence of Tannins, Steroids, Alkaloids, Glycosides, Flavonoids and Phenolic compounds. In the GC-MS analysis, 17 bioactive phytochemical compounds were identified in the alcoholic extract. The identification of phytochemical compounds in very high peak area, 1, 2-Benzenedicarboxylic acid, diisooctyl ester (C24H38O4) with RT 24.95 has peak area 51.86% and 1-Methyl-pyrrolidine-2-carboxylic acid (C6H11NO2) with RT 6.89 has peak area 20.58%. The main important compound phytol (C20H40O) with RT 18.95 ranks with peak area 1.21%. A nature compound contains diterpene activity anti-cancer, anti-diabetic, anti-inflammatory, anti-oxidant activity and antimicrobial activity.Keywords:- Cadaba trifoliata, phytochemical constituents, alcoholic root extracts

Projector Light Control And Fuzzy Based Control For EDOC In Electric Vehicle For Two Wheelers

Projector light control mainly focus on the battery management in an e-vehicle. This provides a long time journey without any unnecessary wastage of the battery. This may be used in all sort of e-vehicle. The system can replace the hardware components of the Electric vehicles in Two wheelers and does not need extra equipment. The size and volume EDOC is reducedTo control electric drive onboard converter (EDOC) using Fuzzy in the DC (battery) side. To automate the projector light in an E-vehicle for two wheeler to reduce the battery consumptio

Effect of Helical Winding Angle on External Pressure based Buckling of Partially Filled Thin Composite Cylindrical Shells

Effect of helical winding angle on buckling load of thin composite tubes is investigated in this work.  Experiments are conducted on both empty and partially filled S2 glass tubes to estimate contribution of strength to the tubes by the filler material.  Chosen filler material mechanically simulates behavior of typical solid propellant used in aerospace application.   FE analysis with non-linear effect correlates well with the experimental data.  Three series of experiments are conducted to quantify effect of helical winding angle and increase in volumetric loading fraction(VLF).  Results confirm appreciable improvement in strength of filled tubes for higher VLF.  For the chosen pattern of winding, lower winding angle provides more strength to the tubes against external pressure buckling.  &nbsp

2-Amino­pyridinium picrate

In the title compound, C5H7N2 +·C6H2N3O7 −, there are two crystallographically independent cations and anions (A and B) in the asymmetric unit. In both picrate anions, one of the nitro groups lies in the plane of the benzene ring [r.m.s. deviations = 0.014 (2) and 0.014 (2) Å for anions A and B, respectively] and the other two are twisted away by 39.0 (2) and 18.8 (2)° in A, and 18.2 (1) and 2.5 (2)° in B. In the crystal, the cations and anions are linked by inter­molecular N—H⋯O and C—H⋯O hydrogen bonds, forming a two-dimensional network

2-(1,2,3,4-Tetra­hydro-9H-carbazol-1-yl­idene)propane­dinitrile

In the title compound, C15H11N3, the cyclo­hexene ring adopts a sofa conformation. An intra­molecular N—H⋯N hydrogen bond generates an S(7) ring motif. In the crystal, mol­ecules are linked by inter­molecular N—H⋯N, C—H⋯N and C—H⋯π inter­actions into a three-dimensional network

6-Bromo-2-(3-phenyl­allyl­idene)-2,3,4,9-tetra­hydro-1H-carbazol-1-one

Mol­ecules of the title compound, C21H16BrNO, are linked through pairs of N—H⋯O inter­molecular hydrogen bonds into centrosymmetric R 2 2(10) dimers. One of the C atoms of the cyclohex-2-enone ring is disordered with refined occupancies of 0.61 (2) and 0.39 (2)

2-(6-Chloro-2,3,4,9-tetra­hydro-1H-carbazol-1-yl­idene)propane­dinitrile

The mol­ecular conformation of the title compound, C15H10ClN3, is stabilized by an intra­molecular N—H⋯N hydrogen bond with an S(7) ring motif. The crystal packing is controlled by N—H⋯N and C—H⋯N inter­molecular inter­actions. One of the methyl­ene groups of the cyclo­hexene ring is disordered over two positions with refined occupancies of 0.457 (12) and 0.543 (12)

Geometries, Electronic Structures and Electronic Absorption Spectra of Silicon Dichloride Substituted Phthalocyanine for Dye Sensitized Solar Cells

The geometries, electronic structures, polarizabilities, and hyperpolarizabilities of Silicon dichloride substituted phthalocyanine dye sensitizer were studied based on Density Functional Theory (DFT) using the hybrid functional B3LYP. Ultraviolet-Visible (UV-Vis) spectrum was investigated by using a hybrid method which combines the single-excitation configuration interactions (CIS) with DFT, i.e. CIS-DFT(B3LYP). Features of the electronic absorption spectrum in the visible and near-UV regions were assigned based on CIS-DFT calculations. The absorption bands are assigned to n→π* transitions. Calculated results suggest that the three lowest energy excited states of Silicon dichloride substituted phthalocyanine are due to photoinduced electron transfer processes. The interfacial electron transfer between semiconductor TiO2 electrode and dye sensitizer is due to an electron injection process from excited dye to the semiconductor’s conduction band. The role of Silicon dichloride in phthalocyanine geometries, electronic structures and electronic absorption spectra were analysed and these results were concluded that Silicon dichloride substituted phthalocyanine used in Dye Sensitized Solar Cells (DSSC) give a good conversion efficiency

Studies on Correlation and Path Analysis in Mutants of Coleus (Coleus forskohlii Briq.) for Yield and forskolin Content in V2M1 Generation

The present investigation was carried out during 2003-2007 involving terminal cuttings of coleus ecotype 'Garmai'. Genotypic correlation coefficient between yield and its components in mutants of coleus was studied, viz., plant height, number of branches plant-1, number of leaves plant-1, number of tubers plant-1, tuber length and tuber girth were found to have positive and highly significant correlation with yield. However, forskolin and essential oil content showed negative correlation with yield. Path analysis of component characters on yield of Coleus in V2M1 generation exerted positive direct effect through the characters plant height, number of leaves plant-1 and number of tubers plant-1. Similarly, direct effect was observed to be negative through number of branches plant-1 (-0.930), total amount of alkaloids (-0.066) and forskolin content (-0.026). The current investigation resulted in residual effect of 0.158 indicating the accuracy and appropriate selection of component character for crop improvement programme. Weightage must be given to component characters exhibiting positive attributes towards fresh tuber yield in Coleus. However, some traits with negative attributes are also chosen for getting improved quality, i.e., forskolin content, without much inhibition on fresh tuber yield plant-1

Molybdenum status and critical limit in the soil for green gram (Vigna radiata) growing in Madurai and Sivagangai districts of Tamil Nadu, India

A survey was undertaken during 2008 to determine molybdenum (Mo) status of soils and to establish critical limits in soils of Madurai and Sivagangai districts of Tamil Nadu. A total of 202 surface soil samples were collected from 16 soil series of the study areas based on their percent coverage. The samples were analyzed for extractable or available Mo. Extractable Mo varied from 0.028 to 0.661 mg kg−1 and 0.035 to 0.961 mg kg−1 at Madurai and Sivagangai districts, respectively. Based on the results of a pot culture experiment, the critical limit of available Mo was determined to be 0.043 mg kg−1 for green gram [Vigna radiata (L.) Wilczek] (Var; CO 6) in both the districts. Based on this critical limit, we classified the soils into three categories: (1) low: 0.082 mg kg−1. Green gram responded highly to Mo application in soils below the critical limit whereas soils with Mo greater than 0.082 mg kg−1 did not respond. Among rates of Mo application, 0.075 mg kg−1 showed better yield than others. Overall, 3–41% and 7–46% of total area in Madurai and Sivagangai districts were in the low to medium Mo status, respectively. The application of 0.075 mg of Mo kg−1 or 0.4 kg ha−1 as sodium molybdate was sufficient to optimize green gram yield in the major soil series of the districts. These results will be useful in decision-making to apply Mo for improving green gram yields in the two districts studied