12 research outputs found
Anomalously large oxygen-ordering contribution to the thermal expansion of untwinned YBa2Cu3O6.95 single crystals: a glass-like transition near room temperature
We present high-resolution capacitance dilatometry studies from 5 - 500 K of
untwinned YBa2Cu3Ox (Y123) single crystals for x ~ 6.95 and x = 7.0. Large
contributions to the thermal expansivities due to O-ordering are found for x ~
6.95, which disappear below a kinetic glass-like transition near room
temperature. The kinetics at this glass transition is governed by an energy
barrier of 0.98 +- 0.07 eV, in very good agreement with other O-ordering
studies. Using thermodynamic arguments, we show that O-ordering in the Y123
system is particularly sensitive to uniaxial pressure (stress) along the chain
axis and that the lack of well-ordered chains in Nd123 and La123 is most likely
a consequence of a chemical-pressure effect.Comment: 4 pages, 3 figures, submitted to PR