Comparative life cycle assessment of cellulose nanofibres production routes from virgin and recycled raw materials

Nanocellulose-based materials are attracting an increasing interest for the positive role they could play in sustainable development; being originated from renewable resources. Moreover, cellulose has a high potential of recycling from both post-consumer waste and industrial waste. Both factors, i.e., recyclability and renewable resources; results are also extremely favourable in the perspective of circular economy. Despite all these positive aspects, an industrial production has yet to start. At the lab scale, many preparation methods of cellulose nanofibres (CNF) are available; here, the three most common are analysed: (1) enzymatic pre-treatment followed by homogenisation (ENZHO), (2) oxidative pre-treatment combined with homogenisation (TOHO) or (3) oxidative pre-treatment followed by sonication (TOSO). All three processes have been experimentally carried out starting from both virgin and recycled cellulose from industrial waste sludge. The environmental sustainability of these three routes is estimated by the Life Cycle Assessment (LCA) using experimental lab scale data. In this scenario, the comparative LCA has pointed out a superior performance of the ENZHO process, followed by TOHO and, lastly, by TOSO. The influence of energy consumption on the final results has been further investigated by a sensitivity analysis, showing that the TOHO and TOSO routes could reach similar performances by scaling-up the process from the laboratory. The different typology of CNF obtained by conducting the ENZHO process with respect to the TEMPO-mediated oxidation approach is also outlined as an additional element to be considered for the final selection of a suitable process

Design Approach for the Development of the Flow Field of Bipolar Plates for a PEMFC Stack Prototype

This work is part of a project whose final aim is the realization of an auxiliary power fuel cell generator. It was necessary to design and develop bipolar plates that would be suitable for this application. Bipolar plates have a relevant influence on the final performances of the entire device. A gas leakage or a bad management of the water produced during the reaction could be determinant during operations and would cause the failure of the stack. The development of the bipolar plates was performed in different steps. First, the necessity to make an esteem of the dynamics that happen inside the feeding channels led to perform analytical calculations. The values found were cross-checked performing a computational fluid dynamics (CFD) simulation; finally, it was defined the best pattern for the feeding channels, so that to enhance mass transport and achieve the best velocity profile. The bipolar plates designed were machined and assembled in a laboratory scale two cells prototype stack. Influences of the temperature and of the humidity were evaluated performing experiments at 60 deg and 70 deg and between 60% and 100% of humidity of the reactant gasses. The best operating point achieved in one of these conditions was improved by modifying the flow rates of the reactant, in order to obtain the highest output power, and it evaluated the reliability of the plates in experiments performed for longer times, at fixed voltages