Direct Measurement of Vanadium Crossover in an Operating Vanadium Redox Flow Battery

Measurements of Vanadium diffusion coefficients for transport across cation exchange membranes using dialysis cells have been reported in the literature. However, to date direct measurement of crossover coefficients in an operating Vanadium redox flow battery (VRB) cell have not been reported. Results are reported in this paper on experiments utilizing a special VRB cell which allows measurement of Vanadium ion transport across ion exchange membranes with and without the presence of current. The cell utilizes two additional flow regions which collect Vanadium ions which diffuse from the positive and negative half cells. The effects of the magnitude and direction of electrical current on transport can be measured directly with this cell. We observe that transport is greatly enhanced when the direction of the hydrogen ion flux is in the same direction as the density gradient driven vanadium flux and suppressed when the hydrogen ion flux is in the opposite direction. The cell has been used to of investigate the effects on transport of current densities up to 900 mA/cm(2).US Department of Energy ARPA-E program DE-AR00000149Materials Science and Engineerin

A Dual Dutch Auction in Taipei: The Choice of Numeraire and Auction Form in Multi-Object Auctions with Bundling. .

In Taipei we observed a dual Dutch fish auction, like a conventional Dutch auction with bundling, but with reversed roles of price and quantity. We study dual and conventional auctions with symmetric, independent private values, when agents’ utilities are linear in money but strictly concave in fish. With known buyers’ values, conventional and dual auctions, English or Dutch, are equivalent. With values known to buyers but not the seller, the seller prefers conventional auctions. With private values, the seller can prefer a dual Dutch or a conventional English or Dutch auction, but prefers all three to a dual English auction.

The prevalence of dust on the exoplanet HD 189733b from Hubble and Spitzer observations

The hot Jupiter HD189733b is the most extensively observed exoplanet. Its atmosphere has been detected and characterised in transmission and eclipse spectroscopy, and its phase curve measured at several wavelengths. This paper brings together results of our campaign to obtain the complete transmission spectrum of the atmosphere of this planet from UV to IR with HST, using STIS, ACS and WFC3. We provide a new tabulation of the transmission spectrum across the entire visible and IR range. The radius ratio in each wavelength band was rederived to ensure a consistent treatment of the bulk transit parameters and stellar limb-darkening. Special care was taken to correct for, and derive realistic estimates of the uncertainties due to, both occulted and unocculted star spots. The combined spectrum is very different from the predictions of cloud-free models: it is dominated by Rayleigh scattering over the whole visible and near infrared range, the only detected features being narrow Na and K lines. We interpret this as the signature of a haze of condensate grains extending over at least 5 scale heights. We show that a dust-dominated atmosphere could also explain several puzzling features of the emission spectrum and phase curves, including the large amplitude of the phase curve at 3.6um, the small hot-spot longitude shift and the hot mid-infrared emission spectrum. We discuss possible compositions and derive some first-order estimates for the properties of the putative condensate haze/clouds. We finish by speculating that the dichotomy between the two observationally defined classes of hot Jupiter atmospheres, of which HD189733b and HD209458b are the prototypes, might not be whether they possess a temperature inversion, but whether they are clear or dusty. We also consider the possibility of a continuum of cloud properties between hot Jupiters, young Jupiters and L-type brown dwarfs.Comment: Accepted for publication in MNRAS. 31 pages, 19 figures, 8 table

GTC OSIRIS transiting exoplanet atmospheric survey: detection of sodium in XO-2b from differential long-slit spectroscopy

We present two transits of the hot-Jupiter exoplanet XO-2b using the Gran Telescopio Canarias (GTC). The time series observations were performed using long-slit spectroscopy of XO-2 and a nearby reference star with the OSIRIS instrument, enabling differential specrophotometric transit lightcurves capable of measuring the exoplanet's transmission spectrum. Two optical low-resolution grisms were used to cover the optical wavelength range from 3800 to 9300{\AA}. We find that sub-mmag level slit losses between the target and reference star prevent full optical transmission spectra from being constructed, limiting our analysis to differential absorption depths over ~1000{\AA} regions. Wider long slits or multi-object grism spectroscopy with wide masks will likely prove effective in minimising the observed slit-loss trends. During both transits, we detect significant absorption in the planetary atmosphere of XO-2b using a 50{\AA} bandpass centred on the Na I doublet, with absorption depths of Delta(R_pl/R_star)^2=0.049+/-0.017 % using the R500R grism and 0.047+/-0.011 % using the R500B grism (combined 5.2-sigma significance from both transits). The sodium feature is unresolved in our low-resolution spectra, with detailed modelling also likely ruling out significant line-wing absorption over an ~800{\AA} region surrounding the doublet. Combined with narrowband photometric measurements, XO-2b is the first hot Jupiter with evidence for both sodium and potassium present in the planet's atmosphere.Comment: 9 pages, 10 figures, 1 table, accepted for publication in MNRA

A single-photon sampling architecture for solid-state imaging

Advances in solid-state technology have enabled the development of silicon photomultiplier sensor arrays capable of sensing individual photons. Combined with high-frequency time-to-digital converters (TDCs), this technology opens up the prospect of sensors capable of recording with high accuracy both the time and location of each detected photon. Such a capability could lead to significant improvements in imaging accuracy, especially for applications operating with low photon fluxes such as LiDAR and positron emission tomography. The demands placed on on-chip readout circuitry imposes stringent trade-offs between fill factor and spatio-temporal resolution, causing many contemporary designs to severely underutilize the technology's full potential. Concentrating on the low photon flux setting, this paper leverages results from group testing and proposes an architecture for a highly efficient readout of pixels using only a small number of TDCs, thereby also reducing both cost and power consumption. The design relies on a multiplexing technique based on binary interconnection matrices. We provide optimized instances of these matrices for various sensor parameters and give explicit upper and lower bounds on the number of TDCs required to uniquely decode a given maximum number of simultaneous photon arrivals. To illustrate the strength of the proposed architecture, we note a typical digitization result of a 120x120 photodiode sensor on a 30um x 30um pitch with a 40ps time resolution and an estimated fill factor of approximately 70%, using only 161 TDCs. The design guarantees registration and unique recovery of up to 4 simultaneous photon arrivals using a fast decoding algorithm. In a series of realistic simulations of scintillation events in clinical positron emission tomography the design was able to recover the spatio-temporal location of 98.6% of all photons that caused pixel firings.Comment: 24 pages, 3 figures, 5 table

A new look at NICMOS transmission spectroscopy of HD189733, GJ-436 and XO-1: no conclusive evidence for molecular features

We present a re-analysis of archival HST/NICMOS transmission spectroscopy of three exoplanet systems; HD 189733, GJ-436 and XO-1. Detections of several molecules, including H20, CH4 and CO2, have been claimed for HD 189733 and XO-1, but similarly sized features are attributed to systematic noise for GJ-436. The data consist of time-series grism spectra covering a planetary transit. After extracting light curves in independent wavelength channels, we use a linear decorrelation technique account for instrumental systematics (which is becoming standard in the field), and measure the planet-to-star radius ratio as a function of wavelength. For HD 189733, the uncertainties in the transmission spectrum are significantly larger than those previously reported. We also find the transmission spectrum is considerably altered when using different out-of-transit orbits to remove the systematics, when some parameters are left out of the decorrelation procedure, or when we perform the decorrelation with quadratic functions rather than linear functions. Given that there is no physical reason to believe the baseline flux should be modelled as a linear function of any particular set of parameters, we interpret this as evidence that the linear decorrelation technique is not a robust method to remove systematic effects from the light curves for each wavelength channel. For XO-1, the parameters measured to decorrelate the light curves would require extrapolation to the in-transit orbit to remove the systematics, and we cannot reproduce the previously reported results. We conclude that the resulting NICMOS transmission spectra are too dependent on the method used to remove systematics to be considered robust detections of molecular species in planetary atmospheres, although the presence of these molecules is not ruled out.Comment: 17 pages, 28 figures, accepted in MNRA

Novel Omega-3 Fatty Acid Epoxygenase Metabolite Reduces Kidney Fibrosis.

Cytochrome P450 (CYP) monooxygenases epoxidize the omega-3 polyunsaturated fatty acid (PUFA) docosahexaenoic acid into novel epoxydocosapentaenoic acids (EDPs) that have multiple biological actions. The present study determined the ability of the most abundant EDP regioisomer, 19,20-EDP to reduce kidney injury in an experimental unilateral ureteral obstruction (UUO) renal fibrosis mouse model. Mice with UUO developed kidney tubular injury and interstitial fibrosis. UUO mice had elevated kidney hydroxyproline content and five-times greater collagen positive fibrotic area than sham control mice. 19,20-EDP treatment to UUO mice for 10 days reduced renal fibrosis with a 40%-50% reduction in collagen positive area and hydroxyproline content. There was a six-fold increase in kidney α-smooth muscle actin (α-SMA) positive area in UUO mice compared to sham control mice, and 19,20-EDP treatment to UUO mice decreased α-SMA immunopositive area by 60%. UUO mice demonstrated renal epithelial-to-mesenchymal transition (EMT) with reduced expression of the epithelial marker E-cadherin and elevated expression of multiple mesenchymal markers (FSP-1, α-SMA, and desmin). Interestingly, 19,20-EDP treatment reduced renal EMT in UUO by decreasing mesenchymal and increasing epithelial marker expression. Overall, we demonstrate that a novel omega-3 fatty acid metabolite 19,20-EDP, prevents UUO-induced renal fibrosis in mice by reducing renal EMT

Languages and Learning at Key Stage 2: A Longitudinal Study Final Report

In 2006, The Open University, the University of Southampton and Canterbury Christ Church University were commissioned by the then Department for Education and Skills (DfES), now Department for Children, Schools and Families (DCSF) to conduct a three-year longitudinal study of languages learning at Key Stage 2 (KS2). The qualitative study was designed to explore provision, practice and developments over three school years between 2006/07 and 2008/09 in a sample of primary schools and explore children’s achievement in oracy and literacy, as well as the possible broader cross-curricular impact of languages learning