Effect of dislocations on charge carrier mobility-lifetime product in synthetic single crystal diamond

The authors report correlations between variations in charge transport of electrons and holes in synthetic single crystal diamond and the presence of nitrogen impurities and dislocations. The spatial distribution of these defects was imaged using their characteristic luminescence emission and compared with maps of carrier drift length measured by ion beam induced charge imaging. The images indicate a reduction of electron and hole mobility-lifetime product due to nitrogen impurities and dislocations. Very good charge transport is achieved in selected regions where the dislocation density is minimal

Pore-pressure cycling experiments on Mx80 bentonite

The Swedish concept for geological disposal of radioactive waste involves the use of bentonite as part of an engineered barrier system. A primary function of the bentonite is its ability to swell when hydrated by its surroundings. One particular uncertainty is the impact on this function, resulting from deviations in pore-water pressure, pw, from expected in situ hydrostatic conditions. We present results from a series of laboratory experiments designed to investigate the form of the relationship between swelling pressure and pw, for compacted Mx80 bentonite, from low to elevated applied water pressure conditions. The experiments were conducted using constant volume cells, designed to allow the total stresses acting on the surrounding vessel to be monitored (at five locations) during clay swelling. The results demonstrate that swelling pressure reduces nonlinearly with increasing pw, becoming less sensitive to changes at elevated pressures. After cyclic loading a marked hysteresis was also observed, with swelling pressure remaining elevated after a subsequent reduction in applied water pressure. Such behaviour may impact the mechanical and transport properties of the bentonite and its resulting performance. However, such hysteric behaviour was not always observed. Further testing is required to better understand the causes of this phenomenon and the controls on such behaviour

Bentonite homogenisation during the closure of void spaces

In a geological repository, the disposal of radioactive waste will result in the creation of engineering voids. Bentonite is commonly proposed as a sealing material as a result of its high swelling capacity. As the bentonite expands, the non-uniform development of porewater pressure and its coupling to total stress within the bentonite, may impair homogenisation. In this study we present results from five laboratory tests performed on sodium- and calcium-based bentonites to examine their swelling potential and capacity to homogenise over extreme bentonite-to-void ratios. Results demonstrate that even under these extreme ratios, the bentonite is able to swell and ultimately fill each void, creating a small swelling pressure. The swelling pressure development is spatially complex and time-consuming, and does not appear to be influenced by friction. Instead, it is characterised by plastic yielding of the clay with 70%–80% of the volume change associated with clay expansion adjacent to the void. This leads to heterogeneity illustrated by the presence of persistent differential stresses and the non-uniform distribution of moisture contents. Increases in the moisture content were measured but did not always correlate with the development of swelling pressure. This disequilibrium of the system is likely a reflection of the test durations and the slow evolution in the rates of change in swelling and porewater pressure beyond 130 days. Given the length of the experimental tests presented here, the time required to achieve full homogenisation of the clay is likely to be many years, if it occurs at all. Gravity segregation was also present in horizontal tests, further impairing clay homogenisation. However, as presented in this paper, it is possible to define functional relationships describing the bentonite swelling potential across engineering voids of differing size. This information will assist in establishing a safety case for bentonite usage in geological radioactive waste disposal

Evidence of localised gas propagation pathways in a field-scale bentonite engineered barrier system: results from three gas injection tests in the large scale gas injection test (Lasgit)

Three gas injection tests have been conducted during a large scale gas injection test (Lasgit) performed at the Äspö Hard Rock Laboratory, Sweden. Lasgit is a full-scale experiment based on the Swedish KBS-3 repository concept, examining the processes controlling gas and water flow in highly water-saturated compact buffer bentonite. Three preliminary gas injection tests have been performed. The first two tests were conducted in the lower array of injection filters (FL903). Both of these tests showed similar behaviour that corresponded with laboratory observations. The third gas test was conducted in an upper array filter (FU910), which gave a subtly dissimilar response at major gas entry with an initial pressure drop followed by a secondary gas peak pressure. Lasgit has confirmed the coupling between gas, stress and pore-water pressure for flow before and after major gas entry at the field scale. All observations suggest mechanisms of pathway propagation and dilatancy predominate. In all three gas tests the propagation was through localised features that tended to exploit the interface between the copper canister and the bentonite buffer. Considerable evidence exists for the development of a highly-dynamic, tortuous network of pressure induced pathways which evolves both temporally and geospatially within the clay, opening and closing probably due to local changes in gas pressure and or effective stress