Influence of a tight isotropic harmonic trap on photoassociation in ultracold homonuclear alkali gases

The influence of a tight isotropic harmonic trap on photoassociation of two ultracold alkali atoms forming a homonuclear diatomic is investigated using realistic atomic interaction potentials. Confinement of the initial atom pair due to the trap leads to a uniform strong enhancement of the photoassociation rate to most, but also to a strongly suppressed rate for some final states. Thus tighter traps do not necessarily enhance the photoassociation rate. A further massive enhancement of the rate is found for strong interatomic interaction potentials. The details of this interaction play a minor role, except for large repulsive interactions for which a sharp window occurs in the photoassociation spectrum as is known from the trap-free case. A comparison with simplified models describing the atomic interaction like the pseudopotential approximation shows that they often provide reasonable estimates for the trap-induced enhancement of the photoassociation rate even if the predicted rates can be completely erroneous.Comment: 19 pages, 17 figure

Exploring the distribution and physiological roles of bacterial membrane lipids in the marine environment

Submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy at the Massachusetts Institute of Technology and the Woods Hole Oceanographic Institution June 2010Lipids have a legacy in the geologic record extending back to the Archaean. Since the phylogenetic diversity of life is reflected in the structural diversity of biomolecules, lipid biomarkers that are shown to be diagnostic of certain organisms that carry out specific biochemical processes or that are demonstrated to have unique physiological roles can be used to trace the biogeochemical influence of bacteria in modern and ancient environments. In this thesis I explore the application of two classes of bacterial membrane lipids as biomarkers for marine biogeochemical processes in marine environments: ladderanes and hopanoids. Through the detection of ladderane lipids – biomarkers for anaerobic ammonium oxidizing (anammox) bacteria – I demonstrate the presence and distribution of anammox bacteria in a subterranean estuary. Through a survey of hopanoids in marine environments and cultured marine cyanobacteria I show that hopanoids are ubiquitous in the oceans and that their presence in ancient marine sediments could provide information about biogeochemical processes in past environments. Based on novel results demonstrating that hopanoids are resistant to extraction by non-ionic detergent, I propose that they may play a role in lipid ordering and the formation of putative lipid rafts in hopanoid-producing bacteria.This work was supported by National Science Foundation grants to R.E. Summons and T.I. Eglinton (ETBC 084990) an American Chemical Society Petroleum Research Fund to R.E. Summons (ACS PRF 46838-AC2), and a WHOI OLI Tropical Initiatives grant to T.I. Eglinton and J. Waterbury. I received support from an NSF Graduate Research Fellowship, Dan David Doctoral Fellowship, WHOI COI Student Fellowship, and a WHOI Ocean Ventures Fund

Break-down of the single-active-electron approximation for one-photon ionization of the B 1Σu+^1\Sigma_u^+ state of H2_2 exposed to intense laser fields

Ionization, excitation, and de-excitation to the ground state is studied theoretically for the first excited singlet state B $^1\Sigma_u^+$ of H$_2$ exposed to intense laser fields with photon energies in between about 3 eV and 13 eV. A parallel orientation of a linear polarized laser and the molecular axis is considered. Within the dipole and the fixed-nuclei approximations the time-dependent Schr\"odinger equation describing the electronic motion is solved in full dimensionality and compared to simpler models. A dramatic break-down of the single-active-electron approximation is found and explained to be due to the inadequate description of the final continuum states.Comment: 9 pages, 4 figure

Accurate photoionisation cross section for He at non-resonant photon energies

The total single-photon ionisation cross section was calculated for helium atoms in their ground state. Using a full configuration-interaction approach the photoionisation cross section was extracted from the complex-scaled resolvent. In the energy range from ionisation threshold to 59\,eV our results agree with an earlier $B$-spline based calculation in which the continuum is box discretised within a relative error of $0.01\%$ in the non-resonant part of the spectrum. Above the \He^{++} threshold our results agree on the other hand very well to a recent Floquet calculation. Thus our calculation confirms the previously reported deviations from the experimental reference data outside the claimed error estimate. In order to extend the calculated spectrum to very high energies, an analytical hydrogenic-type model tail is introduced that should become asymptotically exact for infinite photon energies. Its universality is investigated considering also H$^-$, Li$^+$, and HeH$^+$. With the aid of the tail corrections to the dipole approximation are estimated.Comment: 20 pages, 7 figures, 2 table

Stopping power of antiprotons in H, H2, and He targets

The stopping power of antiprotons in atomic and molecular hydrogen as well as helium was calculated in an impact-energy range from 1 keV to 6.4 MeV. In the case of H2 and He the targets were described with a single-active electron model centered on the target. The collision process was treated with the close-coupling formulation of the impact-parameter method. An extensive comparison of the present results with theoretical and experimental literature data was performed in order to evaluate which of the partly disagreeing theoretical and experimental data are most reliable. Furthermore, the size of the corrections to the first-order stopping number, the average energy transferred to the target electrons, and the relative importance of the excitation and the ionization process for the energy loss of the projectile was determined. Finally, the stopping power of the H, H2, and He targets were directly compared revealing specific similarities and differences of the three targets.Comment: v1: 12 pages, 8 figures, and 1 table v2: 15 pages, 9 figures, and 2 tables; extended discussion on IPM in Method; influence of double ionization on stopping power discussed in Result

High School Students Embedded in Adult Community College Classes

Early college high schools were established as an initiative of the Bill and Melinda Gates Foundation with the goal for students of earning college credit and an associate degree while in high school. Many of these high school students attend college classes with adults, ages 18 and older, in the same class. Instructors are challenged to address these students’ diverse needs and diverse ways of learning. Young teenagers typically are told exactly what to learn and how it is to be learned; the adult learner, however, is much more independent and he or she learns and thinks differently based on more varied experiences. In this paper, the authors provide some concrete examples of instructional practices based on Knowles’ Model of Adult Learning

Exploring relationships between playspaces, pedagogy, and preschoolers’ play-based science and engineering practices

This manuscript reports the results of a research study exploring the ways in which physical space and teacher pedagogy are related to preschoolers’ engagement with science and engineering practices while at play. Using the Science and Engineering Practices Observation Protocol (SciEPOP), researchers captured children’s engagement with the eight science and engineering practices identified in the Next Generation Science Standards (NGSS). This study explores relationships between specific playspaces, materials, and pedagogical strategies, and children’s patterns of engagement with particular science and engineering practices during free play. There are notable differences in the spaces, materials, and pedagogies children encounter across the four participating preschools, and these differences suggest significant gaps in children’s opportunities to engage in and deepen their enactment of science and engineering practices. The authors present evidence in support of adaptive, personalized strategies for deepening children’s engagement with science through play, and raise questions about equity in early science learning environments that have implications both nationally and internationally for science education research, practice, and policy

Photoassociative spectroscopy at long range in ultracold strontium

We report photoassociative spectroscopy of $^{88}$Sr$_2$ in a magneto-optical trap operating on the ${^1S_0}\to{^3P_1}$ intercombination line at 689 nm. Photoassociative transitions are driven with a laser red-detuned by 600-2400 MHz from the ${^1S_0}\to{^1P_1}$ atomic resonance at 461 nm. Photoassociation takes place at extremely large internuclear separation, and the photoassociative spectrum is strongly affected by relativistic retardation. A fit of the transition frequencies determines the ${^1P_1}$ atomic lifetime ($\tau=5.22 \pm 0.03$ ns) and resolves a discrepancy between experiment and recent theoretical calculations.Comment: 4 pages, 4 figures, submitte