Frequency dependence dielectrophoresis technique for bridging graphene nanoribbons

We succeeded in bridging unzipped graphene nanoribbons (GNRs) and separating them from unwanted single-walled carbon nanotubes (SWNTs) using a frequency-dependent dielectrophoresis (DEP) method by varying the frequency and applied voltage used for future assembly. Atomic force micrographs and Raman spectra proved that unzipped GNRs were successfully bridged by the DEP method at frequencies higher than 13 MHz. The theoretical calculation also supported the finding that only GNRs were collected from a mixture of SWNTs/GNRs suspensions

Visualizing Ribbon‐to‐Ribbon Heterogeneity of Chemically Unzipped Wide Graphene Nanoribbons by Silver Nanowire‐Based Tip‐Enhanced Raman Scattering Microscopy

Graphene nanoribbons (GNRs), a quasi-one-dimensional form of graphene, have gained tremendous attention due to their potential for next-generation nanoelectronic devices. The chemical unzipping of carbon nanotubes is one of the attractive fabrication methods to obtain single-layered GNRs (sGNRs) with simple and large-scale production. The authors recently found that unzipping from double-walled carbon nanotubes (DWNTs), rather than single- or multi-walled, results in high-yield production of crystalline sGNRs. However, details of the resultant GNR structure, as well as the reaction mechanism, are not fully understood due to the necessity of nanoscale spectroscopy. In this regard, silver nanowire-based tip-enhanced Raman spectroscopy (TERS) is applied for single GNR analysis and investigated ribbon-to-ribbon heterogeneity in terms of defect density and edge structure generated through the unzipping process. The authors found that sGNRs originated from the inner walls of DWNTs showed lower defect densities than those from the outer walls. Furthermore, TERS spectra of sGNRs exhibit a large variety in graphitic Raman parameters, indicating a large variation in edge structures. This work at the single GNR level reveals, for the first time, ribbon-to-ribbon heterogeneity that can never be observed by diffraction-limited techniques and provides deeper insights into unzipped GNR structure as well as the DWNT unzipping reaction mechanism

Frequency dependence dielectrophoresis technique for bridging graphene nanoribbons

We succeeded in bridging unzipped graphene nanoribbons (GNRs) and separating them from unwanted single-walled carbon nanotubes (SWNTs) using a frequency-dependent dielectrophoresis (DEP) method by varying the frequency and applied voltage used for future assembly. Atomic force micrographs and Raman spectra proved that unzipped GNRs were successfully bridged by the DEP method at frequencies higher than 13 MHz. The theoretical calculation also supported the finding that only GNRs were collected from a mixture of SWNTs/GNRs suspensions