9 research outputs found

    Hydrogen ordering effects in Laves - phase YFe2

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    Mössbauer spectroscopy and X-ray diffraction measurements were performed before and after hydrogenation of YFe2 Laves phase in order to investigate the effect of hydrogen on their structural and magnetic properties. The experimental results show an instant change of both the lattice parameters and the hyperfine field. The results are interpreted due to the phase decomposition of the parent intermetallic in the aftermath of creation of stoichiometric hydrides YHc (c = 0.9; 2.5)

    The hippodrome of Gerasa : a report on excavations and research 1982-1987

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    Ostrasz Antoni A. The hippodrome of Gerasa : a report on excavations and research 1982-1987. In: Syria. Tome 66 fascicule 1-4, 1989. pp. 51-77

    A Dilute-Limit Heat οf Solution of Aluminium in Iron Studied with 57Fe\text{}^{57}Fe Mössbauer Spectroscopy

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    The room temperature 57Fe\text{}^{57}Fe Mössbauer spectra for binary iron-based solid solutions Fe1−xAlxFe_{1-x}Al_x, with x in the range 0.03 ≤ x ≤ 0.05, were analysed in terms of binding energy EbE_b between two Al atoms in the Fe-Al system. The extrapolated values of EbE_b for x= 0 were used for computation of the dilute-limit heat of solution of aluminium in iron. The results were compared with that resulting from the Miedema's model of alloys as well as those derived from the heat of formation of the system, obtained with both calorimetric measurements and theoretical calculations. The comparison shows that our Mössbauer spectroscopy findings are in good agreement with all the other results mentioned above

    A Dilute-Limit Heat οf Solution of Aluminium in Iron Studied with 57

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    The room temperature 57Fe\text{}^{57}Fe Mössbauer spectra for binary iron-based solid solutions Fe1−xAlxFe_{1-x}Al_x, with x in the range 0.03 ≤ x ≤ 0.05, were analysed in terms of binding energy EbE_b between two Al atoms in the Fe-Al system. The extrapolated values of EbE_b for x= 0 were used for computation of the dilute-limit heat of solution of aluminium in iron. The results were compared with that resulting from the Miedema's model of alloys as well as those derived from the heat of formation of the system, obtained with both calorimetric measurements and theoretical calculations. The comparison shows that our Mössbauer spectroscopy findings are in good agreement with all the other results mentioned above

    Hydrogen effect on the electronic and structural properties of Nb-Fe alloys

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    The influence of hydrogen on the electronic and structural properties of Nb1-yFey alloys has been studied with 57Fe Mössbauer spectroscopy and X-ray diffraction. No ability of hydrogen to creation of the ferromagnetic properties has been observed in this system. The results clearly indicate the ß-NbH0.85÷0.77 hydride formation in place of ?-Nb phase. The quadrupole splitting and the isomer shift of the ß-NbHx subspectrum have been considered in terms of interaction between the interstitials and the Mössbauer atoms within the hydride phase
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