20 research outputs found
Transformation of in-plane in at fixed oxygen content
This paper reveals the origin of variation in the magnitude and temperature
dependence of the normal state resistivity frequently observed in different
YBCO single crystal or thin film samples with the same . We investigated
temperature dependence of resistivity in thin films
with 7- and 6.90, which were subjected to annealing in argon at
400-420 K (). Before annealing these films exhibited a non-linear
, with a flattening below 230 K, similar to and
observed in untwinned and twinned YBCO crystals, respectively.
For all films the annealing causes an increase of resistivity and a
transformation of from a non-linear dependence towards a more
linear one (less flattening). In films with 7- the increase of
resistivity is also associated with an increase in . We proposed the
model that provides an explanation of these phenomena in terms of thermally
activated redistribution of residual O(5) oxygens in the chain-layer of YBCO.
Good agreement between the experimental data for , where t is
the annealing time, and numerical calculations was obtained.Comment: 8 pages, 9 figures, submitted to PR
Silver on copper phthalocyanine: Abrupt and inert interfaces
The chemistry and electronic structure evolution were studied upon the formation of the interfaces between copper phthalocyanine and Ag and Sn deposited on it in ultra high vacuum conditions. The measurements were performed by means of high-resolution photoemission spectroscopy of core-levels and the valence band, and using synchrotron-radiation facilities. The investigations demonstrate the formation of chemically inert and abrupt interfaces