Statistical Mechanics of Glass Formation in Molecular Liquids with OTP as an Example

We extend our statistical mechanical theory of the glass transition from examples consisting of point particles to molecular liquids with internal degrees of freedom. As before, the fundamental assertion is that super-cooled liquids are ergodic, although becoming very viscous at lower temperatures, and are therefore describable in principle by statistical mechanics. The theory is based on analyzing the local neighborhoods of each molecule, and a statistical mechanical weight is assigned to every possible local organization. This results in an approximate theory that is in very good agreement with simulations regarding both thermodynamical and dynamical properties

Capitalist Care : Will the Coalition Government's reforms move the NHS toward a US-style healthcare market?

The Coalition government’s plans for reform are meant to transform the NHS into a more privately run, competitive system, raising the question as to whether or not the NHS is likely to resemble the US capitalist healthcare industry. The US system will be examined for comparative purposes, followed by an analysis of how far earlier reforms under Conservative and New Labour governments have moved the NHS in that direction. The implications of the White Paper proposals are analysed to determine the degree to which the NHS is destined to become a commodity-producing industry. The tentative conclusion is that while secondary care will be similar in many ways to the US hospital industry, state funding remains a barrier to complete transformation, and what is likely to emerge is a hybrid system in which competition, consolidation, and pressure on the workforce all increase.Peer reviewe