Houtkwaliteit en bosbeheer; beslist meer aandacht waard (deel 1)

Dit artikel gaat in op verschillende aspecten van houtkwaliteit in relatie tot het gevoerde bosbeheer. Het omvat de gehele inlandse bosbouw en houtverwerkingskete

Onderzoek naar de relatie van eikensterfte met droogte en bodemchemie

In verband met verhevigde eikensterfte is onderzocht of er verband is tussen de eikensterfte en droogte en/of bodemchemie. Hiervoor is op tien locaties in een opstand met veel sterfte en een opstand met weinig sterfte de jaarringbreedte van de laatste 50 jaar vergeleken met weersgegevens van de dichtstbijzijnde weerstations, de hoeveelheid fijne wortels op 0-25 cm en 25-50 cm diepte bepaald en aan de hand van grondmonsters de bodemchemie gekarakteriseerd. Uit dit onderzoek is gebleken dat er een duidelijk verband is tussen de van tijd tot tijd optredende sterke groeivermindering van eiken en droogteperioden. Niet alle sterke groeiverminderingen zijn hiermee te verklaren. Er zijn aanwijzingen dat het aantal vorstdagen in de lente ook een rol speelt. In opstanden met veel sterfte zitten gemiddeld bovenin het bodemprofiel meer wortels en onderin minder dan in opstanden met weinig sterfte. In opstanden met veel sterfte heeft de bodem in de meeste gevallen lagere gehaltes aan uitwisselbaar Ca en/of K en/of Mg (dus een lagere buffercapaciteit). Het gehele proces van primaire oorzaken en secundaire factoren, die verantwoordelijk zijn voor de sterfte, is nog niet helder. Hiervoor is een breder en fundamenteler onderzoek noodzakelijk. Voor het beheer van eikenbossen worden voorlopige adviezen gegeven

Eikensterfte: een serieus en complex probleem

Steeds meer beheerders zien met lede ogen aan hoe de eiken in hun bossen langzaam maar zeker afsterven. Over de precieze oorzaak is nog niet zo heel veel bekend. Wel maakt onderzoek duidelijk dat er meerdere oorzaken zijn die elkaar lijken te versterken. Droogte en aantasting door insecten zijn zeker een deel van het probleem, maar ook de snelle uitspoeling van basische kationen zijn waarschijnlijk een heel belangrijke facto

The Phoenix Deep Survey: The 1.4 GHz microJansky catalogue

The initial Phoenix Deep Survey (PDS) observations with the Australia Telescope Compact Array have been supplemented by additional 1.4 GHz observations over the past few years. Here we present details of the construction of a new mosaic image covering an area of 4.56 square degrees, an investigation of the reliability of the source measurements, and the 1.4 GHz source counts for the compiled radio catalogue. The mosaic achieves a 1-sigma rms noise of 12 microJy at its most sensitive, and a homogeneous radio-selected catalogue of over 2000 sources reaching flux densities as faint as 60 microJy has been compiled. The source parameter measurements are found to be consistent with the expected uncertainties from the image noise levels and the Gaussian source fitting procedure. A radio-selected sample avoids the complications of obscuration associated with optically-selected samples, and by utilising complementary PDS observations including multicolour optical, near-infrared and spectroscopic data, this radio catalogue will be used in a detailed investigation of the evolution in star-formation spanning the redshift range 0 < z < 1. The homogeneity of the catalogue ensures a consistent picture of galaxy evolution can be developed over the full cosmologically significant redshift range of interest. The 1.4 GHz mosaic image and the source catalogue are available on the web at http://www.atnf.csiro.au/~ahopkins/phoenix/ or from the authors by request.Comment: 16 pages, 11 figures, 4 tables. Accepted for publication by A

Accurate prediction of core-level spectra of radicals at density functional theory cost via square gradient minimization and recoupling of mixed configurations

State-specific orbital optimized approaches are more accurate at predicting core-level spectra than traditional linear-response protocols, but their utility had been restricted on account of the risk of `variational collapse' down to the ground state. We employ the recently developed square gradient minimization (SGM, J. Chem. Theory Comput. 16, 1699-1710, 2020) algorithm to reliably avoid variational collapse and study the effectiveness of orbital optimized density functional theory (DFT) at predicting second period element 1s core-level spectra of open-shell systems. Several density functionals (including SCAN, B3LYP and $\omega$B97X-D3) are found to predict excitation energies from the core to singly occupied levels to high accuracy ($\le 0.3$ eV RMS error), against available experimental data. Higher excited states are however more challenging by virtue of being intrinsically multiconfigurational. We thus present a CI inspired route to self-consistently recouple single determinant mixed configurations obtained from DFT, in order to obtain approximate doublet states. This recoupling scheme is used to predict the C K-edge spectra of the allyl radical, the O K-edge spectra of CO$^+$ and the N K-edge of NO$_2$ to high accuracy relative to experiment, indicating substantial promise in using this approach for computation of core-level spectra for doublet species (vs more traditional time dependent DFT, EOM-CCSD or using unrecoupled mixed configurations). We also present general guidelines for computing core-excited states from orbital optimized DFT.Comment: Added more dat

Untangling the stranglehold through mathematical modelling of Streptococcus equi subspecies equi transmission

Strangles, a disease caused by infection with Streptococccus equi subspecies equi (S. equi), is endemic worldwide and one of the most frequently diagnosed infectious diseases of horses. Recent work has improved our knowledge of key parameters of transmission dynamics, but important knowledge gaps remain. Our aim was to apply mathematical modelling of S. equi transmission dynamics to prioritise future research areas, and add precision to estimates of transmission parameters thereby improving understanding of S. equi epidemiology and quantifying the control effort required. A compartmental deterministic model was constructed. Parameter values were estimated from current literature wherever possible. We assessed the sensitivity of estimates for the basic reproduction number on the population scale to varying assumptions for the unknown or uncertain parameters of: (mean) duration of carriership (1∕γ C), relative infectiousness of carriers (f), proportion of infections that result in carriership (p), and (mean) duration of immunity after natural infection (1∕γ R). Available incidence and (sero-)prevalence data were compared to model outputs to improve point estimates and ranges for these currently unknown or uncertain transmission-related parameters. The required vaccination coverage of an ideal vaccine to prevent major outbreaks under a range of control scenarios was estimated, and compared available data on existing vaccines. The relative infectiousness of carriers (as compared to acutely ill horses) and the duration of carriership were identified as key knowledge gaps. Deterministic compartmental simulations, combined with seroprevalence data, suggest that 0.05<fˆ<0.5 and that the duration of protective immunity after infection is likely 4-6 years. The presence of carriers alone may suffice to keep S. equi endemic in a population, implying that carriers cannot be ignored in control efforts. Weekly screening of herds for signs of strangles could be sufficient to ensure R < 1, provided all horses are screened for carriership post-infection. In some of worst-case scenarios, vaccination alone would not suffice to prevent major outbreaks from occurring. A stochastic agent-based model was also constructed and validated, and used to simulate a remount depot, to evaluate whether historical incidence data of recurrence of strangles within individuals could be explained without the assumption that one in four horses fail to mount a lasting immune response. These simulations demonstrated that the observed data could have occurred without that assumption

Guidance on Monitoring of Marine Litter in European Seas

This publication is a Reference Report by the Joint Research Centre of the European Commission.The MSFD Technical Subgroup on Marine Litter was tasked to deliver guidance so that European Member States could initiate programmes for monitoring of Descriptor 10 of the MSFD. The present document provides the recommendations and information needed to commence the monitoring required for marine litter, including methodological protocols and categories of items to be used for the assessment of litter on the Beach, Water Column, Seafloor and Biota, including a special section on Microparticles

Design of a multicentered randomized controlled trial on the clinical and cost effectiveness of schema therapy for personality disorders

<p>Abstract</p> <p>Background</p> <p>Despite international guidelines describing psychotherapy as first choice for people with personality disorders (PDs), well-designed research on the effectiveness and cost-effectiveness of psychotherapy for PD is scarce. Schema therapy (ST) is a specific form of psychological treatment that proved to be effective for borderline PD. Randomized controlled studies on the effectiveness of ST for other PDs are lacking. Another not yet tested new specialized treatment is Clarification Oriented Psychotherapy (COP). The aim of this project is to perform an effectiveness study as well as an economic evaluation study (cost effectiveness as well as cost-utility) comparing ST versus COP versus treatment as usual (TAU). In this study, we focus on avoidant, dependent, obsessive-compulsive, paranoid, histrionic and narcissistic PD.</p> <p>Methods/Design</p> <p>In a multicentered randomized controlled trial, ST, and COP as an extra experimental condition, are compared to TAU. Minimal 300 patients are recruited in 12 mental health institutes throughout the Netherlands, and receive an extensive screening prior to enrolment in the study. When eligible, they are randomly assigned to one of the intervention groups. An economic evaluation and a qualitative research study on patient and therapist perspectives on ST are embedded in this trial. Outcome assessments (both for clinical effectiveness and economic evaluation) take place at 6,12,18,24 and 36 months after start of treatment. Primary outcome is recovery from PD; secondary measures include general psychopathological complaints, social functioning and quality of life. Data for the cost-effectiveness and cost-utility analyses are collected by using a retrospective cost interview. Information on patient and therapist perspectives is gathered using in-depth interviews and focus groups, and focuses on possible helpful and impeding aspects of ST.</p> <p>Discussion</p> <p>This trial is the first to compare ST and COP head-to-head with TAU for people with a cluster C, paranoid, histrionic and/or narcissistic PD. By combining clinical effectiveness data with an economic evaluation and with direct information from primary stakeholders, this trial offers a complete and thorough view on ST as a contribution to the improvement of treatment for this PD patient group.</p> <p>Trial registration</p> <p>Netherlands Trial Register (NTR): <a href="http://www.trialregister.nl/trialreg/admin/rctview.asp?TC=566">NTR566</a></p

Software for the frontiers of quantum chemistry:An overview of developments in the Q-Chem 5 package

This article summarizes technical advances contained in the fifth major release of the Q-Chem quantum chemistry program package, covering developments since 2015. A comprehensive library of exchange–correlation functionals, along with a suite of correlated many-body methods, continues to be a hallmark of the Q-Chem software. The many-body methods include novel variants of both coupled-cluster and configuration-interaction approaches along with methods based on the algebraic diagrammatic construction and variational reduced density-matrix methods. Methods highlighted in Q-Chem 5 include a suite of tools for modeling core-level spectroscopy, methods for describing metastable resonances, methods for computing vibronic spectra, the nuclear–electronic orbital method, and several different energy decomposition analysis techniques. High-performance capabilities including multithreaded parallelism and support for calculations on graphics processing units are described. Q-Chem boasts a community of well over 100 active academic developers, and the continuing evolution of the software is supported by an “open teamware” model and an increasingly modular design