SEASONAL VARIATION OF HEAVY METAL POLLUTION OF GROUNDWATER AND SOIL IN THE M’NASRA REGION (GHARB, MOROCCO)

M’nasra region is well known for increasing levels of heavy metal pollution in the environment, mainly due to waste discharge of Ouled Berjal, the irrational use of fertilizers, and the discharge of waste from several industries. The objective of this study was to access the seasonal variations in the groundwater and soil quality with respect to heavy metal pollution. Water samples from wells and samples from soil near them were taken during wet (January - March 2017) and dry (July 2017) seasons and concentrations of Cd, Cu, Cr, Mn, Ni, Pb, and Zn were determined using an Atomic Absorption Spectrophotometer (AAS). Contamination factor for each heavy metal and Nemerow pollution index was calculated. Results of the study revealed a decrease in pollution degree from wet to dry for soil and an increase in the case of groundwater. Cu had the lowest and Ni had the highest concentration in irrigation water whereas, for soil, Cd had the lowest and Zn had the highest concentration. During the wet season, all the concentrations of heavy metals decreased compared to the dry season, this can be explained by the dilution of these concentrations by precipitation water and therefore to lower absorption of these heavy metals in the water of irrigations and/or soil. Vertical transfer of pollutants from topsoil to groundwater was assessed using Hierarchical Cluster Analysis to identify associations between heavy metals and soil texture. In the case of Ni and Cr, the variables corresponding to the concentrations from soil and groundwater were part of the same cluster, in both seasons, the distribution maps of concentrations confirmed the pattern of transfer. This study can be considered as a baseline for the seasonal variation of heavy metal pollution of groundwater and soil. This study can be used not only for monitoring the study area but also as a tool for the implementation of environmental protection policies

GIS AND STATISTICAL EVALUATION OF SOIL QUALITY OF SIDI YAHYA, GHARBPLAIN (MOROCCO)

The study of soil quality in irrigated areas is necessary to evaluate the sustainability of the agricultural production system. Indeed, the assessment of this quality is based on the physicochemical and biological characterization of soil parameters, as well as the knowledge of their spatial distribution and their evolution over time. This work aims to make a diagnosis of the current situation of soil quality of SidiYahya in the Gharb plain, Morocco. For this, sampling was carried out from 33 sites distributed over the studied plain during 2019. In this study, different soil properties including specifically texture, pH, electrical conductivity (EC), organic matter (OM), phosphorus (P2O5), and potassium (K2O) were measured while exchangeable sodium percentage (ESP) was calculated using the standard formula. Based on the observed soil properties a map was prepared by using a geographic information system (GIS), which was based specifically on the inverse distance weighted (IDW) spatial interpolation method. Data were processed using different statistical tools like descriptive statistics, correlation, and principal component analysis (PCA). Results of the study revealed that 70% of the soils have a heavy clayey texture with a predominance of vertisols (55%). Further, the study area soil is mainly alkaline (70%), poor in organic matter (61%) and phosphorus (52%), while very rich in potassium (70%), and non-saline (88%) contents. Soil pH was reported to be the least variable whereas sand, phosphorus, and salinity were the highest variable. IDW allowed mapping the soil properties by moving from punctual information to whole extent information. Furthermore, correlations were found between various soil properties by using PCA, 3 principal components (PCs) were able to extract 76% of the information from the 9 initial soil properties. Collected soil samples were grouped into 3 groups, based on their scores on the 3 PCs. Based on these two kinds of information, delineation of management zones can be established for a site-specific supply of agricultural inputs leading to better management of soil and water resources for securing their sustainable use

Comparative Study of Groundwater Pollution of M’nasra and Sfafaa zones (Gharb, Morocco) by Nitrates

The quality of water resources in Morocco is degraded by pollution from agriculture, industry and urbanization. In this work we have realized a comparative study of two groundwater pollution zones: M’nasra (Kenitra) and Sfafaa (Sidi Slimane). In general, the results of this study showed that most water wells are strongly mineralized as the conductivity far exceeds the standard of drinking water. Sodium chloride (NaCl) concentration is between 33.9 and 1184.6 mg / l and shows some of the wells are loaded with salts. The pH is generally basic in all wells. Pollution by nitrates two regions showed that the ground water is strongly affected M’nasra zone terms of the permeability of the soil of the city. The concentration of nitrate can reach high values compared to the results obtained on the ground water at Sfafaa zone whose nitrate concentrations around 20 mg/l. Further pollution of groundwater in the two regions of the shows values of organic matters that go far beyond the standards of drinking