1,520 research outputs found
Surface-induced layer formation in polyelectrolytes
We analyze, by means of an RPA calculation, the conditions under which a
mixture of oppositely charged polyelectrolytes can micro-segregate in the
neighborhood of a charged surface creating a layered structure. A number of
stable layers can be formed if the surface is sufficiently strongly charged
even at temperatures at which the bulk of the mixture is homogeneous.Comment: 6 pages, 3 figures, revtex, epsf, psfi
Competing Interactions among Supramolecular Structures on Surfaces
A simple model was constructed to describe the polar ordering of
non-centrosymmetric supramolecular aggregates formed by self assembling
triblock rodcoil polymers. The aggregates are modeled as dipoles in a lattice
with an Ising-like penalty associated with reversing the orientation of nearest
neighbor dipoles. The choice of the potentials is based on experimental results
and structural features of the supramolecular objects. For films of finite
thickness, we find a periodic structure along an arbitrary direction
perpendicular to the substrate normal, where the repeat unit is composed of two
equal width domains with dipole up and dipole down configuration. When a short
range interaction between the surface and the dipoles is included the balance
between the up and down dipole domains is broken. Our results suggest that due
to surface effects, films of finite thickness have a none zero macroscopic
polarization, and that the polarization per unit volume appears to be a
function of film thickness.Comment: 3 pages, 3 eps figure
Competing interactions in two dimensional Coulomb systems: Surface charge heterogeneities in co-assembled cationic-anionic incompatible mixtures
A binary mixture of oppositely charged components confined to a plane such as
cationic and anionic lipid bilayers may exhibit local segregation. The relative
strength of the net short range interactions, which favors macroscopic
segregation, and the long range electrostatic interactions, which favors
mixing, determines the length scale of the finite size or microphase
segregation. The free energy of the system can be examined analytically in two
separate regimes, when considering small density fluctuations at high
temperatures, and when considering the periodic ordering of the system at low
temperatures (F. J. Solis and M. Olvera de la Cruz, J. Chem. Phys. 122, 054905
(2000)). A simple Molecular Dynamics simulation of oppositely charged monomers,
interacting with a short range Lennard Jones potential and confined to a two
dimensional plane, is examined at different strengths of short and long range
interactions. The system exhibits well-defined domains that can be
characterized by their periodic length-scale as well as the orientational
ordering of their interfaces. By adding salt, the ordering of the domains
disappears and the mixture macroscopically phase segregates in agreement with
analytical predictions.Comment: 8 pages, 5 figures, accepted for publication in J. Chem. Phys, Figure
1 include
Spontaneous chirality via long-range electrostatic forces
We consider a model for periodic patterns of charges constrained over a
cylindrical surface. In particular we focus on patterns of chiral helices,
achiral rings or vertical lamellae, with the constraint of global
electroneutrality. We study the dependence of the patterns' size and pitch
angle on the radius of the cylinder and salt concentration. We obtain a phase
diagram by using numerical and analytic techniques. For pure Coulomb
interactions, we find a ring phase for small radii and a chiral helical phase
for large radii. At a critical salt concentration, the characteristic domain
size diverges, resulting in macroscopic phase segregation of the components and
restoring chiral symmetry. We discuss possible consequences and generalizations
of our model.Comment: Revtex, 4 pages, 4 figure
Inversion polymorphism in some natural populations of Drosophila pseudoobscura from central Mexico
Samples of D. pseudoobscura were taken in seventeen localities in Central Mexico inside the parallels 18o - 20o N, with the purpose of determine the chromosomal polymorphism in the third of the different populations of this species. From each captured female a single larva of its offspring was taken, its salivary glands extracted and stained with a solution of aceto orcein to observe the polytene chromosomes. From these smears the corresponding karyotype of each larva was determined, keeping a record of them. With the information gathered the relative frequency of each one of the fourteen different inversions found was calculated. A grand total of 1894 third chromosomes were analyzed. The fourteen different inversions found are equivalent to a 34.1 % of the total chromosomal variation of the species. The most abundant inversions found were: TL 50.6 %, CU 27.2 5, SC 9.1 % and EP 5.5 %; the remaining ten inversions detected are in general grounds rare ones with variable relative frequencies depending on the locality. Analysis of the predominant inversions for each population was done. The presence of West-East gradients is reported, even if in cases not so well defined, since as one moves in a particular direction the ups and downs in relative frequency for the alternating pairs TL-CU; TL-SC in the western populations and TL-CU in the eastern ones were observed. The assignment of each population to a particular race was also done, and such a way we were able to recognize three different races coexisting in the area of study
Charged Particles on Surfaces: Coexistence of Dilute Phases and Periodic Structures on Membranes
We consider a mixture of one neutral and two oppositely charged types of
molecules confined to a surface. Using analytical techniques and molecular
dynamics simulations, we construct the phase diagram of the system and exhibit
the coexistence between a patterned solid phase and a charge-dilute phase. The
patterns in the solid phase arise from competition between short-range
immiscibility and long-range electrostatic attractions between the charged
species. The coexistence between phases leads to observations of stable
patterned domains immersed in a neutral matrix background.Comment: 5 pages, 3 figure
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