First-principles extrapolation method for accurate CO adsorption energies on metal surfaces

We show that a simple first-principles correction based on the difference between the singlet-triplet CO excitation energy values obtained by DFT and high-level quantum chemistry methods yields accurate CO adsorption properties on a variety of metal surfaces. We demonstrate a linear relationship between the CO adsorption energy and the CO singlet-triplet splitting, similar to the linear dependence of CO adsorption energy on the energy of the CO 2$\pi$* orbital found recently {[Kresse {\em et al.}, Physical Review B {\bf 68}, 073401 (2003)]}. Converged DFT calculations underestimate the CO singlet-triplet excitation energy $\Delta E_{\rm S-T}$, whereas coupled-cluster and CI calculations reproduce the experimental $\Delta E_{\rm S-T}$. The dependence of $E_{\rm chem}$ on $\Delta E_{\rm S-T}$ is used to extrapolate $E_{\rm chem}$ for the top, bridge and hollow sites for the (100) and (111) surfaces of Pt, Rh, Pd and Cu to the values that correspond to the coupled-cluster and CI $\Delta E_{\rm S-T}$ value. The correction reproduces experimental adsorption site preference for all cases and obtains $E_{\rm chem}$ in excellent agreement with experimental results.Comment: Table sent as table1.eps. 3 figure

A study of pseudoscalar states produced centrally in pp interactions at 450 GeV/c

A study has been made of pseudoscalar mesons produced centrally in pp interactions. The results show that the eta and etaprime appear to have a similar production mechanism which differs from that of the pi0. The production properties of the eta and etaprime are not consistent with what is expected from double Pomeron exchange. In addition the production mechanism for the eta and etaprime is such that the production cross section are greatest when the azimuthal angle between the pT vectors of the two protons is 90 degrees.Comment: 11 pages, Latex, 3 Figure

A study of the centrally produced phiphi system in pp interactions at 450 GeV/c

The reaction pp to pfps(K+K-K+K-) in which the K+K-K+K- system is centrally produced has been studied at 450 GeV/c. Phi phi production has been found to dominate this reaction and is compatible with being produced by double Pomeron exchange. An angular analysis of the phi phi system favours JPC = 2++ and its dPT dependence is similar to that observed for glueball candidates.Comment: 11 pages, Latex, 4 Figure

Branes, Anti-Branes and Brauer Algebras in Gauge-Gravity duality

We propose gauge theory operators built using a complex Matrix scalar which are dual to brane-anti-brane systems in $AdS_5 \times S^5$, in the zero coupling limit of the dual Yang-Mills. The branes involved are half-BPS giant gravitons. The proposed operators dual to giant-anti-giant configurations satisfy the appropriate orthogonality properties. Projection operators in Brauer algebras are used to construct the relevant multi-trace Matrix operators. These are related to the ``coupled representations'' which appear in 2D Yang-Mills theory. We discuss the implications of these results for the quantum mechanics of a complex matrix model, the counting of non-supersymmetric operators and the physics of brane-anti-brane systems. The stringy exclusion principle known from the properties of half-BPS giant gravitons, has a new incarnation in this context. It involves a qualitative change in the map between brane-anti-brane states to gauge theory operators. In the case of a pair of sphere giant and anti-giant this change occurs when the sum of the magnitudes of their angular momenta reaches $N$.Comment: 52 pages, 10 figure

Europeanization and the soft law process of EU corporate governance: how has the 2003 action plan impacted on national corporate governance codes?

This study explores Europeanization, the interrelationship between domestic and EU-level policy activity. Specifically, it asks how domestic policy is affected by EU-level (soft-law) policy processes. This contrasts with the hard-law focus of most Europeanization research. Our empirical analysis seeks to determine the extent to which the European Commission's 2003 plan to enhance corporate governance delivered on its aim of 'co-ordinating corporate governance efforts of member states'. This study thus differs from most others on convergence in corporate governance regimes, which look for evidence of convergence perse, rather than convergence towards a specified set of principles. Applying content analysis and econometric tests to 95 corporate governance codes issued between 1992 and mid-2010, we find that the Action Plan has influenced member states' corporate governance policies. However, the degree of national policy alignment to the Action Plan's priorities depends on when the corporate governance code was issued, here, and by whom

Modeling the actinides with disordered local moments

A first-principles disordered local moment (DLM) picture within the local-spin-density and coherent potential approximations (LSDA+CPA) of the actinides is presented. The parameter free theory gives an accurate description of bond lengths and bulk modulus. The case of $\delta$-Pu is studied in particular and the calculated density of states is compared to data from photo-electron spectroscopy. The relation between the DLM description, the dynamical mean field approach and spin-polarized magnetically ordered modeling is discussed.Comment: 6 pages, 4 figure

Partial wave analysis of J/\psi \to \gamma \phi \phi

Using $5.8 \times 10^7 J/\psi$ events collected in the BESII detector, the radiative decay $J/\psi \to \gamma \phi \phi \to \gamma K^+ K^- K^0_S K^0_L$ is studied. The $\phi\phi$ invariant mass distribution exhibits a near-threshold enhancement that peaks around 2.24 GeV/$c^{2}$. A partial wave analysis shows that the structure is dominated by a $0^{-+}$ state ($\eta(2225)$) with a mass of $2.24^{+0.03}_{-0.02}{}^{+0.03}_{-0.02}$ GeV/$c^{2}$ and a width of $0.19 \pm 0.03^{+0.06}_{-0.04}$ GeV/$c^{2}$. The product branching fraction is: $Br(J/\psi \to \gamma \eta(2225))\cdot Br(\eta(2225)\to \phi\phi) = (4.4 \pm 0.4 \pm 0.8)\times 10^{-4}$.Comment: 11 pages, 4 figures. corrected proof for journa

D-brane Deconstructions in IIB Orientifolds

With model building applications in mind, we collect and develop basic techniques to analyze the landscape of D7-branes in type IIB compact Calabi-Yau orientifolds, in three different pictures: F-theory, the D7 worldvolume theory and D9-anti-D9 tachyon condensation. A significant complication is that consistent D7-branes in the presence of O7^- planes are generically singular, with singularities locally modeled by the Whitney Umbrella. This invalidates the standard formulae for charges, moduli space and flux lattice dimensions. We infer the correct formulae by comparison to F-theory and derive them independently and more generally from the tachyon picture, and relate these numbers to the closed string massless spectrum of the orientifold compactification in an interesting way. We furthermore give concrete recipes to explicitly and systematically construct nontrivial D-brane worldvolume flux vacua in arbitrary Calabi-Yau orientifolds, illustrate how to read off D-brane flux content, enhanced gauge groups and charged matter spectra from tachyon matrices, and demonstrate how brane recombination in general leads to flux creation, as required by charge conservation and by equivalence of geometric and gauge theory moduli spaces.Comment: 49 pages, v2: two references adde