Assessment of efficiency of diesel generators use in distributed energy industry

The existing methods for calculation electricity tariffs for enterprises are analyzed numerically. The efficiency of diesel generators use for power supply was estimated using a real object as an example. A methodology has been developed for choosing the optimal price category, based on the schedule for consumption of electrical energy of a particular enterprise, taking into account introduction of its own generation in the 0.4 kV network. It is shown how to get the maximum benefit using one of the most affordable and autonomous power sources, taking into account the peculiarities of tariff setting for electricity

Differentiation of positional isomers of nitro meso-tetraphenylporphyrins by tandem mass spectrometry

AbstractWe studied by tandem mass spectrometry two isomers of nitro meso-tetraphenylporphyrin, one with a nitro group in the para position of a phenyl ring and the other with the same group in a β-pyrrolic position, and their copper complexes. Collisional activation of the molecular ions of both free-base porphyrins and of their copper complexes produces an array of product ions that permit ready differentiation of the two positional isomers. The diagnostic ions, when the nitro group is in a β-pyrrolic position, may be produced through intramolecular and double cyclization processes, triggered by the interaction of the nitro substituent with the neighboring meso-phenyl ring. These diagnostic ions do not form when the nitro group is in the para position. The gas-phase processes have precedents in solution chemistry