First Data on PAE Levels in Surface Water in Lakes of the Eastern Coast of Baikal

The increasing consumption of phthalates (PAEs), along with their high toxicity and high mobility, poses a threat to the environment. This study presents initial data on the contents of six priority PAEs in the water of lakes located on the eastern shore of Lake Baikal-Arangatui, Bormashevoe, Dukhovoe, Kotokel, and Shchuchye. The mean total concentrations of the six PAEs in lakes Arangatui and Bormashevoe (low anthropogenic load) were comparable to those in Kotokel (medium anthropogenic load, 17.34 µg/L) but were significantly higher (p < 0.05) than in Dukhovoe and Shchuchye (high anthropogenic load, 10.49 and 2.30 µg/L, respectively). DBP and DEHP were the main PAEs in all samples. The DEHP content in lakes Arangatui and Bormashevoe was quite high, and at some sampling sites it exceeded the MACs established by Russian, U.S. EPA, and WHO regulations. The assessment showed that there is no potential risk to humans associated with the presence of PAEs in drinking water. However, the levels of DEHP, DBP, and DnOP in the water pose a potential threat to sensitive aquatic organisms, as shown by the calculated risk quotients (RQs). It is assumed that the origin of the phthalates in the studied lakes is both anthropogenic and biogenic

Ecological State of Lake Gusinoe—A Cooling Pond of the Gusinoozersk GRES

The study of the transformation of substances in the basin of the Selenga River—the main tributary of Lake Baikal—under anthropogenic pressure and in the context of global climate change, is especially important for the lake, a globally important source of drinking water. The ecosystem of Lake Gusinoe is one of the key objects in the Selenga River basin that is exposed to significant anthropogenic pressure. This study presents the results of an analysis of water level changes and physicochemical parameters of the water mass of Lake Gusinoe; literature data from 1951 to 2017 and own data from 2017 to 2021. The water level in the lake had depended on natural factors before the Gusinoozersk GRES was launched; however, since the plant has begun using the lake as a cooling pond, its level has actually been regulated by the economic entity. Over the years, there has been a significant increase in mineralization, sulfate, sodium, fluoride and organic matter fractions resistant to oxidation. Seasonal increases in iron and manganese concentrations in water were detected. Increased concentrations of nutrients and organic matter fractions resistant to oxidation were registered at the wastewater discharge sites. Heavy metals in the bottom sediments of Lake Gusinoe accumulate mainly in the silt of the deep zone of the lake. Plants growing in the zones of influence of the Gusinoozersk GRES and Gusinoozersk wastewater discharge accumulate the largest amount of metals

Phthalates in Surface Waters of the Selenga River (Main Tributary of Lake Baikal) and Its Delta: Spatial-Temporal Distribution and Environmental Risk Assessment

The Selenga River provides about half of the water and chemical runoff into Lake Baikal and plays an important role in the sustainability of the ecosystem of this large natural freshwater lake. Phthalate esters (PAEs) are organic compounds that can disrupt reproductive and endocrine systems. This study focused on investigating the distribution of six priority phthalates in the Selenga River and its delta utilizing SPE-GC/MS. The study found that the highest levels of Σ6PAE were observed during the high-water years, 2021 and 2023, and were evenly distributed along the river from the sampling sites upstream of Ulan-Ude to the delta channels. In contrast, the mean annual Σ6PAE content was relatively low in the low water period of 2022. Dibutyl phthalate (DBP) and di-(2-ethylhexyl) phthalate (DEHP) are the two dominant phthalates found in the surface waters of the Selenga River and delta channels. In 2021, the average total concentration of six phthalates (Σ6PAE) ranged from 8.84 to 25.19 µg/L, while in 2022 it ranged from 0.45 to 4.01 µg/L, and in 2023 it ranged from 5.40 to 21.08 µg/L. The maximum level for the sum of phthalates was 61.64 µg/L in 2021, 13.57 µg/L in 2022, and 30.19 µg/L in 2023. The wastewater treatment facilities in Ulan-Ude were identified as a stable local source of phthalates. In some cases, PAE concentrations exceeded maximum allowable concentrations, particularly for DEHP. This could have adverse effects on aquatic organisms