Photodissociation of Cl_2O at 248 and 308 nm

Molecular beam studies of Cl_2O photolysis at 248 and 308 nm have been repeated and the analysis refined. At 248 nm, three distinct dissociation pathways that led to Cl+ClO products were resolved. At 308 nm, the angular distribution was slightly more isotropic than previously reported, leaving open the possibility that Cl_2O excited at 308 nm lives longer than a rotational period

Infrared diode laser spectroscopy of the fundamental band of NF(a1Δ)

Thirty-one lines of the fundamental vibration–rotation band of the NF free radical in its a 1 state have been detected in absorption near 8.6 µm using a tunable infrared diode laser. Linewidths were Doppler limited and several transitions were accompanied by resolved hyperfine structure due to fluorine and nitrogen nuclear moments. Wave number calibration using accurately determined N2O lines yielded v0 = 1165.952±0.001 cm^−1 for the band center. Rotational and centrifugal distortion constants for both v = 0 and 1 states have also been determined

BRST invariant Lagrangian of spontaneously broken gauge theories in noncommutative geometry

The quantization of spontaneously broken gauge theories in noncommutative geometry(NCG) has been sought for some time, because quantization is crucial for making the NCG approach a reliable and physically acceptable theory. Lee, Hwang and Ne'eman recently succeeded in realizing the BRST quantization of gauge theories in NCG in the matrix derivative approach proposed by Coquereaux et al. The present author has proposed a characteristic formulation to reconstruct a gauge theory in NCG on the discrete space $M_4\times Z_{_N}$. Since this formulation is a generalization of the differential geometry on the ordinary manifold to that on the discrete manifold, it is more familiar than other approaches. In this paper, we show that within our formulation we can obtain the BRST invariant Lagrangian in the same way as Lee, Hwang and Ne'eman and apply it to the SU(2)$\times$U(1) gauge theory.Comment: RevTeX, page

Dissociation Dynamics of CIONO_2 and Relative Cl and ClO Product Yields following Photoexcitation at 308 nm

Chlorine nitrate photolysis at 308 nm has been investigated with a molecular beam technique. Two primary decomposition pathways, leading to Cl + NO_3 and ClO + NO_2, were observed. The branching ratio between these two respective channels was determined to be 0.67 ± 0.06 : 0.33 ± 0.06. This ratio is an upper limit because some of the ClO photoproducts may have undergone secondary photodissociation. The angular distributions of the photoproducts with respect to the direction of polarization of the exciting light were anisotropic. The anisotropy parameters were β= 0.5 ± 0.2 for the Cl + NO_3 channel and β= 1.1 ± 0.2 for the ClO + NO_2 channel, indicating that dissociation of ClONO_2 by either pathway occurs within a rotational period. Weak signal at mass-to-charge ratios of 35 and 51, arising from products with laboratory velocities close to the beam velocity, was observed. While this signal could result from statistical dissociation channels with a total relative yield of 0.07 or less, it is more likely attributable to products from ClO secondary photodissociation or from dissociation of clusters

A Field-Theoretic Approach to Connes' Gauge Theory on M4×Z2M_4\times Z_2

Connes' gauge theory on $M_4\times Z_2$ is reformulated in the Lagrangian level. It is pointed out that the field strength in Connes' gauge theory is not unique. We explicitly construct a field strength different from Connes' one and prove that our definition leads to the generation-number independent Higgs potential. It is also shown that the nonuniqueness is related to the assumption that two different extensions of the differential geometry are possible when the extra one-form basis $\chi$ is introduced to define the differential geometry on $M_4\times Z_2$. Our reformulation is applied to the standard model based on Connes' color-flavor algebra. A connection between the unimodularity condition and the electric charge quantization is then discussed in the presence or absence of $\nu_R$.Comment: LaTeX file, 16 page

Primary and secondary dissociation pathways in the ultraviolet photolysis of Cl_2O

The photodissociation of dichlorine monoxide (Cl_2O) at 308, 248, and 193 nm was studied by photofragment translational energy spectroscopy. The primary channel upon excitation at 308 and 248 nm was Cl–O bond fission with production of ClO+Cl. A fraction of the ClO photoproducts also underwent spontaneous secondary dissociation at 248 nm. The center-of-mass translational energy distribution for the ClO+Cl channel at 248 nm appeared to be bimodal with a high energy component that was similar in shape to the 308 nm distribution and a second, low energy component with a maximum close to the threshold for the 2Cl+O(3P) channel. Observation of a bimodal distribution suggests that two pathways with different dissociation dynamics lead to ClO+Cl products. The high product internal energy of the second component raises the possibility that ClO is formed in a previously unobserved spin-excited state a 4∑−. Following excitation at 193 nm, a concerted dissociation pathway leading to Cl_2+O was observed in addition to primary Cl–O bond breakage. In both processes, most of the diatomic photofragments were formed with sufficient internal energy that they spontaneously dissociated. The time-of-flight distributions of the Cl_2+O products suggest that these fragments are formed in two different channels Cl_2(3II)+O(3P) and Cl_2(X1∑)+O(1D)

Reconstruction of the spontaneously broken gauge theory in non-commutative geometry

The scheme previously proposed by the present authors is modified to incorporate the strong interaction by affording the direct product internal symmetry. We do not need to prepare the extra discrete space for the color gauge group responsible for the strong interaction to reconstruct the standard model and the left-right symmetric gauge model(LRSM). The approach based on non-commutative geometry leads us to presents many attractive points such as the unified picture of the gauge and Higgs field as the generalized connection on the discrete space; Minkowski space multipied by N-points discrete space. This approach leads us to unified picture of gauge and Higgs fields as the generalized connection. The standard model needs N=2 discrete space for reconstruction in this formalism. \lr is still alive as a model with the intermediate symmetry of the spontaneously broken SO(10) grand unified theory(GUT). N=3 discrete space is needed for the reconstruction of LRSM to include two Higgs bosons $\phi$ and $\xi$ which are as usual transformed as (2,2*,0)$ and (1,3,-2) under left-handed SU(2)x right-handed SU(2)x U(1), respectively. xi is responsible to make the right handed-neutrino Majorana fermion and so well explains the seesaw mechanism. Up and down quarks have the different masses through the vacuum expectation value of phi.Comment: 21 page