The Flameretardant Study of PVA Using for Corrugated Cardboard

AbstractCorrugated cardboards have truss structure, so these have advantageous in terms of specific strength, workability, price and recycling efficiency. For these properties, corrugated cardboards are used as packing materials. In this research We tried to study about the flameretardancy (FR) of a corrugated cardboards using for Poly(vinyl alcohol) (PVA). The coating PVA on the cardboard is possible to be recyclable, because PVA has water solubility. Also the reason using PVA is to protect from the toxicity of flameretardant, which is used to the cardboards. We studied the FR-PVA for different with decomposition point of FR agent. We measured TGA and combustion test of the PVA. In the result, we could get the flameretardancy of PVA

Synthesis of submicron metastable phase of silicon using femtosecond laser-driven shock wave

We measured the grain size of metastable phase of Si synthesized by shock compression. We analyzed the crystalline structures of the femtosecond laser-driven shock compressed silicon with x-ray diffraction measurements. We found that submicron grains of metastable Si-VIII exist in the silicon. We suggest that the pressure loading time is too short for the nucleated high-pressure phases to grow in case of the femtosecond laser-driven shock compression, therefore Si-VIII grains of submicron size are obtained. We are expecting to discover other unique crystalline structures induced by the femtosecond laser-driven shock wave. © 2011 American Institute of Physics.Tsujino M., Sano T., Sakata O., et al, Journal of Applied Physics, 110, 12, 126103 (2011) https://doi.org/10.1063/1.3673591

Electrical Utilizations of Air Gap Region Formed on Superhydrophobic Silicone Rubber in NaCl Aqueous Solution

A uniform air gap was successfully formed on a superhydrophobic silicone rubber in water or NaCl aqueous solution. The main chain of Si–O bonds of a silicone rubber was photodissociated by a 193 nm ArF excimer laser to lower the molecular weight only in the laser-irradiated microareas; due to the volume expansion, the microswelling structure was periodically fabricated on a silicone rubber, showing the superhydrophobic property. A pair of metal needles were inserted in the air gap formed on the superhydrophobic silicone rubber in a NaCl aqueous solution; an electrical insulation between two metal needles in the air gap was demonstrated. Additionally, a droplet of NaCl aqueous solution was confined in the air gap, after which the pair of metal needles contacted with the droplet through the air gap. As a result, an electrolysis of the droplet of NaCl aqueous solution occurred to produce hydrogen gas on the cathode in the air gap. Moreover, when Al and Cu wires were provided across the air gap and NaCl aqueous solution on the superhydrophobic silicone rubber, approximately 0.8–0.9 V of electric voltage was successfully generated between the two wires in the air gap based on the difference in electrochemical potential as an energy harvesting device in the sea

Photochemical Micro-/Nano-Swelling of Silicone Rubber Induced by Long Pulse-Repetition Interval of an ArF Excimer Laser

Long pulse-repetition intervals of 100 to 500 ms of a 193 nm ArF excimer laser successfully increased the height of the photochemical micro-/nano-swelling of silicone rubber, observed with a scanning electron microscope. The effect of the interval was seen despite the heating of the silicone rubber to 80 °C during laser irradiation. The height of the micro-/nano-swelling was saturated when the laser pulse number was 300 or greater, although each of the saturated heights of the micro-/nano-swelling formed by several pulse-repetition intervals was different. Thus, a second ArF excimer laser irradiated the growing micro-/nano-swelling before the saturation; the saturated height of the growing micro-/nano-swelling could be controlled by the pulse-repetition interval of the second ArF excimer laser. To examine the process of micro-/nano-swelling, an early stage of the growth was observed using an atomic force microscope; a dent structure of the micro-/nano-swelling was clearly recognized. In addition, a needle-like structure of the micro-/nano-swelling could be formed when silica glass microspheres were sparsely aligned