The Impact of Drugs as Corrosion Inhibitors on Aluminum Alloy in Coastal-Acidified Medium

The use of corrosion inhibitors has proven to be one of the effective methods of corrosion protection of metals and alloys. Aluminum alloys are good candidate materials for structural components in major industrial application owing to their excellent corrosion resistance. However in high intensity coastal and acidified medium the challenge of micro porosity and hydrogen embrittlement distributed along the interface cannot be neglected as suitable corrosion inhibitive compounds is needful without significantly reacts with the environmental components. The challenges of most effective organic and inorganic Inhibitors when dissolved in aqueous environments are increasingly due to their toxicity. Drug as inhibitive compound have been seen as suitable replacement for this high toxic organic inhibitors since both react by adsorption on a metallic surface. They are usually compounds that form film and cause the formation of precipitates on the metal surface, thereby blocking both cathodic and anodic and sites. Therefore, this study covers the general overview of impact of some drugs as corrosion inhibitive compound on aluminum for industrial applications and their environmental impact

Effect of Alloying Element on the Integrity and Functionality of Aluminium-Based Alloy

Aluminum alloy are gaining huge industrial significance because of their outstanding combination of mechanical, physical and tribological properties over the base metal. Alloying elements are selected based on their individual properties as they impact on the structure and performance characteristics. The choice of this modifier affects the materials integrity in service resulting to improved corrosion, tribological and mechanical behavior. Hence, the need to understand typically the exact inoculants that could relatively impact on the low strength, unstable mechanical properties is envisage with the help of liquid stir casting technique. In this contribution, sufficient knowledge on Al alloy produced by stir casting will be reviewed with close attention on how the structural properties impact on the mechanical performance

Comparative Analysis and Performance Characteristics of Bio-Additives Induced Fuel Blend

Global demand for efficient transportation and energy dissipation in industries that use engine-powered equipment is enormous and largely supplied by liquid fuels derived from petroleum that power internal combustion engines (ICEs). Since the demand for jet fuel and diesel is anticipated to surpass gasoline consumption in the near future, low-octane gasoline components will become more widely available. As a result, low-octane gasoline components are expected to become more readily available, as demand for jet fuel and diesel is expected to outpace gasoline consumption in the near future. Experimentally, the effects of organic fuel additives (OFAs) on the performance of internal combustion engines were investigated. The findings compare plain, commercially available, neat gasoline samples to pure ethanol and fuel samples injected with OFAs. The development of various fuel blends; the analysis and characterization of fuel samples, including blended fuel samples; and the experimental investigation and comparative analysis of the engine performance powered by the various samples and blends of gasoline on the TQ TD115 MK11 testbed for single-cylinder engines were carried out in the study. The study demonstrated that the nanoadditions were superior to pure ethanol and undiluted gasoline in terms of performance. and showed that pure ethanol has a high torque value at lower speeds, but at speeds greater than 3000 rpm, D-NA outperformed ethanol additives and neat gasoline in terms of torque. At lower speeds, pure ethanol also had a high brake power value, but as speeds increased, samples containing D-NA outperformed ethanol additive and neat gasoline in brake power. Pure ethanol in a concentration of more than 3 has a high brake thermal efficiency value at lower speeds, but as speeds increased, samples containing D-NA outperformed ethanol additive and neat gasoline in terms of brake thermal efficienc

Equal Channel Angular Extrusion Characteristics on Mechanical Behavior of Aluminum Alloy

Materials strengthened by conventional methods such as strain hardening, solute additions, precipitation and grain size refinement are often adopted in industrial processes. But there is limitation to the amount of deformation that these conventional methods can impact to a material. This study focused on the review of major mechanical properties of aluminum alloys in the presence of an ultrafine grain size into polycrystalline materials by subjecting the metal to an intense plastic straining through simple shear without any corresponding change in the cross-sectional dimensions of the sample. The effect of the heavy strain rate on the microstructure of aluminum alloys was in refinement of the coarse grains into ultrafine grain size by introducing a high density of dislocations and subsequently re-arranging the dislocations to form an array of grain boundaries. Hence, this investigation is aimed at gathering contributions on the influence of equal channel angular extrusion toward improving the mechanical properties of the aluminum alloys through intense plastic strain

Exploration of the effect of Zn-MgO-UPP coating on hardness, corrosion resistance and microstructure properties of mild steel

This paper investigated the effect of unripe plantain peel (UPP) nanoparticles reinforced Zn-MgO composite coating on the hardness, anti-corrosion and microstructure properties of mild steel. The anti-corrosion characteristics of the coatings were examined using the potentiodynamic polarization method, employing 3.65 % NaCl solution as the test medium. The hardness of the coatings was studied employing the Brinell hardness technique, while the microstructure characteristics were examined using XRD and SEM/EDS. The results of the study revealed that the as-received mild steel sample exhibited the corrosion rate and hardness value of 8.6272 mm year-1 and 136.8 kgf mm-2, respectively, while the Zn-MgO co­ated mild steel sample exhibited a corrosion rate and hardness value of 3.6362 mm year-1 and 42.5 kgf mm-2, respectively. The optimal performing Zn-MgO-UPP coated mild steel sample (sample coated with 20 g L-1 of MgO and 6 g L-1 of UPP) exhibited a corrosion rate and hardness value of 0.8317 mm year-1 and 245.8 kgf mm-2, respectively. The corrosion rate and hardness value of the Zn-20MgO-6UPP coated mild steel sample indicated that the UPP nanoparticles further improved the passivating and strengthening ability of Zn-MgO coating. Moreover, the XRD profile of the coatings possessed high intensities, which indi­cat­ed that the coatings exhibit microstructural and chemical homogeneity, high stability and good texture. It was observed on the SEM micrographs that the Zn-MgO-UPP coating exhi­bited a more refined microstructure compared to the Zn-MgO coating, indicating the grain refining tendency of the UPP nanoparticles. The EDS further indicated the presence of essential and dispersion strengthening elements in the coatings

In-situ formation characteristic, tribological characterization and anti-corrosion properties of quaternary composites films

Improvements of wear and corrosion properties are essential characteristic in engineering application. A study was made on the structure, electro-oxidation and properties of fabricated Z

Synthesis of PET-Magnesium Oxide-Chitosan Nanocomposite Membranes for the Dehydration of Natural Gas

Flat thin-film magnesium oxide-chitosan nanocomposite membranes were synthesized with polyethylene terephthalate (PET) and employed for natural gas dehydration. The water vapor permeation was most pronounced with a nanocomposite membrane doped with 0.9 g MgO nanoparticles (NP) as a result of a significant upsurge in the permeability of water vapor in the membrane (0.87). With the increase in MgO NP, large macro-voids are created, substratum pore size, and thickness together with the water vapor permeation were upsurged. The dehydration of natural gas performance of magnesium oxide-chitosan nanocomposite membranes synthesized with PET was enhanced with the increase in MgO NP embedded in the membrane. Though water vapor permeation was restricted by the polyester non-woven material used as a support for the nano composite membranes, as the three membranes did not reach the permeation coefficient of 1. However, the permeation coefficient increased with an increased MgO NP, with three mambrane samples (M1, M2 and M3) having permeation coefficient of 0.763, 0.77 and 0.87 respectively. The gas reduced with an increase MgO NP, with M1, M2 and M3 having 3.46×10−2, 3.17×10−2 and 3.88×10−3 kg/m3 respectively. From the adsorption study, the discrepancy observed between CH4 and vapor with isotherm models was ascribed to the different adsorption behavior of CH4 and vapor on the membrane-active area. The cost of making the membrane cannot be considered as a terminal criterion because most of the cost-effective option is not always the optimum one. The membranes confirmed their suitability for the dehydration of natural gas

Corrosion Resistance of AA6063-Type Al-Mg-Si Alloy by Silicon Carbide in Sodium Chloride Solution for Marine Application

The present work focused on corrosion inhibition of AA6063 type Al-Mg-Si alloy in sodium chloride (NaCl) solution with a silicon carbide inhibitor, using the potentiodynamic electrochemical method. The aluminium alloy surface morphology was examined, in the as-received and as-corroded in the un-inhibited state, with scanning electron microscopy equipped with energy dispersive spectroscopy (SEM-EDS). The results obtained via linear polarization indicated a high corrosion potential for the unprotected as-received alloy. Equally, inhibition efficiency as high as 98.82% at 10.0 g/v silicon carbide addition was obtained with increased polarization resistance (Rp), while the current density reduced significantly for inhibited samples compared to the un-inhibited aluminium alloy. The adsorption mechanism of the inhibitor aluminium alloy follows the Langmuir adsorption isotherm. This shows that the corrosion rate of aluminium alloy with silicon carbide in NaCl environment decreased significantly with addition of the inhibito

Effect of functional composite coating developed via sulphate and chloride process parameter on the UNS G10150 steel for structural and wear mitigation in defence application

The major engineering challenge of materials in defence technologies is the vulnerability of based metals to structural and wears deformation in service. In this paper, structural formation, mechanical and thermal stability behavior of developed composite coating of Zn-30Al-7%Ti/Sn chloride bath and Zn-30Al-7%Ti/Sn sulphate bath was investigated and compared to provide mitigation against failure. The thermal ageing property was done for 2 h at 600 °C via isothermal furnace. The structural, interfacial effect and stability behaviors of the co-deposited alloys were evaluated using scanning electron microscope equipped with energy dispersive spectrometer (SEM/EDS), atomic force microscope (AFM) and X-ray diffractometer (XRD). The hardness and wear properties of the deposited coatings were examined with diamond base micro-hardness tester and reciprocating sliding tester respectively. The result shows that Zn-30Al-7%Ti/Sn sulphate co-deposition contributed to increase hardness and wear resistance than Zn-30Al-7%Ti/Sn chloride bath alloy. The stable crystal growth and significant performance of Zn-30Al-7%Ti/Sn sulphate are link to the intermetallic phase hybrid of ZnAl, Zn4TiAl2, Zn3AlTi. Besides, it was observed that Zn-30Al-7%Ti/Sn sulphate has excellent thermomechanical stability at harsh temperature, due to the deposition of Sn/Ti on steel; leading to formation of super-hard interface. However, it was established that co-deposition of mild steel with Zn-30Al-7%Ti/Sn in sulphate bath significantly improved the structural and wear performance. It was shown that the hardness and wear of the developed composite Zn-30Al-7%Ti/Sn is increased by about 80% compared to as received sample and about 25% compared with Zn-30Al-7%Ti/Sn chloride coating developed. The improvement was proved to be an interference of zinc-composite growth. Thus, this work shows that sulphate induced Zn-30Al-7%Ti/Sn via generation of controllable process parameter can provide significant improvements in thin film coating for wear mitigation and structural improvement in defence application. Keywords: Reinforced particulates, Mechanical behaviour, Tribology, Mildsteel, Electrodepositio

Data on the optimized sulphate electrolyte zinc rich coating produced through in-situ variation of process parameters

In this study, a comprehensive effect of particle loading and optimised process parameter on the developed zinc electrolyte was presented. The depositions were performed between 10–30 min at a stirring rate of 200 rpm at room temperature of 30 °C. The effect of coating difference on the properties and interfacial surface was acquired, at a voltage interval between 0.6 and 1.0 V for the coating duration. The framework of bath condition as it influences the coating thickness was put into consideration. Hence, the electrodeposition data for coating thickness, and coating per unit area at constant distance between the anode and cathode with depth of immersion were acquired. The weight gained under varying coating parameter were acquired and could be used for designing and given typical direction to multifunctional performance of developed multifacetal coatings in surface engineering application. Keywords: Coating thickness, Weight gained, Sulphate electrolyte, Voltage, Microhardnes