Precise U-Pb mineral ages, Rb-Sr and Sm-Nd systematics for the Great Dyke, Zimbabwe - constraints on late Archean events in the Zimbabwe craton and Limpopo belt

U–Pb dating of zircon and rutile from bronzitites of the P1 pyroxenite layer of the Great Dyke precisely constrains the crystallization age of this part of the intrusion to 2575.4±0.7 Ma. Whole rock Rb–Sr and Sm–Nd data of various rock types sampled along the entire length of the Great Dyke record inhomogeneous initial isotope ratios, and also later (<1.5 Ga) disturbances of the Rb–Sr and Sm–Nd isotope systems. The 2575.4±0.7 Ma emplacement age of the Great Dyke is ≈120 Ma older than assumed until recently, and calls for new interpretations of the crustal development of the Zimbabwe craton. Close temporal links between the intrusion of the Great Dyke and the emplacement of late Archean granitoids (Chilimanzi and Razi suites) of the Zimbabwe craton are indicated by the new precise age data. The Chilimanzi and Razi suites of granitoids form at least two sub-suites, which can be described as pre- and post-Great Dyke in age. The Great Dyke age now falls within the range of ages for tectonic events in the Limpopo belt including granitoid magmatism, metamorphism, and thrusting of the Northern Marginal Zone over the Zimbabwe craton. A west-to-east diachroneity in both thrusting and crustal stabilization is suggested by the observations that the Great Dyke cuts across the thrust in the west, but syn-tectonic granitoids that are younger than the Great Dyke are deformed by the thrusting in the east. Intrusion of the Great Dyke cannot be linked to collision of the Zimbabwe and Kaapvaal cratons. The overlap in ages of intrusion of the Great Dyke and late Archean events in the Zimbabwe craton shows that Archean crust was cratonized shortly after large-scale melting and granite intrusion

Gold mineralization in the Mazowe area, Harare-Bindura-Shamva greenstone belt, Zimbabwe: II. Genetic relationships deduced from mineralogical, fluid inclusion and stable isotope studies, and the Sm-Nd isotopic composition of scheelites

In the Mazowe area some 40 km NW of Harare in Zimbabwe, gold mineralization is hosted in a variety of lithologies of the Archean Harare-Bindura-Shamva greenstone belt, in structures related to the late Archean regional D2/3 event. Conspicuous mineralzogical differences exist between the mines; the mainly granodiorite-hosted workings at Mazowe mine are on pyrite-rich reefs, mines of the Bernheim group have metabasalt host rocks and are characterized by arsenopyrite-rich ores, and Stori's Golden Shaft and Alice mine, both in metabasalts, work sulfide-poor quartz veins. In contrast to the mineralogical diversity, near-identical fluid inventories were found at the different mines. Both H2O-CO2-CH4 fluids of low salinity, and highly saline fluids are present and are regarded to indicate fluid mixing during the formation of the deposits. Notably, these fluid compositions in the Mazowe gold field markedly contrast to ore fluids “typical” of Archean mesothermal gold deposits on other cratons. Stable isotope compositions of quartz from the various deposits (δ18O=10.8 to 13.2‰ SMOW), calcite (δ18O=9.5 to 11.9‰ SMOW and δ13C=−3.2 to −8.0‰ PDB), inclusion water (δD=−28 to −40‰ SMOW) and sulfides (δ34S=1.3 to 3.2‰ CDT) are uniform within the range typical for Archean lode gold deposits worldwide. The fluid and stable isotope compositions support the statement that the mineralization in the Mazowe gold field formed from relatively reduced fluids with a “metamorphic” signature during a single event of gold mineralization. Microthermometric data further indicate that the deposits formed in the PT range of 1.65–2.3 kbar and 250–380 °C. Ages obtained by using the Sm/Nd and Rb/Sr isotope systems on scheelites are 2604 ± 84 Ma for the mineralization at Stori's Golden Shaft mine, and 2.40 ± 0.20 Ga for Mazowe mine. The Archean age at Stori's is regarded as close to the true age of gold mineralization in the area, whereas the Proterozoic age at Mazowe mine probably reflects later resetting

The age and petrology of the Chimbadzi Hill Intrusion, NW Zimbabwe: first evidence for early Paleoproterozoic magmatism in Zimbabwe

The mafic-ultramafic Chimbadzi Hill intrusion in the NW of the Zimbabwe craton is a dyke with inward-dipping margins comprising magnetite peridotite, troctolite and magnetite melatroctolite. The magnetite peridotite is composed of about equal amounts of V- and Ti-bearing magnetite and olivine (∼Fo60). The troctolite is composed of about 50% olivine (∼Fo50-54), 40% plagioclase (An53-58), 7% clinopyroxene and minor apatite and magnetite with ilmenite lamellae. Geochemical trends suggest that the Chimbadzi Hill Intrusion formed by fractional crystallisation from a single initial magma. However, the more primitive magnetite peridotite overlies the more evolved troctolite in the intrusion. This ‘apparent’ inverted stratigraphy may be due to emptying of a fractionated magma chamber from the top, or to floor subsidence during intrusion. U–Pb dating on baddeleyite reveals that the age of the Chimbadzi Hill Intrusion is 2262 ± 2 Ma. This age does not correspond to any known tectono-thermal event in the Zimbabwe Craton or adjacent metamorphic belts. It is ∼300 Ma younger than the late Archean Great Dyke, and ∼230 Ma older than other Paleoproterozoic events in and around the craton. Therefore, it may represent a so far undocumented very early Proterozoic igneous event in the Zimbabwe Craton. The intrusion represents a vanadium resource for Zimbabwe, with titanium potentially being mined as by-product

Genetic control of quantitative grain and malt quality traits in barley

Many of the important determinants of barley grain and malt quality exhibit quantitative variation and are affected by both genetic and environmental factors. In recent years, the application of molecular marker techniques has permitted the detection and mapping of quantitative trait loci (QTL) for grain and malt quality traits in many populations. Here, the quantitative traits affecting the grain and malt quality of barley grain are reviewed, and results from two analyses of grain and malt quality data from barley mapping populations (a multi-variate analysis of interrelationships among traits and a comparative analysis of QTL positions and effects among five populations) are presented and discussed.E. Igartua, P. M. Hayes, W. T. B. Thomas, R. Meyer & D. E. Mathe