64 research outputs found
Fully protonated B-type hexamolybdoplatinate [H6PtMo6O24]2− and its adduct formation with [Pt(OH)6]2−
No full textThe crystral structure of tris(tetra-n-butylammonium) hydrogen hexahydroxidoplatinate(IV) [hexahydrogen α-hexamolybdoplatinate(IV)] pentadecahydrate, (C16H36N)3H[Pt(OH)6][H6PtMo6O24]·15H2O, was determined. The structural analysis revealed that all six triply-bridging O atoms of the hexamolybdoplatinate(IV) anion are protonated, making it formally the B-type Anderson anion [H6PtMo6O24]2−. The [H6PtMo6O24]2− anions connect with the [Pt(OH)6]2− anions through strong hydrogen bonds (O...O = 2.45–2.62 Å) to form a linear polymer in the crystal
Guest driven rearrangements of protonation and hydrogen bonding in decavanadate anions as their tetraalkylammonium salts
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[(IMo<SUB>7</SUB>O<SUB>26</SUB>)<SUB>2</SUB>]<SUP>6-</SUP>: A Missing Link between Molecular and Solid Oxides
No full textPhotoluminescence Properties and Crystal Structure of K_3_Na_4_H_2_[TbW_10_O_36_].20H_2_O
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Crystal Structure Analysis of a Hexatungstate by a High-Energy X-ray Diffraction Experiment Using an Imaging Plate Weissenberg Camera at the BL04B2 Beamline of SPring-8
No full textSynchrotron structure determination of an α-Keggin doubly Pt<SUP>IV</SUP>-substituted silicotungstate, (CH<SUB>6</SUB>N<SUB>3</SUB>)<SUB>8</SUB>[α-SiPt<SUB>2</SUB>W<SUB>10</SUB>O<SUB>40</SUB>].6H<SUB>2</SUB>O
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