5 research outputs found

    Tetra-n-butyl­ammonium bis­(1,1-dicyano­ethyl­ene-2,2-dithiol­ato)platinum(II)

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    In the title compound, (C16H36N)2[Pt(C4N2S2)2], the PtII center adopts a distorted square-planar geometry due to the 4-membered chelate rings formed by coordination to the S atoms of the 1,1-dicyano­ethyl­ene-2,2-dithiol­ate (i-mnt) ligands [bite angle 74.35 (4)°]. The bond distances in the coordinated i-mnt ligands indicate some delocalization of the π-system

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    Tetra-n-butylammonium bis(2,2-dicyanoethylene-1,1-dithiolato)palladium(II)

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    In the title compound, (C16H36N)2[Pd(C4N2S2)2], the PdII center adopts a distorted square-planar geometry due to the four-membered chelate rings formed by coordination of the 2,2-dicyanoethylene-1,1-dithiolate (i-mnt) ligands [bite angle 75.0159 (17)°]. The bond distances in the coordinated i-mnt ligands indicate some delocalization of the π-system
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