310 research outputs found

    Forgiveness Motives Among Evangelical Christians: Implications for Christian Marriage and Family Therapists

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    Therapists and researchers interested in forgiveness can learn from those who have experienced interpersonal wounds and have chosen to forgive. We interviewed 20 evangelical Christian forgivers, asking about motives for forgiveness. Transcripts were analyzed using qualitative methods. Five categories of motivation are presented: comfort, duty, relational, humility/empathy, and Christian beliefs. Respondents described multiple motives for forgiveness, often combining a desire for comfort or a sense of duty with their Christian beliefs. Four implications for Christian marriage and family therapists are discussed: Expect diversity, avoid moralistic views of motives, remember religious resources in the forgiveness process, and expect benefits, but not immediately

    Exciton Energy Transfer in Pairs of Single-Walled Carbon Nanotubes

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    We studied the exciton energy transfer in pairs of semiconducting nanotubes using high-resolution optical microscopy and spectroscopy on the nanoscale. Photoluminescence from large band gap nanotubes within bundles is observed with spatially varying intensities due to distance-dependent internanotube transfer. The range of efficient energy transfer is found to be limited to a few nanometers because of competing fast nonradiative relaxation responsible for low photoluminescence quantum yield

    Visualizing the Local Optical Response of Semiconducting Carbon Nanotubes to DNA-Wrapping

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    We studied the local optical response of semiconducting single-walled carbon nanotubes to wrapping by DNA segments using high resolution tip-enhanced near-field microscopy. Photoluminescence (PL) near-field images of single nanotubes reveal large DNA-wrapping-induced red shifts of the exciton energy that are two times higher than indicated by spatially averaging confocal microscopy. Near-field PL spectra taken along nanotubes feature two distinct PL bands resulting from DNA-wrapped and unwrapped nanotube segments. The transition between the two energy levels occurs on a length scale smaller than our spatial resolution of about 15 nm

    EC-FORC: A New Cyclic Voltammetry Based Method for Examining Phase Transitions and Predicting Equilibrium

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    We propose a new, cyclic-voltammetry based experimental technique that can not only differentiate between discontinuous and continuous phase transitions in an adsorbate layer, but also quite accurately recover equilibrium behavior from dynamic analysis of systems with a continuous phase transition. The Electrochemical first-order reversal curve (EC-FORC) diagram for a discontinuous phase transition (nucleation and growth), such as occurs in underpotential deposition, is characterized by a negative region, while such a region does not exist for a continuous phase transition, such as occurs in the electrosorption of Br on Ag(100). Moreover, for systems with a continuous phase transition, the minima of the individual EC-FORCs trace the equilibrium curve, even at very high scan rates. Since obtaining experimental data for the EC-FORC method would require only a simple reprogramming of the potentiostat used in conventional cyclic-voltammetry experiments, we believe that this method has significant potential for easy, rapid, in-situ analysis of systems undergoing electrochemical deposition.Comment: 8 pages, 4 figures, 211th ECS Meetin
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