Dispersive Gap Mode of Phonons in Anisotropic Superconductors

We estimate the effect of the superconducting gap anisotropy in the dispersive gap mode of phonons, which is observed by the neutron scattering on borocarbide superconductors. We numerically analyze the phonon spectrum considering the electron-phonon coupling, and examine contributions coming from the gap suppression and the sign change of the pairing function on the Fermi surface. When the sign of the pairing function is changed by the nesting translation, the gap mode does not appear. We also discuss the suppression of the phonon softening of the Kohn anomaly due to the onset of superconductivity. We demonstrate that observation of the gap dispersive mode is useful for sorting out the underlying superconducting pairing function.Comment: 7 pages, 12 figures, to be published in J. Phys. Soc. Jp

Charge-Stripe Order and Superconductivity in Ir1−xPtxTe2\mathrm{Ir_{1-x}Pt_xTe_2}

A combined resistivity and hard x-ray diffraction study of superconductivity and charge ordering in $\mathrm{Ir_{1-x}Pt_xTe_2}$, as a function of Pt substitution and externally applied hydrostatic pressure, is presented. Experiments are focused on samples near the critical composition $x_c\sim 0.045$ where competition and switching between charge order and superconductivity is established. We show that charge order as a function of pressure in $\mathrm{Ir_{0.95}Pt_{0.05}Te_{2}}$ is preempted - and hence triggered - by a structural transition. Charge ordering appears uniaxially along the short crystallographic (1,0,1) domain axis with a $\mathrm{(\frac{1}{5},0,\frac{1}{5})}$ modulation. Based on these results we draw a charge-order phase diagram and discuss the relation between stripe ordering and superconductivity.Comment: 8 pages, 4 figures: Accepted in Scientific Report

Hole Localization in Underdoped Superconducting Cuprates Near 1/8th Doping

Measurements of thermal conductivity versus temperature over a broad range of doping in YBa$_2$Cu$_3$O$_{6+x}$ and HgBa$_2$Ca$_{n-1}$Cu$_n$O$_{2n+2+\delta}$ ($n$=1,2,3) suggest that small domains of localized holes develop for hole concentrations near $p$=1/8. The data imply a mechanism for localization that is intrinsic to the CuO$_2$-planes and is enhanced via pinning associated with oxygen-vacancy clusters.Comment: 4 pages, 4 eps fig.'s, to be published, Phys. Rev.

Anisotropic spin freezing in the S=1/2 zigzag ladder compound SrCuO2

Using magnetic neutron scattering we characterize an unusual low temperature phase in orthorhombic SrCuO2. The material contains zigzag spin ladders formed by pairs of S=1/2 chains (J=180 meV) coupled through a weak frustrated interaction |J'|<0.1J. At T<Tc1=5.0(4)K an elastic peak develops in a gapless magnetic excitation spectrum indicating spin freezing on a time scale larger than 200 picoseconds. While the frozen state has long range commensurate antiferromagnetic order along the chains with the correlation length exceeding 200 lattice periods along the c-axis and a substantial correlation length of 60(25) spacings along the a-axis perpendicular to the zigzag plane, only 2 lattice units are correlated along the b-axis which is the direction of the frustrated interactions. The frozen magnetic moment of each Cu ion is very small, 0.033(7) Bohr magneton even at T=0.35K, and has unusual temperature dependence with a cusp at Tc2=1.5K reminiscent of a phase transition. We argue that slow dynamics of stripe-like cooperative magnetic defects in tetragonal a-c planes yield this anisotropic frozen state.Comment: 4 pages, LaTeX, submitted to PR

Structural instability associated with the tilting of CuO6 octahedra in La2-xSrxCuO4

Comprehensive inelastic neutron-scattering measurements were performed to study the soft optical phonons in La2-xSrxCuO4 at x=0.10, 0.12 and 0.18. We found at x=0.18 that the softening of Z-point phonon, suggesting incipient structural transition from the low-temperature orthorhombic (LTO) to low-temperature tetragonal (LTT) phase, breaks at Tc, which is consistent with the previous report by Lee et al. for the optimally doped x=0.15 sample. As for x=0.10 and 0.12, on the other hand, the softening continues even below Tc. It is thus clarified that the breaking of soft phonon is characteristic of La2-xSrxCuO4 in the optimally and overdoped regions. In the course of studying the soft phonons, we discovered that a central peak remains above the LTO to high-temperature tetragonal (HTT) phase transition at Ts1 and splits into incommensurate components along the (1 1 0)HTT direction at higher temperatures. This is a common feature for both x=0.12 and 0.18 and their temperature dependences of the splitting 2d can be scaled by using a renormalized temperature T/Ts1. In the high temperature limit, d saturates around d ~ 0.12 r.l.u., which value is close to the splitting of incommensurate magnetic signals. This implies that the incipient lattice modulation starts appearing at very high temperature. Details of this modulation and its relations with other properties are, however, not yet clarified.Comment: 7 pages, 5 eps figure

Magnetic Field Dependence of Electronic Specific Heat in Pr_{1.85} Ce_{0.15} CuO_4

The specific heat of electron-doped Pr_{1.85} Ce_{0.15} CuO_4 single crystals is reported for the temperature range 2 - 10 K and magnetic field range 0 - 10 T. A non-linear magnetic field dependence is observed for the field range 0 - 2 T. Our data supports a model with lines of nodes in the gap function of these superconductors. Theoretical calculations of the electronic specific heat for dirty d-wave, clean d-wave, and s-wave symmetries are compared to our data.Comment: 10 pages Latex and 4 eps figures, submitted to Phys. Rev.

Specific Heat Study of the Magnetic Superconductor HoNi2B2C

The complex magnetic transitions and superconductivity of HoNi2B2C were studied via the dependence of the heat capacity on temperature and in-plane field angle. We provide an extended, comprehensive magnetic phase diagram for B // [100] and B // [110] based on the thermodynamic measurements. Three magnetic transitions and the superconducting transition were clearly observed. The 5.2 K transition (T_{N}) shows a hysteresis with temperature, indicating the first order nature of the transition at B=0 T. The 6 K transition (T_{M}), namely the onset of the long-range ordering, displays a dramatic in-plane anisotropy: T_{M} increases with increasing magnetic field for B // [100] while it decreases with increasing field for B // [110]. The anomalous anisotropy in T_{M} indicates that the transition is related to the a-axis spiral structure. The 5.5 K transition (T^{*}) shows similar behavior to the 5.2 K transition, i.e., a small in-plane anisotropy and scaling with Ising model. This last transition is ascribed to the change from a^{*} dominant phase to c^{*} dominant phase.Comment: 9 pages, 11 figure

Thermal Conductivity across the Phase Diagram of Cuprates: Low-Energy Quasiparticles and Doping Dependence of the Superconducting Gap

Heat transport in the cuprate superconductors YBa$_2$Cu$_3$O$_{y}$ and La$_{2-x}$Sr$_x$CuO$_4$ was measured at low temperatures as a function of doping. A residual linear term kappa_{0}/T is observed throughout the superconducting region and it decreases steadily as the Mott insulator is approached from the overdoped regime. The low-energy quasiparticle gap extracted from kappa_{0}/T is seen to scale closely with the pseudogap. The ubiquitous presence of nodes and the tracking of the pseudogap shows that the overall gap remains of the pure d-wave form throughout the phase diagram, which excludes the possibility of a complex component (ix) appearing at a putative quantum phase transition and argues against a non-superconducting origin to the pseudogap. A comparison with superfluid density measurements reveals that the quasiparticle effective charge is weakly dependent on doping and close to unity.Comment: 12 pages, 9 figure

Acid epimerization of 20-keto pregnane glycosides is determined by 2D-NMR spectroscopy

Carbohydrates influence many essential biological events such as apoptosis, differentiation, tumor metastasis, cancer, neurobiology, immunology, development, host-pathogen interactions, diabetes, signal transduction, protein folding, and many other contexts. We now report on the structure determination of pregnane glycosides isolated from the aerial parts of Ceropegia fusca Bolle (Asclepiadaceae). The observation of cicatrizant, vulnerary and cytostatic activities in some humans and animals of Ceropegia fusca Bolle, a species endemic to the Canary Islands, encouraged us to begin a pharmacological study to determine their exact therapeutic properties. High resolution 1H-NMR spectra of pregnane glycosides very often display well-resolved signals that can be used as starting points in several selective NMR experiments to study scalar (J coupling), and dipolar (NOE) interactions. ROESY is especially suited for molecules such that ωτc ~ 1, where τc are the motional correlation times and ω is the angular frequency. In these cases the NOE is nearly zero, while the rotating-frame Overhauser effect spectroscopy (ROESY) is always positive and increases monotonically for increasing values of τc. The ROESY shows dipolar interactions cross peaks even in medium-sized molecules which are helpful in unambiguous assignment of all the interglycosidic linkages. Selective excitation was carried out using a double pulsed-field gradient spin-echo sequence (DPFGSE) in which 180° Gaussian pulses are sandwiched between sine shaped z-gradients. Scalar interactions were studied by homonuclear DPFGSE-COSY and DPFGSE-TOCSY experiments, while DPFGSE-ROESY was used to monitor the spatial environment of the selectively excited proton. Dipolar interactions between nuclei close in space can be detected by the 1D GROESY experiment, which is a one-dimensional counterpart of the 2D ROESY method. The C-12 and C-17 configurations were determined by ROESY experiments