High-energy, curable polycyclopentadiene binder for solid rocket propellants

Diels Alder polymerization of cyclopentadiene ( CPD ) has been carried out at 170°C under inert atmosphere. The resulted polymer has a low bulk viscosity, 7.4 cps, and a number average molecular weight Mn up to 3000. This liquid Prepolymer is curable with maleic anhydride. With ammonium perchlorate, aluminum, and maleic anhydride, a high energy solid propellant has been formulated with this polymer. Via bomb calorimeter, Instron, and density measurement, it was found that this propellant has a better heat of combustion, tensile strength, and solid loading than that of the commercial rocket propellant based on hydroxyl terminated polybutadiene

A constitutive model for particulate-reinforced titanium matrix composites subjected to high strain rates and high temperatures

Quasi-static and dynamic tension tests were conducted to study the mechanical properties of particulate-reinforced titanium matrix composites at strain rates ranging from 0.0001/s to 1000/s and at temperatures ranging from 20 °C to 650 °C Based on the experimental results, a constitutive model, which considers the effects of strain rate and temperature on hot deformation behavior, was proposed for particulate-reinforced titanium matrix composites subjected to high strain rates and high temperatures by using Zener-Hollomon equations including Arrhenius terms. All the material constants used in the model were identified by fitting Zener-Hollomon equations against the experimental results. By comparison of theoretical predictions presented by the model with experimental results, a good agreement was achieved, which indicates that this constitutive model can give an accurate and precise estimate for high temperature flow stress for the studied titanium matrix composites and can be used for numerical simulations of hot deformation behavior of the composites

Biomimetic Polymer Film with Brilliant Brightness Using a One‐Step Water Vapor–Induced Phase Separation Method

The scales of the white Cyphochilus beetles are endowed with unusual whiteness arising from the exceptional scattering efficiency of their disordered ultrastructure optimized through millions of years of evolution. Here, a simple, one‐step method based on water vapor–induced phase separation is developed to prepare thin polystyrene films with similar microstructure and comparable optical performance. A typical biomimetic 3.5 µm PS film exhibits a diffuse reflectance of 61% at 500 nm wavelength, which translates into a transport mean free path below 1 µm. A complete optical characterization through Monte Carlo simulations reveals how such a scattering performance arises from the scattering coefficient and scattering anisotropy, whose interplay provides insight into the morphological properties of the material. The potential of bright‐white coatings as smart sensors or wearable devices is highlighted using a treated 3.5 µm film as a real‐time sensor for human exhalation

The extended BLMSSM with a 125 GeV Higgs boson and dark matter

To extend the BLMSSM, we not only add exotic Higgs superfields $(\Phi_{NL},\varphi_{NL})$ to make the exotic lepton heavy, but also introduce the superfields($Y$,$Y^\prime$) having couplings with lepton and exotic lepton at tree level. The obtained model is called as EBLMSSM, which has difference from BLMSSM especially for the exotic slepton(lepton) and exotic sneutrino(neutrino). We deduce the mass matrices and the needed couplings in this model. To confine the parameter space, the Higgs boson mass $m_{h^0}$ and the processes $h^0\rightarrow \gamma\gamma$, $h^0\rightarrow VV, V=(Z,W)$ are studied in the EBLMSSM. With the assumed parameter space, we obtain reasonable numerical results according to data on Higgs from ATLAS and CMS. As a cold dark mater candidate, the relic density for the lightest mass eigenstate of $Y$ and $Y'$ mixing is also studied