7 research outputs found
Triple oxygen isotope variations in magnetite from iron-oxide deposits, central Iran, record magmatic fluid interaction with evaporite and carbonate host rocks
Oxygen isotope ratios in magnetite can be used to study the origin of iron-oxide ore deposits.
In previous studies, only 18O/16O ratios of magnetite were determined. Here, we report triple
O isotope data (17O/16O and 18O/16O ratios) of magnetite from the iron-oxide-apatite (IOA)
deposits of the Yazd and Sirjan areas in central Iran. In contrast to previous interpretations of
magnetite from similar deposits, the triple O isotope data show that only a few of the magnetite
samples potentially record isotopic equilibrium with magma or with pristine magmatic water
(H2O). Instead, the data can be explained if magnetite had exchanged O isotopes with fluids
that had a mass-independently fractionated O isotope composition (i.e., MIF-O), and with
fluids that had exchanged O isotopes with marine sedimentary carbonate rocks. The MIF-O
signature of the fluids was likely obtained by isotope exchange with evaporite rocks of early
Cambrian age that are associated with the IOA deposits in central Iran. In order to explain
the triple O isotope composition of the magnetite samples in conjunction with available iron
isotope data for magnetite from the deposits, we propose that magnetite formed from magmatic fluids that had interacted with evaporite and carbonate rocks at high temperatures and
at variable water/rock ratios; e.g., magmatic fluids that had been released into the country
rocks of a magma reservoir. Additionally, the magnetite could have formed from magmatic
fluids that had exchanged O isotopes with SO2 and CO2 that, in turn, had been derived by the
magmatic assimilation and/or metamorphic breakdown of evaporite and carbonate rocks
Mineral chemistry and petrogenesis of the Gurgur Mount volcanic rocks (Northeast Takab)
Andesitic and andesitic-basaltic lavas are widespread over most of the ground surface of the Gurgur area altered mostly by the hydrothermal solutions. The main rock forming minerals in these rocks are plagioclase, pyroxene and olivine affected by the hydrothermal solutions. The altered rocks do contain minerals including calcite, sericite and chlorite. Given the results obtained and the mineral chemistry studies, the clinopyroxenes formed in the area are, chemically, calkalkaline and of diopside-augite type formed in subvolcanic to near surface levels contemporaneous with magma ascending. Plagioclase minerals show zoning textures and lie within the two andesine and albite-oligoclase fields. These units, in terms of total rock chemistry, are classified as the calk-alkaline volcanic rocks formed in the continental arcs. On the other hand, on the trace elements chondrite-normalized diagrams and enriched mantle-normalized multi- element diagrams, the LREE enrichment relative to the HREE is observed. The LILE (i.e. Rb, K and Th) and the LREE (e.g. La, Ce and Nd) show an enrichment in comparison to the HFSE (Zr, Hf, Nb, Yb, Y and Sm). Given the Nd/Th (1.42-1.15), Zr/Nb (12.27-21.22), Ba/La (18.64-29.77) as well as LILE enrichment associated with depletion in Nb, Ta and Ti, an environment related to the subduction zones can be proposed for the area under study. Moreover, the similarity between the REE distribution pattern and the incompatible elements point to the genetic relationship between these rocks. Finally, on the base of the obtained data, it can be concluded that the volcanic rocks in the Gurgur Mountain were likely formed during the extended magmatism of the Urumieh-Dokhtar in the Cenozoic
A Computational Method for Selecting Short Peptide Sequences for Inorganic Material Binding
Triple oxygen isotope variations in magnetite from iron-oxide deposits, central Iran, record magmatic fluid interaction with evaporite and carbonate host rocks Reply
Zircon U–Pb ages and Sr–Nd–Pb–Hf isotopic compositions constrain the tectono-magmatic evolution of the Anomaly 21-A iron ore region, Bafq metallogenic province, Central Iran
The late Proterozoic - early Paleozoic tectono-magmatic evolution of Central Iran is considered to be a result of
subduction of the Proto-Tethys Ocean and the amalgamation of Gondwana continental fragments. Here, we
present whole-rock geochemistry, Sr-Nd-Pb isotopes and zircon U-Pb-Hf data for monzonite to quartz monzonite
from deep drill core in the area of the Iron Anomaly 21-A, Bafq metallogenic province of Central Iran, to decipher
the petrogenetic evolution of the mantle during late Proterozoic–early Paleozoic times. The plutonic rocks
display enrichment in large-ion lithophile elements (Rb, Ba, K, and Cs), and depletion in high-field-strength
elements (Nb, Ta, Ti), typical of continental arcs. Zircon U-Pb ages of the studied rocks are in the range of
474–512 Ma, which is consistent with the general consensus on the age of the Cadomian basement of Central
Iran, and the culmination of subduction along northern Gondwana in the early Paleozoic. The isotopic signatures
of the samples, e.g., (87Sr/86Sr)i = 0.706 to 0.718, εNd(t) = -3.3 to +1.8, (206Pb/204Pb)i = 18.87 to 20.32,
(207Pb/204Pb)i = 15.72 to 15.84, (208Pb/204Pb)i = 40.74 to 42.32, and εHf(t) = -4.7 to +11.6, cover a compositional
range of mantle-derived melts with variable degree of contamination by Neoproterozoic continental
crust. A setting of back-arc continental rifting is envisaged for the late Neoproterozoic to early Paleozoic magmatism
in the Bafq province