8 research outputs found
dermatological emulsion and method for the preparation thereof
A foaming gelled composition in the form of a stable oil-in-water microemulsion comprising a fatty phase of microdroplets dispersed in an aqueous phase and a dermatological active ingredient, characterized in that it comprises a surfactant sytem comprising : -at least one ethoxylated nonionic surfactant;-at least one cosurfactant for stabilizing the ethoxylated nonionic surfactant;-at least one nonethoxylated hydrophilic nonionic surfactant;-at least one foaming agent chosen from the group of anionic surfactant
Le soleil (photoprotection et méthodes de détermination in vitro du facteur de protection solaire)
MONTPELLIER-BU Pharmacie (341722105) / SudocSudocFranceF
Utilisation de la Toxine botulique à des fins esthétiques
MONTPELLIER-BU Pharmacie (341722105) / SudocPARIS-BIUP (751062107) / SudocSudocFranceF
Microémulsions et émulsions submicroniques (utilisations en cosmétique)
MONTPELLIER-BU Pharmacie (341722105) / SudocPARIS-BIUP (751062107) / SudocSudocFranceF
Contribution Ă l'Ă©tude des alkyls glucosides formulation d'Ă©mulsions submicroniques
MONTPELLIER-BU Pharmacie (341722105) / SudocSudocFranceF
Cellulite (formulation d'une crème amincissante)
MONTPELLIER-BU Pharmacie (341722105) / SudocPARIS-BIUP (751062107) / SudocSudocFranceF
Synthesis of Polyoxazolines Using Glycerol Carbonate Derivative and End Chains Functionalization via Carbonate and Isocyanate Routes
International audienceWe report the cationic ring-opening polymerization of 2-methyl-2-oxazoline (MOx) using bio-based initiator (GCTs). The functional initiator GCTs was prepared by tosylation of the corresponding alcohol: glycerol carbonate (GC). The termination stage of the polymerization was achieved in presence of KOH and the telechelic polyoxazoline carrying five-membered cyclic carbonate and oxazolium end groups (GC-POxium) was converted to ((HO)2-POx-OH) carrying a-diol and x-hydroxyl groups. End-functionalized polyoxazolines (HO)2-POx-OH with Mn ranging from 4200 to 8400 g mol1 were synthesized. According to GPC results, the polymerizations of MOx using GCTs and other initiator coming from 1,2-isopropylidene-glycerol (Solk-Ts) were compared. On the basis of FTIR and NMR spectroscopies, the chemical modification of end chains of polyoxazolines was investigated by two alternative synthetic routes. The isocyanate route is a postpolymerization urethanization. The nucleophilic reactivity of the a-diol and x-hydroxyl groups of (HO)2-POx-OH was studied with functional isocyanate (TESPI). In the carbonate route, the electrophilic reactivity of a- and x-end groups of GC-POxium were explored with amine. It was demonstrated that during the termination stage of the polymerization in presence of allylamine both urethane linker in a-end chain was synthesized and the x-oxazolium group was converted into terminal amine. The carbonate route is an alternative to synthesize urethane without isocyanate