High pressure cosmochemistry applied to major planetary interiors: Experimental studies

The infrared spectra of H2O ice VII and D2O ice VII were studied and techniques were developed for measuring adiabats of phases of NH3-H2O to 5 GPa. A mixing system for pressurized fluids was constructed in which liquid solutions of definite compositions can be prepared and loaded reliably into diamond cells in a project which seeks to determine the properties and boundaries of several high pressure phases of the H2-He-H2O-NH3-CH4 system. These data are needed to constrain theoretical models of the interiors of the major planets

High pressure cosmochemistry applied to major planetary interiors: Experimental studies

Progress is reported in the development of the P-T-X diagram for 0 less than or = X less than or = 0.50 and in the development of techniques for measuring adiabats of phases of NH3-H2O. The partial phase diagram is presented, investigations of the compositions of ammonia ices are described, and methods for obtaining the infrared spectra of ices are discussed

High pressure cosmochemistry applied to major planetary interiors: Experimental studies

Progress is reported on a project to determine the properties and boundaries of high pressure phases of the H2-He-H2O-NH3-CH4 system that are needed to constrain theoretical models of the interiors of the major planets. This project is one of the first attempts to measure phase equilibria in binary fluid-solid systems in diamond anvil cells. Vibrational spectroscopy, direct visual observations, and X-ray diffraction crystallography of materials confined in externally heated cells are the primary experimental probes. Adiabats of these materials are also measured in order to constrain models of heat flow in these bodies and to detect phase transitions by thermal anomalies. Initial efforts involve the NH3-H2O binary. This system is especially relevant to models for surface reconstruction of the icy satellites of Jupiter and Saturn. Thermal analysis experiments were completed for the P-X space, p4GPa:0 or = 0.50, near room temperature. The cryostat, sample handling equipment, and optics needed to extend the optical P-T-X work below room temperature was completed

Proteomics reveals that a high-fat diet induces rapid changes in hypothalamic proteins related to neuronal damage and inflammation

Peer reviewedPublisher PD

Polynomial loss of memory for maps of the interval with a neutral fixed point

We give an example of a sequential dynamical system consisting of intermittent-type maps which exhibits loss of memory with a polynomial rate of decay. A uniform bound holds for the upper rate of memory loss. The maps may be chosen in any sequence, and the bound holds for all compositions.Comment: 16 page

Lithium hydroxide dihydrate: A new type of icy material at elevated pressure

We show that, in addition to the known monohydrate, LiOH forms a dihydrate at elevated pressure. The dihydrate involves a large number of H-bonds establishing chains along the direction. In addition, the energy surface exhibits a saddle point for proton locations along certain O interatomic distances, a feature characteristic for superprotonic conductors. However, MD simulations indicate that LiOH·2H_2O is not a superprotonic conductor and suggest the relevant interpolyhedral O–O distances being too large to allow for proton transfer between neighboring Li-coordinated polyhedra at least on the time scale of the MD-simulations

Development of an adaptive window-opening algorithm to predict the thermal comfort, energy use and overheating in buildings

This investigation of the window opening data from extensive field surveys in UK office buildings demonstrates: 1) how people control the indoor environment by opening windows; 2) the cooling potential of opening windows; and 3) the use of an ‘adaptive algorithm’ for predicting window opening behaviour for thermal simulation in ESP-r. It was found that when the window was open the mean indoor and outdoor temperatures were higher than when closed, but show that nonetheless there was a useful cooling effect from opening a window. The adaptive algorithm for window opening behaviour was then used in thermal simulation studies for some typical office designs. The thermal simulation results were in general agreement with the findings of the field surveys. The adaptive algorithm is shown to provide insights not available using non adaptive simulation methods and can assist in achieving more comfortable, lower energy buildings while avoiding overheating

Comfort driven adaptive window opening behaviour and the influence of building design

It is important to understand and model the behaviour of occupants in buildings and how this behaviour impacts energy use and comfort. It is similarly important to understand how a buildings design affects occupant comfort, occupant behaviour and ultimately the energy used in the operation of the building. In this work a behavioural algorithm for window opening developed from field survey data has been implemented in a dynamic simulation tool. The algorithm is in alignment with the proposed CEN standard for adaptive thermal comfort. The algorithm is first compared to the field study data then used to illustrate the impact of adaptive behaviour on summer indoor temperatures and heating energy. The simulation model is also used to illustrate the sensitivity of the occupant adaptive behaviour to building design parameters such as solar shading and thermal mass and the resulting impact on energy use and comfort. The results are compared to those from other approaches to model window opening behaviour. The adaptive algorithm is shown to provide insights not available using non adaptive simulation methods and can assist in achieving more comfortable and lower energy buildings