Neoproterozoic Stratigraphic Comparison of the Lesser Himalaya (India) and Yangtze Block (South China): Paleogeographic Implications

Recent studies of terminal Neoproterozoic rocks (ca. 590–543 Ma) in the Lesser Himalaya of northwestern India and the Yangtze block (south China) reveal remarkably similar facies assemblages and carbonate platform architecture, with distinctive karstic unconformities at comparable stratigraphic levels. These similarities suggest that south China may have been located close to northwestern India during late Neoproterozoic time, an interpretation permitted by the available, yet sparse paleomagnetic data. Additional parallels in older rocks of both blocks—similar rift-related siliciclastic-volcanic successions overlying metamorphic basement, and comparable glaciogenic intervals of possibly Sturtian and Marinoan or Varanger age—suggest that this spatial relationship may have developed earlier in the Neoproterozoic. With the exception of basal Cambrian phosphorite and comparable small shelly fossils, stratigraphic contrasts between northern India and south China and increasing biogeographic affinity between south China and northwestern Australia suggest that south China may have migrated toward northwestern Australia during the Cambrian

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The authors respond to Hoffman et al. (2001), who acknowledged that methane may have played an important role in unusual events associated with Neoproterozoic glaciation, but questioned the authors' permafrost gas hydrate hypothesis for 13C-depleted cap carbonate formation. The critique focused on three issues: (1) an interpretation for tube structures in cap carbonates unrelated to gas migration; (2) the absence of a suitable source for methane gas; and (3) the degree of 13C depletion in sheet-crack cements

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The authors address additional comments on their hypothesis for the origin of Neoproterozoic postglacial cap carbonates and their isotopic excursions

Are Proterozoic Cap Carbonates and Isotopic Excursions a Record of Gas Hydrate Destabilization Following Earth’s Coldest Intervals

Regionally persistent, thin intervals of carbonate rock directly and ubiquitously overlie Proterozoic glacial deposits on almost every continent, and are commonly referred to as cap carbonates. Their unusual facies, stratigraphically abrupt basal and upper contacts, and strongly negative carbon isotopic signature (δ13C values between ∼0‰ and −5‰) suggest a chemical oceanographic origin, the details of which remain unresolved. Here we propose that these enigmatic deposits are related to the destabilization of gas hydrate in terrestrial permafrost following rapid postglacial warming and flooding of widely exposed continental shelves and interior basins. Supporting evidence for this hypothesis includes (1) the common occurrence within the cap carbonates of unusual fabrics, similar to those produced by cold methane seeps; (2) a distinctive time evolution for the carbon isotopic excursions indicative of a pulse addition of isotopically depleted carbon to the ocean- atmosphere system; and (3) agreement between mass-balance estimates of carbon released by hydrate destabilization and carbon buried in the cap carbonate. We infer that during times of low-latitude glaciation, characteristic of the Neoproterozoic, gas hydrates may have been in greater abundance than at any other time in Earth history

Considering a Neoproterozoic Snowball Earth

P. F. Hoffman et al. and N. Christie-Blick et al. discuss Hoffman et al.'s paper that "developed a modified 'snowball Earth' hypothesis (2) to explain the association of Neoproterozoic low-latitude glaciation with the deposition of 'cap carbonate' rocks bearing highly depleted carbon isotopic values (δ13C ≤ −5‰). According to Hoffman et al., the ocean became completely frozen over as a result of a runaway albedo feedback, and primary biological productivity collapsed for an interval of geological time exceeding the carbon residence time (greater than 105 years). During this interval, continental ice cover is inferred to have been thin and patchy owing to the virtual elimination of the hydrological cycle.

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