789 research outputs found
Magnetic frustration in a stoichiometric spin-chain compound, CaCoIrO
The temperature dependent ac and dc magnetization and heat capacity data of
CaCoIrO, a spin-chain compound crystallizing in a KCdCl-derived
rhombohedral structure, show the features due to magnetic ordering of a
frustrated-type below about 30 K, however without exhibiting the signatures of
the so-called "partially disordered antiferromagnetic structure" encountered in
the isostructural compounds, CaCoO and CaCoRhO. This class
of compounds thus provides a variety for probing the consequences of magnetic
frustration due to topological reasons in stoichiometric spin-chain materials,
presumably arising from subtle differences in the interchain and intrachain
magnetic coupling strengths. This compound presents additional interesting
situations in the sense that, ac susceptibility exhibits a large frequency
dependence in the vicinity of 30 K uncharacteristic of conventional
spin-glasses, with this frustrated magnetic state being robust to the
application of external magnetic fields.Comment: Physical Review (Rapid Communications), in pres
Transport and Magnetic Properties of FexVse2 (x = 0 - 0.33)
We present our results of the effect of Fe intercalation on the structural,
transport and magnetic properties of 1T-VSe2. Intercalation of iron, suppresses
the 110K charge density wave (CDW) transition of the 1T-VSe2. For the higher
concentration of iron, formation of a new kind of first order transition at
160K takes place, which go on stronger for the 33% Fe intercalation.
Thermopower of the FexVSe2 compounds (x = 0 - 0.33), however do not show any
anomaly around the transition. The intercalation of Fe does not trigger any
magnetism in the weak paramagnetic 1T-VSe2, and Fe is the low spin state of
Fe3+.Comment: 7 pages, 8 figures, 2 table
^{17}O and ^{51}V NMR for the zigzag spin-1 chain compound CaV2O4
V NMR studies on CaV2O4 single crystals and O NMR studies on
O-enriched powder samples are reported. The temperature dependences of
the O NMR line width and nuclear spin-lattice relaxation rate give
strong evidence for a long-range antiferromagnetic transition at Tn = 78 K in
the powder. Magnetic susceptibility measurements show that Tn = 69 K in the
crystals. A zero-field V NMR signal was observed at low temperatures (f
237 MHz at 4.2 K) in the crystals. The field swept spectra with the
field in different directions suggest the presence of two antiferromagnetic
substructures. Each substructure is collinear, with the easy axes of the two
substructures separated by an angle of 19(1) degree, and with their average
direction pointing approximately along the b-axis of the crystal structure. The
two spin substructures contain equal number of spins. The temperature
dependence of the ordered moment, measured up to 45 K, shows the presence of an
energy gap Eg in the antiferromagnetic spin wave excitation spectrum.
Antiferromagnetic spin wave theory suggests that Eg lies between 64 and 98 K.Comment: 11 pages, 14 figures. v2: 2 new figures; version published in Phys.
Rev.
Crystallography, magnetic susceptibility, heat capacity, and electrical resistivity of heavy fermion LiVO single crystals grown using a self-flux technique
Magnetically pure spinel compound is a rare -electron
heavy fermion. Measurements on single crystals are needed to clarify the
mechanism for the heavy fermion behavior in the pure material. In addition, it
is known that small concentrations ( mol%) of magnetic defects in the
structure strongly affect the properties, and measurements on single crystals
containing magnetic defects would help to understand the latter behaviors.
Herein, we report flux growth of and preliminary measurements
to help resolve these questions. The magnetic susceptibility of some as-grown
crystals show a Curie-like upturn at low temperatures, showing the presence of
magnetic defects within the spinel structure. The magnetic defects could be
removed in some of the crystals by annealing them at 700 C\@. A very
high specific heat coefficient = 450 mJ/(mol K\@) was obtained
at a temperature of 1.8 K for a crystal containing a magnetic defect
concentration = 0.5 mol%. A crystal with = 0.01 mol% showed a residual resistivity ratio of 50.Comment: 6 pages, 7 figures, Title modifie
Phase Relations in the Li2O-V2O3-V2O5 System at 700 C: Correlations with Magnetic Defect Concentration in Heavy Fermion LiV2O4
The phase relations in the Li2O-V2O3-V2O5 ternary system at 700 C for
compositions in equilibrium with LiV2O4 are reported. This study clarified the
synthesis conditions under which low and high magnetic defect concentrations
can be obtained within the spinel structure of LiV2O4. We confirmed that the
LiV2O4 phase can be obtained containing low (0.006 mol%) to high (0.83 mol%)
magnetic defect concentrations n{defect} and with consistently high magnetic
defect spin S values between 3 and 6.5. The high n{defect} values were obtained
in the LiV2O4 phase in equilibrium with V2O3, Li3VO4, or LiVO2 and the low
values in the LiV2O4 phase in equilibrium with V3O5. A model is suggested to
explain this correlation.Comment: 6 pages, 7 figures; Phys. Rev. B (accepted
Inhomogeneous magnetism in single crystalline SrCuIrO: Implications to phase-separation concepts
The single crystalline form of an insulator, SrCuIrO, is
shown to exhibit unexpectedly more than one magnetic transition (at 5 and 19 K)
with spin-glass-like magnetic susceptibility behaviour. On the basis of this
finding, viz., inhomogeneous magnetism in a chemically homogeneous material, we
propose that the idea of "phase- separation" described for manganites [1] is
more widespread in different ways. The observed experimental features enable us
to make a comparison with the predictions of a recent toy model [2] on {\it
magnetic} phase separation in an insulating environment.Comment: 4 pages, 4 figure
Magnetic anomalies in the spin chain system, SrCuZnIrO
We report the results of ac and dc magnetization (M) and heat-capacity (C)
measurements on the solid solution, SrCuZnIrO. While the Zn
end member is known to form in a rhombohedral pseudo one-dimensional
KCdCl structure with an antiferromagnetic ordering temperature of
(T =) 19 K, the Cu end member has been reported to form in a monoclinically
distorted form with a Curie temperature of (T =) 19 K. The magnetism of the
Zn compound is found to be robust to synthetic conditions and is broadly
consistent with the behavior known in the literature. However, we find a lower
magnetic ordering temperature (T) for our Cu compound (~ 13 K), thereby
suggesting that T is sensitive to synthetic conditions. The Cu sample
appears to be in a spin-glass-like state at low temperatures, judged by a
frequency dependence of ac magnetic susceptibility and a broadening of the C
anomaly at the onset of magnetic ordering, in sharp contrast to earlier
proposals. Small applications of magnetic field, however, drive this system to
ferromagnetism as inferred from the M data. Small substitutions for Cu/Zn (x =
0.75 or 0.25) significantly depress magnetic ordering; in other words, T
varies non-monotonically with x (T ~ 6, 3 and 4 K for x = 0.25, 0.5, and
0.67 respectively). The plot of inverse susceptibility versus temperature is
non-linear in the paramagnetic state as if correlations within (or among) the
magnetic chains continuously vary with temperature. The results establishComment: 7 pages, 7 figures, Revte
The emergence of enterovirus D68 in England in autumn 2014 and the necessity for reinforcing enterovirus respiratory screening.
In autumn 2014, enterovirus D68 (EV-D68) cases presenting with severe respiratory or neurological disease were described in countries worldwide. To describe the epidemiology and virological characteristics of EV-D68 in England, we collected clinical information on laboratory-confirmed EV-D68 cases detected in secondary care (hospitals), between September 2014 and January 2015. In primary care (general practitioners), respiratory swabs collected (September 2013-January 2015) from patients presenting with influenza-like illness were tested for EV-D68. In secondary care 55 EV-D68 cases were detected. Among those, 45 cases had clinical information available and 89% (40/45) presented with severe respiratory symptoms. Detection of EV-D68 among patients in primary care increased from 0.4% (4/1074; 95% CI 0.1-1.0) (September 2013-January 2014) to 0.8% (11/1359; 95% CI 0.4-1.5) (September 2014-January 2015). Characterization of EV-D68 strains circulating in England since 2012 and up to winter 2014/2015 indicated that those strains were genetically similar to those detected in 2014 in USA. We recommend reinforcing enterovirus surveillance through screening respiratory samples of suspected cases
N-type organic electrochemical transistors with stability in water.
Organic electrochemical transistors (OECTs) are receiving significant attention due to their ability to efficiently transduce biological signals. A major limitation of this technology is that only p-type materials have been reported, which precludes the development of complementary circuits, and limits sensor technologies. Here, we report the first ever n-type OECT, with relatively balanced ambipolar charge transport characteristics based on a polymer that supports both hole and electron transport along its backbone when doped through an aqueous electrolyte and in the presence of oxygen. This new semiconducting polymer is designed specifically to facilitate ion transport and promote electrochemical doping. Stability measurements in water show no degradation when tested for 2 h under continuous cycling. This demonstration opens the possibility to develop complementary circuits based on OECTs and to improve the sophistication of bioelectronic devices
Locked-in Syndrome in a Young Patient Due to SARS-CoV-2: A Case Report
© Copyright © 2020 Sattar, Iqbal, Haider, Zia, Niazi, Hanif, Ali and Khan. Coronavirus disease 2019 (COVID-19), apart from commonly involving the respiratory system, has its impact on the central nervous system, with a wide spectrum of clinical presentations ranging from headaches to ischemic strokes. The ongoing research regarding this novel disease has found that there is a very high prevalence of thrombotic episodes especially in critically ill patients when compared to severe presentation of other viral illnesses. This COVID-19-associated coagulopathy has a very complex etiology with the ability to form thrombus in arteries, veins, and microvasculatures of different organs. We present a unique case of a young woman with underlying COVID-19 who unfortunately developed locked-in syndrome due to bilateral pontine infarction during the course of her illness
- …