Characterization of carbon nanotubes synthesized from hydrocarbon-rich flame

The present study focuses on the characterization of carbon nanotubes (CNTs) synthesized from flame under an atmospheric condition. A laminar flame burner was utilized to establish a rich premixed propane/air flame at the equivalence ratio Φ = 1.8-2.2. The flame was impinged on a stainless steel wire mesh coated with nickel (Ni) catalyst to grow CNTs. Distribution and yield of the CNTs on the substrate were quantified. Carbon nanotubes formed on the substrate were harvested and characterized using scanning electron microscopy (SEM), field emission scanning electron microscopy (FESEM), energy dispersive X-ray spectroscopy (EDX), and thermogravimetric analysis (TGA). The FESEM micrograph showed that the CNTs produced were in disarray. The synthesized CNTs were an average of 50-60 nm in diameter while the length of the tubes was in the order of microns. TGA analysis showed that 75% of CNTs were present in the sample and the oxidation temperature was 510°C

Oil film interferometry in high Reynolds number turbulent boundary layers

There is continuing debate regarding the validity of skin friction measurements that are dependent on the functional form of the mean velocity profile, for example, the Clauser chart method. This has brought about the need for independent and direct measures of wall shear stress, tw. Of the independent methods to measure tw, oil film interferometry is the most promising, and it has been extensively used recently at low and moderately high Reynolds number. The technique uses interferometry to measure the thinning rate of an oil film, which is linearly related to the level of shear stress acting on the oil film. In this paper we report on the use of this technique in a high Reynolds number boundary layer up to Rq = 50,000. Being an independent measure of tw, the oil film measurement can be used as a means to validate more conventional techniques, such as the Preston tube and Clauser chart at these high Reynolds numbers. The oil-film measurement is validated by making comparative measurements of tw in a large-scale fully-developed channel flow facility where the skin friction is known from the pressure gradient along the channe

Control of active filters to attenuate harmonic resonance in power distribution networks

Harmonic resonance occurs when the network equivalent shunt harmonic capacitive reactance is associated with the network series harmonic inductive reactance. When such resonance occurs, it amplifies harmonic components with frequency close to the resonance point. Solutions used to solve harmonic resonance problems can be divided into two main categories. One is to reduce the content of harmonic components in the network (e.g. by using active or passive harmonic filters, etc.) and the other is to remove the resonance stimulating factor by shifting away the resonance frequency to a non-critical frequency range (e.g. detuning PFC capacitors, redesigning feeder transformers, etc.). Studies show that these techniques are not adequate to solve harmonic resonance problems in power distribution networks which are dynamic by their nature and with complex interconnections. Due to this, solutions in the category one are designed for localised harmonic distortion compensation, while solutions in the category two lack real-time operation feature. Therefore, it was identified that there is a need for real-time harmonic resonance attenuation that is suitable for power distribution networks. In this thesis, a new real-time Harmonic Resonance Attenuation (HRA) technique is proposed. This technique may be used with ordinary shunt harmonic filters to make them behave like a virtual shunt capacitor or inductor. Thus, looking from the harmonic current source side, the filter alters the network harmonic impedance and hence results in harmonic resonance attenuation. In order to implement the HRA technique, fast measurement of system harmonics in real-time is required. Therefore, in this work, a fast individual harmonic extraction (FIHE) technique is developed to enhance the desired real-time operation of the HRA. The proposed FIHE needs only one sixth of the fundamental cycle to extract any individual harmonic component which is faster than other methods currently available. In addition to the speed, the proposed FIHE provides overshoot free, oscillation free and ripple free extraction characteristics. The proposed HRA and FIHE techniques are described in this thesis with detailed analysis to illustrate their operating principles. A series of simulations and experiments are conducted to evaluate their functionality and performance. Results of the evaluation are presented and discussed in this thesis together with details of the experimental HRA model developed to verify the theoretical and simulation results.EThOS - Electronic Theses Online ServiceGBUnited Kingdo

Differential expression of microRNAs in plasma of patients with colorectal cancer: A potential marker for colorectal cancer screening

Objective: MicroRNAs (miRNAs) have been shown to offer great potential in the diagnosis of cancer. We investigated whether plasma miRNAs could discriminate between patients with and without colorectal cancer (CRC). Methods: This study was divided into three phases: (1) marker discovery using real-time PCR-based miRNA profiling on plasma, corresponding cancerous and adjacent non-cancerous colonic tissues of five patients with CRC, along with plasma from five healthy individuals as controls; (2) marker selection and validation by real-time quantitative RT-PCR on a small set of plasma; and (3) independent validation on a large set of plasma from 90 patients with CRC, 20 patients with gastric cancer, 20 patients with inflammatory bowel disease (IBD) and 50 healthy controls. Results: Of the panel of 95 miRNAs analysed, five were upregulated both in plasma and tissue samples. All the five miRNAs were validated on the plasma of 25 patients with CRC and 20 healthy controls. Both miR-17-3p and miR-92 were significantly elevated in the patients with CRC (p<0.0005). The plasma levels of these markers were significantly reduced after surgery in 10 patients with CRC (p<0.05). Further validation with an independent set of plasma samples (n=180) indicated that miR-92 differentiates CRC from gastric cancer, IBD and normal subjects. This marker yielded a receiver operating characteristic curve area of 88.5%. At a cut-off of 240 (relative expression in comparison to RNU6B snRNA), the sensitivity was 89% and the specificity was 70% in discriminating CRC from control subjects. Conclusion: MiR-92 is significantly elevated in plasma of patients with CRC and can be a potential non-invasive molecular marker for CRC screening.published_or_final_versio

Pyrolysing horse manure via microwave-induced heating for bioenergy recovery

Transforming waste to energy is essential in view of the need to search for greener and more sustainable energy sources. Such transformation of energy is also aligned with the aim of reducing excessive waste generation whilst creating potential biofuel pathways for power generation. In the present study, animal waste in the form of horse manure is being used as feedstock to undergo microwave-induced pyrolysis via a fixed-bed pyrolysis rig. The relationship of the pyrolysis parameters such as pyrolysis temperature of 350 and 550 °C, carrier gas flow rate of 0.5 and 1.5 L/min and ratio of horse manure to activated carbon blend of 1:2 and 1:1, with the yield of pyrolysed products is studied. The derived pyrolysis products in the form of solid, liquid and gaseous are characterised and quantified. Result shows that the highest yield of solid, liquid and gaseous products obtained are 78.8 wt%, 24.7 wt% and 34.2 wt%. Solid yield is observed to decrease with increasing pyrolysis temperature while gaseous yield shows a reverse trend. Higher carrier gas flow rate is observed to lower the generation of gaseous and liquid yield while increasing the solid yield. Higher amount of activated carbon within the feedstock is seen to lower the solid yield but increase the gaseous and liquid yields. The liquid yield is found to contain 55.78 wt% of phenolic compounds while gaseous product consists of up to 55 vol% of syngas. The control of the operating conditions in pyrolysis rig enables the production of pyrolysis end products in different phases, generating useful bioenergy and biofertilizer products in the context of circular economy

Development of a mathematical tool to predict engine in-cylinder friction

A better fuel-efficient automotive engine is more sought-after to promote greener environment in the era of global warming. One of the factors to cause the increase of fuel consumption in vehicles is the frictional loss within an internal combustion engine. In this study, the focus is to determine the tribological behaviour between the piston top compression ring and the engine cylinder liner for a full engine cycle. Mathematical models are derived from a 1-D Reynolds equation, assuming Half-Sommerfeld and Reynolds boundary conditions. Greenwood and Tripp rough surface contact model is applied to predict frictional properties along the ring-liner contact, considering viscous and boundary friction. It is found that the Half-Sommerfeld boundary condition predicts minimum lubricant film thickness that correlates well with literature data. However, the friction force predicted by the Reynolds boundary condition along dead centres correlates better with literature data. With friction along the cylinder liner dead centres being very significant, it is, therefore, suggested that the Reynolds boundary condition be the better mathematical model in studying the piston ring-liner tribological conjunction

Experimental and numerical study on soot formation in laminar diffusion flames of biodiesels and methyl esters

Biodiesel and blends with petroleum diesel are promising renewable alternative fuels for engines. In the present study, the soot concentration generated from four biodiesels, two pure methyl esters, and their blends with petroleum diesel are measured in a series of fully pre-vapourised co-flow diffusion flames. The experimental measurements are conducted using planar laser induced-incandescence (LII) and laser extinction optical methods. The results show that the maximum local soot volume fractions of neat biodiesels are 24.4% - 41.2% of pure diesel, whereas the mean soot volume fraction of neat biodiesel cases was measured as 11.3% - 21.3% of pure diesel. The addition of biodiesel to diesel not only reduces the number of inception particles, but also inhibits their surface growth. The discretised population balance modelling of a complete set of soot processes is employed to compute the 2D soot volume fraction and size distribution across the tested flames. The results show that the model also demonstrates a reduction of both soot volume fraction and primary particle size by adding biodiesel fuels. However, it is not possible to clearly determine which factors are responsible for the reduction from the comparison alone. Moreover, analysis of the discrepancies between numerical and experimental results for diesel and low-blending cases offers an insight for the refinement of soot formation modelling of combustion with large-molecule fuels.Bo Tian is supported by the fellowship provided by ZEPI. C. T. Chong is supported by the Newton Advanced Fellowship of the Royal Society (NA160115). Anxiong Liu gratefully acknowledges the financial support of the Chinese Scholarship Council (CSC) and the EPSRC grant No. EP/S012559/1

A techno-economical and automotive emissions impact study of global biodiesel usage in diesel engines

In recent years, biodiesel has arrived at the forefront, as a mainstream alternative energy, due to its advantages properties such as renewability, compatibility with existing automotive infrastructures and diesel engines, cleaner emissions. Many studies have been conducted to improve the maturity of biodiesel production technology, and fuel application. However, the global-scale economical and emissions impacts of first generation biodiesel is still not being adequately addressed. This requires immediate attention as the current economical setback for biodiesel is affected by low crude oil price. In this study, the correlations between the biodiesel production feasibility, crude oil price, and feedstock availability are defined. By using a data-driven predictive model, insights can be drawn for the worldwide profitability, potential level of diesel replacement using biodiesel, and environmental impact. The model allows prediction to be done on potential biodiesel production at a country-region level, at different crude oil prices and fuel blending ratios. It was also predicted that up to 9% of total global diesel consumption could be replaced by profitable biodiesel, if crude oil price rises up to USD 135 per barrel and factoring in refinery cost of USD 0.05 per litre. Countries near the equatorial belt with abundance palm oil feedstock such as Malaysia, Papua New Guinea and Indonesia could potentially augment their gross domestic products by 10.36%, 7.67% and 5.57%, respectively. If all non-domestic usage feedstock is converted into biodiesel for automotive usage, there will be conclusive reduction of engine-out emissions such as unburnt hydrocarbons and particulate matter. Ultimately, this model proves that there is high potential for mass adoption of biodiesel to supplant fossil diesel globally, allowing the generation of income, improving energy security and produces cleaner automotive emissions

Qigong Exercise Alleviates Fatigue, Anxiety, and Depressive Symptoms, Improves Sleep Quality, and Shortens Sleep Latency in Persons with Chronic Fatigue Syndrome-Like Illness

Objectives:. To evaluate the effectiveness of Baduanjin Qigong exercise on sleep, fatigue, anxiety, and depressive symptoms in chronic fatigue syndrome- (CFS-) like illness and to determine the dose-response relationship. Methods:. One hundred fifty participants with CFS-like illness (mean age = 39.0, SD = 7.9) were randomly assigned to Qigong and waitlist. Sixteen 1.5-hour Qigong lessons were arranged over 9 consecutive weeks. Pittsburgh Sleep Quality Index (PSQI), Chalder Fatigue Scale (ChFS), and Hospital Anxiety and Depression Scale (HADS) were assessed at baseline, immediate posttreatment, and 3-month posttreatment. The amount of Qigong self-practice was assessed by self-report. Results:. Repeated measures analyses of covariance showed a marginally nonsignificant (P = 0.064) group by time interaction in the PSQI total score, but it was significant for the “subjective sleep quality” and “sleep latency” items, favoring Qigong exercise. Improvement in “subjective sleep quality” was maintained at 3-month posttreatment. Significant group by time interaction was also detected for the ChFS and HADS anxiety and depression scores. The number of Qigong lessons attended and the amount of Qigong self-practice were significantly associated with sleep, fatigue, anxiety, and depressive symptom improvement. Conclusion:. Baduanjin Qigong was an efficacious and acceptable treatment for sleep disturbance in CFS-like illness. This trial is registered with Hong Kong Clinical Trial Register: HKCTR-1380