Iron ore minerals depression: influence of mineralogy, morphology, and conditioning pH

Nove amostras de minerais de ferro, provenientes de diferentes minas (jazidas) pertencentes à Vale, foram o objeto desse trabalho, que buscou correlacionar a depressão das referidas amostras com amido e carboximetil celulose versus parâmetros mineralógicos e morfológicos. O amido de milho convencional se mostrou capaz de realizar ação depressora sobre todas as amostras, exceto sobre aquelas que se mostraram mais ricas em hematita compacta (HC). Tais hematitas podem ser chamadas de "problemáticas", visto que interagem fortemente com o coletor e apresentam deficiência de serem deprimidas pelo amido, exigindo elevadas dosagens para minimização de sua tendência à flotação. Carboximetil celulose não apresentou ação depressora sobre nenhuma das amostras estudadas. A flotabilidade das amostras ricas em HC pode ser minimizada pela ação do amido de milho condicionado em pH 8,0-8,5. Testes de flotação com minério itabirítico, contendo elevado percentual de hematitas compactas de pequeno tamanho de cristal, confirmaram a redução do teor de Fe no rejeito com a utilização de amido condicionado em pH≅8.Nine samples of Fe-bearing minerals from several mines of Vale were the object of this work, which aimed to make a correlation between mineralogy and morphology versus flotation depression by starch and carboxy methyl cellulose. They did not demand strong action from depressants. Cornstarch was able to depress all the samples, except those that exhibited high HC content. The latter samples could be regarded as “problematic” because they were able to interact strongly with collector and demanded a high dosage of depressant to accomplish full depression. Carboxy methylcellulose did not show depressive action on any of the studied Febearing minerals. Flotation response of the samples, which are rich in HC, could be minimized by the action of starch conditioned at pH 8.0-8.5, increasing Fe recovery in the process

The Characteristics of Iron Ore Slimes and Their Influence on The Flotation Process

The flotation has been successfully applied to process the iron ore for the particle size (Ps) from 10 µm up to 150 µm. The presence of the slimes (Ps < 10 µm) is harmful on the reverse flotation of quartz, so they are usually prior removed by hydrocyclones. The main effects of the presence of slimes on the flotation are related to the increase on reagents consumption, the froth stability, and decrease on the selectivity. The lower floatability of coarse quartz particles (+74 µm) combined with the presence of slimes, even in small quantities, drastically affect the flotation response. This paper shows a study of characterization of a typical iron ore slime, aiming to create a better understanding of its role on the concentration by flotation. The main characteristics of typical slimes from the Iron Ore Quadrangle in Brazil are the presence of almost 70% of hematite, 25% of quartz, and 5% of kaolinite, as the main silicates gangue minerals. Furthermore, the particle size distribution revealed that 80% of the hematite and the kaolinite are below 20 µm. The affinity between the ultrafine kaolinite of the slimes with the corn starch is harmful to the reverse flotation of quartz, as the starch has an important depressing action over the hematite. The presence of 20% of hematite −20 µm decreased the recovery to the froth of quartz + 74 µm from 97% to 62%, where the slimes coating seems to be the main responsible

Comparative evaluation between mechanical and pneumatic cells for quartz flotation in the iron ore industry

Abstract Flotation plays a relevant role in the concentration of iron ores. Conventional flotation technology employing mechanical machines and columns and also circuits combining both types of cells have been utilized in the iron ore industry. The top size of particles in the flotation circuit feed is 150 µm and the slimes below 10 µm are removed as overflow in hydrocyclone classification. The conventional flotation technology faces difficulties in achieving tailings with iron grades lower than 12% and concentrates with SiO2 grades lower than 1%, and requires long residence times, resulting in large volume machines and huge footprints. The pneumatic flotation technology was evaluated in the reverse flotation of quartz from an iron ore sample of the Iron Quadrangle, Brazil. Bench and industrial scale tests were conducted in pneumatic flotation machines at low residence time. Both tests were carried out in open circuit stages with the objective of comparison with mechanical cells. The bench scale tests were carried out in three stages (rougher, cleaner and recleaner) in an 11 L pneumatic cell aiming at final concentrate with maximum 2% SiO2 while the industrial tests were carried out in a 25 m3 pneumatic cell in the rougher stage aiming at comparison with a circuit of five 14 m3 cells in the rougher stage and four 14 m3 cells in the scavenger stage. The collision and particle-bubble adhesion occur in a step before the pulp reaches the pneumatic cell vessel. The results indicate the possibility of achieving concentrates with a SiO2 content of approximately 1% and tailings with iron contents lower than 10% with three stages (rougher, cleaner and recleaner) without the need of scavenger stages. Furthermore, the residence time was three times shorter than that required for conventional mechanical cells. The speed of the pulp at the entrance of the pneumatic cell strongly affects the quality of the concentrate