Distribution of grout material within 1-m sand column in insitu calcite precipitation technique

AbstractThis study evaluates the potential of improving an insitu calcite grouting technique. The grout is composed of an equimolar solution of urea–CaCl2 and an enzyme named urease. We examine the distribution of the grout materials and precipitated calcite within sand columns with a diameter of 5cm and a height of 100cm. In the first series of experiments, the concentration distributions of the individual grout materials (i.e., urea, CaCl2 and urease) within the sand specimen are evaluated. In the second series of experiments, an enzyme-reagent mixed solution (i.e., grout) is injected into the sand columns to evaluate the distribution of calcite. Sand samples are collected from various vertical locations within the treated columns and the amount of precipitated calcite is evaluated. Furthermore, attempts are made to achieve the uniform distribution of the injected grout and hence uniform calcite distribution throughout the specimen. The results show that a uniform distribution of the grout materials up to a distance of 1m from the inlet is achievable. It is also observed that a relatively uniform distribution of calcite is achievable as long as the rate of calcite precipitation is well controlled

Effect of Magnesium as Substitute Material in Enzyme-Mediated Calcite Precipitation for Soil-Improvement Technique

The optimization of enzyme-mediated calcite precipitation (EMCP) was evaluated as a soil improvement technique. In our previous works, purified urease was utilized to bio-catalyze the hydrolysis of urea, which causes the supplied Ca2+ to precipitate with CO32- as calcium carbonate. In the present work, magnesium chloride was newly added to the injecting solutions to delay the reaction rate and to enhance the amount of carbonate precipitation. Soil specimens were prepared in PVC cylinders and treated with concentration-controlled solutions composed of urea, urease, calcium, and magnesium chloride. The mechanical properties of the treated soil specimens were examined through unconfined compressive strength (UCS) tests. A precipitation ratio of the carbonate up to 90% of the maximum theoretical precipitation was achieved by adding a small amount of magnesium chloride. Adding magnesium chloride as a delaying agent was indeed found to reduce the reaction rate of the precipitation, which may increase the volume of the treated soil if used in real fields because of the slower precipitation rate and the resulting higher injectivity. A mineralogical analysis revealed that magnesium chloride decreases the crystal size of the precipitated materials and that another carbonate of aragonite is newly formed. Mechanical test results indicated that carbonate precipitates within the soils and brings about a significant improvement in strength. A maximum UCS of 0.6 MPa was obtained from the treated samples

Nickel Oxide-Incorporated Polyaniline Nanocomposites as an Efficient Electrode Material for Supercapacitor Application

This work reports the facile, controlled, and low-cost synthesis of a nickel oxide and polyaniline (PANI) nanocomposites-based electrode material for supercapacitor application. PANI-NiO nanocomposites with varying concentrations of NiO were synthesized via in-situ chemical oxidative polymerization of aniline. The XRD and FTIR support the interaction of PANI with NiO and the successful formation of the PANI-NiO-x nanocomposite. The SEM analysis showed that the NiO and PANI were mixed homogenously, in which the NiO nanomaterial was incorporated in porous PANI globular nanostructures. The multiple phases of the nanocomposite electrode material enhance the overall performance of the energy-storage behavior of the supercapacitor that was tested in 1 M H2SO4 using cyclic voltammetry (CV), galvanostatic charge-discharge (GCD), and electrochemical impedance spectroscopy (EIS). Among the different nanocomposites, PANI-NiO-3 exhibit the specific capacitance of a 623 F g−1 at 1 A g−1 current density. Furthermore, the PANI-NiO-3 electrode retained 89.4% of its initial capacitance after 5000 cycles of GCD at a 20 A g−1 current density, indicating its significant cyclic stability. Such results suggest that PANI-NiO nanocomposite could be proposed as an appropriate electrode material for supercapacitor applications