Improved Duncan-Chang model for reconstituted hydrate-bearing clayey silt from the South China Sea

The experimental testing and analysis of strength and deformation characteristics of hydrate reservoirs is an integral part of natural gas hydrate exploitation. However, studies so far have failed to deeply explore samples from the South China Sea. Especially, there is a lack of a simple and applicable method to estimate their mechanical behaviors. Thus, based on test data, an improved Duncan-Chang model is established in this paper to characterize the strength and deformation of reconstituted samples with various hydrate saturation and stress states from this area. This model can accurately describe the strain-hardening characteristics, and failure strength is estimated by the improved Drucker-Prager criterion with high fitting accuracy. The initial elastic modulus and failure ratio are given by the proposed empirical models, which are obtained from experimental data and fitting methods. Generally, this model has several advantages including simple structure, favorable performances, and a limited number of model parameters. Therefore, it could be widely used in strength and deformation analysis. This study can support the prevention and control of geological risks during natural gas hydrate exploitation in the South China Sea.Cited as: Dong, L., Wu, N., Zhang, Y., Liao, H., Hu, G. Li, Y. Improved Duncan-Chang model for reconstituted hydrate-bearing clayey silt from the South China Sea. Advances in Geo-Energy Research, 2023, 8(2): 136-140. https://doi.org/10.46690/ager.2023.05.0

A model to predict the thermodynamic stability of abiotic methane-hydrogen binary hydrates in a marine serpentinization environment

Abiotic methane (CH4) and hydrogen (H2), which are produced during marine serpentinization, provide abundant gas source for hydrate formation on ocean floor. However, previous models of CH4–H2 hydrate formation have generally focused on pure water environments and have not considered the effects of salinity. In this study, the van der Waals–Platteeuw model, which considered the effects of salinity on the chemical potentials of CH4, H2, and H2O, was applied in a marine serpentinization environment. The model uses an empirical formula and the Peng–Robinson equation of state to calculate the Langmuir constants and fugacity values, respectively, of CH4 and H2, and it uses the Pitzer model to calculate the activity coefficients of H2O in the CH4–H2–seawater system. The three-phase equilibrium temperature and pressure predicted by the model for CH4–H2 hydrates in pure water demonstrated good agreement with experimental data. The model was then used to predict the three-phase equilibrium temperature and pressure for CH4–H2 hydrates in a NaCl solutions, for which relevant experimental data are lacking. Thus, this study provides a theoretical basis for gas hydrate research and investigation in areas with marine serpentinization

Reassessing two contrasting Late Miocene-Holocene stratigraphic frameworks for the Pearl River Mouth Basin, northern South China Sea

High-resolution 2D/3D seismic and biostratigraphic data are used to reassess two contrasting Late Miocene-Holocene stratigraphic frameworks (SFI and SFII) for the northern slope of the Pearl River Mouth Basin (PRMB), northern South China Sea. The major stratigraphic boundaries (T1-base Quaternary and T2-base Pliocene) derived from SFI and SFII are different in depth. The trends of average sedimentation rates from Late Miocene to Quaternary were estimated according to the major boundaries in order to highlight the differences between these two frameworks. The seismic reflection terminations as erosional and truncation features were recognized through the seismic data implying that the submarine channels and mass-transport deposits are valid stratigraphic markers of Late Miocene-Holocene basin development on the northern South China Sea margin and other continental margins. The sediments from hydrate drilling sites in the Shenhu Area consist of two allochthonous sedimentary units with similar lithology and grain sizes: a) fine-grained turbidites at the bottom, and b) fine-grained submarine landslides at the top. Nannofossil assemblages with relatively minute sizes were likely to be reworked due to the setting of widespread mass wasting on the middle to lower continental slope. A key result of this study is that the stratigraphic framework based on a combination of seismic and sequence stratigraphic data is more suitable for stratigraphic correlations across the northern slope of the PRMB. Our findings provide a robust foundation to rebuild the tectono-sedimentary evolution of the PRMB and also resolve the uncertainties in the Late Miocene-Holocene stratigraphic frameworks of the study area

Simulation of advective methane flux and AOM in Shenhu area, the northern South China Sea

Anaerobic oxidation of methane (AOM) occurring in the marine sediment is an important process for methane cycle and methane sequestration. In this work, a one-dimensional numerical model was developed to study the distribution of advective methane flux with the AOM process. The model has been applied to investigate the gas hydrates bearing sediments of Shenhu areas located in the northern South China Sea, where advective methane transport was detected. The modeling results suggest that methane flux will be consumed in the sediment column via dissolution, sorption, and AOM reaction. Only when the methane flux was one order of magnitude higher than current level, then a portion of methane will enter water column and possibly escape to the atmosphere. The numerical simulation also revealed that, due to the lower permeability of the silt-clay sediments, a much thicker sulfate-methane transition zone exists in the Shenhu area, where AOM is able to consume more

Numerical pressure transient analysis for unfilled-caved carbonate reservoirs based on Stokes-Darcy coupled theory

Caved carbonate reservoirs are very special because of the strong heterogeneity. The pressure transient behavior of the caved carbonate reservoirs is quite different from the conventional homogeneous or dual medium reservoirs because of the presence of large-scale cavities. There are two types of cavities: filled and unfilled, which dominated the production of the reservoirs. Fluid flow in the unfilled cavity should be described by Stokes' equation rather than Darcy's law. It is needed to better understand the role of the unfilled cavities plays in the pressure transient analysis. The objective of this work is to analyze the pressure transient behavior of the unfilled cavities. A coupled Stokes-Darcy pressure transient model is developed and the finite element method is applied in the solutions of the mathematical models. Then, the numerical pressure transient model is used in the analysis of two typical cases: a well drilled into the unfilled cavity (WIC) and a well not drilled into the unfilled cavity (WOC). The type curves of the WIC model indicate that flow in the unfilled cavity is an oscillated pressure-drop rather than a radial flow. The unfilled cavity that the well drilled into would be considered as an enlarged wellbore which is equivalent to a negative skin factor, as a consequence the wellbore storage coefficient will increase. Main characteristics of type curves for WOC model are the valley on the pressure derivative. A cavity with a larger size and smaller distance from the wellbore would give rise to a deeper valley. Comparative results indicate that unfilled cavities described by the Stokes' equation are not the limit of the filled cavities with extremely large mobility, which was predicted by previous work

Gas hydrate formation in fine sand

Gas hydrate formation from two types of dissolved gas (methane and mixed gas) was studied under varying thermodynamic conditions in a novel apparatus containing two different natural media from the South China Sea. The testing media consisted of silica sand particles with diameters of 150-250 mu m and 250-380 mu m. Hydrate was formed (as in nature) in salt water that occupies the interstitial space of the partially water-saturated silica sand bed. The experiments demonstrate that the rate of hydrate formation is a function of particle diameter, gas source, water salinity, and thermodynamic conditions. The initiation time of hydrate formation was very short and pressure decreased rapidly in the initial stage. The process of mixed gas hydrate formation can be divided into three stages for each type of sediment. Sand particle diameter and water salinity also can influence the formation process of hydrate. The conversion rate of water to hydrate was different under varying thermodynamic conditions, although the formation processes were similar. The conversion rate of methane hydrate in the 250-380 mu m sediment was greater than that in the 150-250 mu m sediment. However, the sediment grain size has no significant influence on the conversion rate of mixed gas hydrate

Distribution and isotopic composition of foraminifera at cold-seep Site 973-4 in the Dongsha area, northeastern South China Sea

A 1375-cm-long gravity core (Site 973-4) was acquired from the Dongsha cold seep area of the northeastern South China Sea (SCS). We measured its stable isotopes of planktonic foraminifera and investigated benthic foraminiferal assemblage compositions. Accelerator mass spectrometry C-14 analysis of planktonic foraminifera shows that some intervals are dated to Marine Isotope Stage (MIS) 3. Pulleniatina obliquiloculata has positive delta C-13 (0.25-1.25 parts per thousand) except for a negative carbon isotopic excursion (up to delta C-13 = 1.15 parts per thousand), but its light -carbon sources remain elusive. The benthic delta C-13 values (Uvigerina) of non -seep and cold-seep boreholes from the SCS have no systematic difference. Therefore, the benthic delta C-13 at Site 973-4 did not record the enhanced seepage activities (if occurred) during the last sea-level lowstand in the Dongsha area. In the pre-Holocene sediments, the foraminiferal assemblages have lower diversities, Shannon-Wiener indices, evenness indices, Simpson indices and higher calcareous proportions like typical cold-seep settings. The changes in oxygen levels (lower in the glacial period than those in the Holocene) indicated by foraminiferal indices reflect either bottom-water oxygen variations on the glacial-interglacial scale or enhanced seepage activities during the last glacial period