Development of Heterogeneous Photosensitized Transition Metal Oxide Water-Splitting Catalysts on Silica Support

The research presented in this manuscript describes the development of photosensitized inexpensive catalysts based on readily available materials. The investigation covers synthesis and characterization of photosensitizers based on porphyrins, mechanical and thermal coating of solid support with semiconducting transition metal oxides, photosensitization of the semiconducting layer, and characterization of the photoelectrochemical properties displayed by the new materials. The process of water oxidation is of primary interest here, with little emphasis put on reduction of protons to gaseous hydrogen. Photoelectrochemically produced protons serve as a probe of effectiveness of the catalysts. Several systems are described, and two catalysts are identified as the most efficient

Jointly Optimal Channel Pairing and Power Allocation for Multichannel Multihop Relaying

We study the problem of channel pairing and power allocation in a multichannel multihop relay network to enhance the end-to-end data rate. Both amplify-and-forward (AF) and decode-and-forward (DF) relaying strategies are considered. Given fixed power allocation to the channels, we show that channel pairing over multiple hops can be decomposed into independent pairing problems at each relay, and a sorted-SNR channel pairing strategy is sum-rate optimal, where each relay pairs its incoming and outgoing channels by their SNR order. For the joint optimization of channel pairing and power allocation under both total and individual power constraints, we show that the problem can be decoupled into two subproblems solved separately. This separation principle is established by observing the equivalence between sorting SNRs and sorting channel gains in the jointly optimal solution. It significantly reduces the computational complexity in finding the jointly optimal solution. It follows that the channel pairing problem in joint optimization can be again decomposed into independent pairing problems at each relay based on sorted channel gains. The solution for optimizing power allocation for DF relaying is also provided, as well as an asymptotically optimal solution for AF relaying. Numerical results are provided to demonstrate substantial performance gain of the jointly optimal solution over some suboptimal alternatives. It is also observed that more gain is obtained from optimal channel pairing than optimal power allocation through judiciously exploiting the variation among multiple channels. Impact of the variation of channel gain, the number of channels, and the number of hops on the performance gain is also studied through numerical examples.Comment: 15 pages. IEEE Transactions on Signal Processin

Orbital transfer vehicle concept definition and system analysis study, 1985. Volume 3: System and program trades

The key system and program trade studies performed to arrive at a preferred Orbital Transfer Vehicle (OTV) system concept and evolutionary approach to the acquisition of the requisite capabilites is documented. These efforts were expanded to encompass a Space Transportation Architecture Study (STAS) mission model and recommended unmanned cargo vehicle. The most important factors affecting the results presented are the mission model requirements and selection criteria. The reason for conducting the OTV concept definition and system analyses study is to select a concept and acquisition approach that meets a delivery requirement reflected by the mission model

MSAT-X electronically steered phased array antenna system

A low profile electronically steered phased array was successfully developed for the Mobile Satellite Experiment Program (MSAT-X). The newly invented cavity-backed printed crossed-slot was used as the radiating element. The choice of this element was based on its low elevation angle gain coverage and low profile. A nineteen-way radial type unequal power divider and eighteen three-bit diode phase shifters constitute the beamformer module which is used to scan the beams electronically. A complete hybrid mode pointing system was also developed. The major features of the antenna system are broad coverage, low profile, and fast acquisition and tracking performance, even under fading conditions. Excellent intersatellite isolation (better than 26 dB) was realized, which will provide good quality mobile satellite communication in the future

Radial honeycomb core

Core alleviates many limitations of conventional nacelle construction methods. Radical core, made of metals or nonmetals, is fabricated either by joining nodes and then expanding, or by performing each layer and then joining nodes. Core may also be produced from ribbons or strips with joined nodes or ribbons oriented in longitudinal planes

Free Energies of Isolated 5- and 7-fold Disclinations in Hexatic Membranes

We examine the shapes and energies of 5- and 7-fold disclinations in low-temperature hexatic membranes. These defects buckle at different values of the ratio of the bending rigidity, $\kappa$, to the hexatic stiffness constant, $K_A$, suggesting {\em two} distinct Kosterlitz-Thouless defect proliferation temperatures. Seven-fold disclinations are studied in detail numerically for arbitrary $\kappa/K_A$. We argue that thermal fluctuations always drive $\kappa/K_A$ into an ``unbuckled'' regime at long wavelengths, so that disclinations should, in fact, proliferate at the {\em same} critical temperature. We show analytically that both types of defects have power law shapes with continuously variable exponents in the ``unbuckled'' regime. Thermal fluctuations then lock in specific power laws at long wavelengths, which we calculate for 5- and 7-fold defects at low temperatures.Comment: LaTeX format. 17 pages. To appear in Phys. Rev.

Neogene grabens in southernmost Illinois

National Earthquake Hazards Reduction Program Award No. 1434-HQ-97-GR-03195Ope