2,857 research outputs found

    Cementation scenarios for New Zealand Cenozoic nontropical limestones

    Get PDF
    Cenozoic limestones are widely distributed in New Zealand, especially in the Oligocene-earliest Miocene in both islands, and the Pliocene-Pleistocene in North Island. A spectrum of limestone types exists, but all are skeletal-dominated (>70%), with usually <20% interparticle cement-matrix and <10% siliciclasts, and they have facies attributes typical of nontropical carbonates. The range of diagenetic features identified within the limestones is the basis for assigning them to a small number of ā€œend-memberā€ cementation classes that are inferred to be associated with four, broad, diagenetic settings

    Lithostratigraphy and depositional episodes of the Oligocene carbonate-rich Tikorangi Formation, Taranaki Basin, New Zealand

    Get PDF
    The subsurface Oligocene Tikorangi Formation is a unique and important oil producer in the onshore Waihapa-Ngaere Field, Taranaki Basin, being the only carbonate and fracture-producing reservoir within the basin. Core sample data from seven onshore wells (foredeep megafacies) and a single offshore well (basinal megafacies) are correlated with a suite of sonic and gamma-ray geophysical well log data to derive interpretative carbonate facies for the Tikorangi Formation. Four mixed siliciclastic-carbonate to carbonate facies have been defined: facies A-calcareous siliciclastite (75% carbonate). Single or interbedded combinations of these facies form the basis for identifying nine major lithostratigraphic units in the Tikorangi Formation that are correlatable between the eight wells in this study.The Tikorangi Formation accumulated across a shelf-slope-basin margin within a tectonically diversified basin setting, notably involving considerable off-shelf redeposition of sediment into a bounding foredeep. Analysis of gamma, sonic, and resistivity well logs identifies five major episodes of sedimentary evolution. Episode I comprises retrogradational siliciclastic-dominated redeposited units associated with foredeep subsidence. Episode II is a continuation of episode I retrogradation, but with increased mass-redeposited carbonate influx during accelerated foredeep subsidence and relative sea-level rise, the top marking the maximum flooding surface. Episode III involves a progradational sequence comprising relatively pure redeposited carbonate units associated with declining subsidence rates and minimal siliciclastic input, with movement of facies belts basinward. Episode IV consists of prograding aggradation involving essentially static facies belts dominated by often thick, periodically mass-emplaced, carbonate-rich units separated by thin background siliciclastic shale-like units. Episode V is a retrogradational sequence marking the reintroduction of siliciclastic material into the basin following uplift of Mesozoic basement associated with accelerated compressional tectonics along the Australia-Pacific plate boundary, initially diluting and ultimately extinguishing carbonate production factories and terminating deposition of the Tikorangi Formation

    Petrogenesis of the Tikorangi Formation fracture reservoir, Waihapa-Ngaere Field, Taranaki Basin

    Get PDF
    The subsurface mid-Tertiary Tikorangi Formation is the sole limestone and the only fracture-producing hydrocarbon reservoir within Taranaki Basin. This study, based on core material from seven wells in the onshore Waihapa/Ngaere Field, uses a range of petrographic (standard, CL, UV, SEM) and geochemical techniques (stable isotope, trace element data, XRD) to unravel a complex diagenetic history for the Tikorangi Formation. A series of eight major geological-diagenetic events for the host rock and fracture systems have been established, ranging from burial cementation through to hydrocarbon emplacement within mineralized fractures. For each diagenetic event a probable temperature field has been identified which, combined with a geohistory plot, has enabled the timing of events to be determined. This study has shown that the Tikorangi Formation comprises a complex mixed siliciclastic-carbonate-rich sequence of rocks that exhibit generally tight, pressure-dissolved, and well cemented fabrics with negligible porosity and permeability other than in fractures. Burial cementation of the host rocks occurred at temperatures of 27-37Ā°C from about 0.5-1.0 km burial depths. Partial replacement dolomitisation occurred during late burial diagenesis at temperatures of 36-50Ā°C and at burial depths of about 1.0 km, without any secondary porosity development. Fracturing occurred after dolomitisation and was associated with compression and thrusting on the Taranaki Fault. The location of more carbonate/dolomite-rich units may have implications for the location of better-developed fracture network systems and for hydrocarbon prospectivity and production. Hydrocarbon productivity has been ultimately determined by original depositional facies, diagenesis, and deformation. Within the fracture systems, a complex suite of vein calcite, dolomite, quartzine, and celestite minerals has been precipitated prior to hydrocarbon emplacement, which have substantially healed and reduced fracture porosities and permeabilities. The occurrence of multiple vein mineral phases, collectively forming a calcite/dolomite-celestite-quartzine mineral assemblage, points to fluid compositions varying both spatially and temporally. The fluids responsible for vein mineralisation in the Tikorangi Formation probably involved waters of diverse origins and compositions. Vein mineralisation records a history of changing pore fluid chemistry and heating during burial, punctuated by changes in the relative input and mixing of downward circulating meteoric and upwelling basinal fluids. A sequence of mineralisation events and their probable burial depth/temperature fields have been defined, ranging from temperatures of 50-80Ā°C and burial depths of 1.0-2.3 km. Hydrocarbon emplacement has occurred over the last 6 m.y. following the vein mineralization events. The Tikorangi Formation must continue to be viewed as a potential fracture reservoir play within Taranaki Basin

    Lithostratigraphy and depositional episodes of the Oligocene carbonate-rich Tikorangi Formation, Taranaki Basin, New Zealand

    Get PDF
    The subsurface Oligocene Tikorangi Formation is a unique and important oil producer in the onshore Waihapa-Ngaere Field, Taranaki Basin, being the only carbonate and fracture-producing reservoir within the basin. Core sample data from seven onshore wells (foredeep megafacies) and a single offshore well (basinal megafacies) are correlated with a suite of sonic and gamma-ray geophysical well log data to derive interpretative carbonate facies for the Tikorangi Formation. Four mixed siliciclastic-carbonate to carbonate facies have been defined: facies A-calcareous siliciclastite (75% carbonate). Single or interbedded combinations of these facies form the basis for identifying nine major lithostratigraphic units in the Tikorangi Formation that are correlatable between the eight wells in this study.The Tikorangi Formation accumulated across a shelf-slope-basin margin within a tectonically diversified basin setting, notably involving considerable off-shelf redeposition of sediment into a bounding foredeep. Analysis of gamma, sonic, and resistivity well logs identifies five major episodes of sedimentary evolution. Episode I comprises retrogradational siliciclastic-dominated redeposited units associated with foredeep subsidence. Episode II is a continuation of episode I retrogradation, but with increased mass-redeposited carbonate influx during accelerated foredeep subsidence and relative sea-level rise, the top marking the maximum flooding surface. Episode III involves a progradational sequence comprising relatively pure redeposited carbonate units associated with declining subsidence rates and minimal siliciclastic input, with movement of facies belts basinward. Episode IV consists of prograding aggradation involving essentially static facies belts dominated by often thick, periodically mass-emplaced, carbonate-rich units separated by thin background siliciclastic shale-like units. Episode V is a retrogradational sequence marking the reintroduction of siliciclastic material into the basin following uplift of Mesozoic basement associated with accelerated compressional tectonics along the Australia-Pacific plate boundary, initially diluting and ultimately extinguishing carbonate production factories and terminating deposition of the Tikorangi Formation

    Petrologic evidence for earliest Miocene tectonic mobility on eastern Taranaki Basin margin

    Get PDF
    At Gibsons Beach on the west coast of central North Island, the earliest Miocene (Waitakian) Otorohanga Limestone, the top-most formation in the Te Kuiti Group, is unconformably overlain on an undulating, locally channelised erosion surface by the Early Miocene (Otaian) Papakura Limestone at the base of the Waitemata Group. The basal facies of the Papakura Limestone is a conglomerate composed exclusively of tightly packed pebble- to cobble-sized clasts of skeletal limestone sourced from the underlying Otorohanga Limestone. This petrographic and geochemical study demonstrates that the Otorohanga Limestone was partially lithified during marine and shallow-burial cementation at subsurface depths down to a few tens of metres prior to uplift, erosion and cannibalisation of the limestone clasts into the Papakura Limestone. Strontium isotope dating of fossils from both the Otorohanga and Papakura Limestones at Gibsons Beach yield comparable ages of about 22 Ma, close to the Waitakian/Otaian boundary, indicating very rapid tectonic inversion and erosion of the section occurred in the earliest Miocene. We envisage the clasts of Otorohanga Limestone were sourced from a proximal shoreline position and redeposited westwards by episodic debris flows onto a shallow-shelf accumulating mixed siliciclastic-skeletal carbonate deposits of the Papakura Limestone. Subsequent burial of both limestones by rapidly accumulating Waitemata Group sandstone and flysch instigated precipitation of widespread burial cements from pressure dissolution of carbonate material at subsurface depths from about 100 m to 1.0 km. The vertical tectonic movements registered at Gibsons Beach can be related to the oblique compression associated with the development of the Australian-Pacific plate boundary through New Zealand at about this time and coincide with overthrusting of basement into Taranaki Basin between mid-Waitakian (earliest Miocene) and Altonian (late Early Miocene) times

    Mobility as a Service for the older population: a transport solution to land use changes in essential services?

    Get PDF
    Land use changes in relation to everyday services are resulting in centralisation of local services from mixed land use town centres to single land use destinations on the edge of cities. Technology advances are disrupting the provision of local community services such as local shops and local health care. Cost considerations and the benefits achieved by economies of scale are driving the land use changes which are changing the landscape of service provision. Whereas hospitals, for example, were typically located in city centres they are now more often in peripheral locations. For many sections of society, these changes have offered better convenience and higher quality of service. However, these changes have both spatial and horizontal equity impacts, particularly for older people and particularly for areas of lower density where accessibility will significantly decline. This paper explores the potential contribution of Mobility as a Service (MaaS) in promoting greater equity for older people using Community Transport (CT) as the service co-ordinator. The travel needs and behaviour of older people are reviewed as well as the contribution of flexible transport services towards meeting these needs. Drawing on discussions with a group of CT operators in Australia the key characteristics of the MaaS model are explored in the context of older people to ascertain whether CT acting as the service co-co-ordinator fits the MaaS model. A series of MaaS packages are proposed to show how the model could be delivered in practice. The paper concludes that as a business model, MaaS for CT could be one way of ameliorating the lack of equity for the old and frail age group brought about by land use changes in essential services

    Haplotypes at the Tas2r locus on distal chromosome 6 vary with quinine taste sensitivity in inbred mice

    Get PDF
    BACKGROUND: The detection of bitter-tasting compounds by the gustatory system is thought to alert animals to the presence of potentially toxic food. Some, if not all, bitter stimuli activate specific taste receptors, the T2Rs, which are expressed in subsets of taste receptor cells on the tongue and palate. However, there is evidence for both receptor-dependent and -independent transduction mechanisms for a number of bitter stimuli, including quinine hydrochloride (QHCl) and denatonium benzoate (DB). RESULTS: We used brief-access behavioral taste testing of BXD/Ty recombinant inbred (RI) mouse strains to map the major quantitative trait locus (QTL) for taste sensitivity to QHCl. This QTL is restricted to a ~5 Mb interval on chromosome 6 that includes 24 genes encoding T2Rs (Tas2rs). Tas2rs at this locus display in total 307 coding region single nucleotide polymorphisms (SNPs) between the two BXD/Ty RI parental strains, C57BL/6J (quinine-sensitive) and DBA/2J (quinine insensitive); approximately 50% of these mutations are silent. Individual RI lines contain exclusively either C57BL/6J or DBA/2J Tas2r alleles at this locus, and RI lines containing C57BL/6J Tas2r alleles are more sensitive to QHCl than are lines containing DBA/2J alleles. Thus, the entire Tas2r cluster comprises a large haplotype that correlates with quinine taster status. CONCLUSION: These studies, the first using a taste-salient assay to map the major QTL for quinine taste, indicate that a T2R-dependent transduction cascade is responsible for the majority of strain variance in quinine taste sensitivity. Furthermore, the large number of polymorphisms within coding exons of the Tas2r cluster, coupled with evidence that inbred strains exhibit largely similar bitter taste phenotypes, suggest that T2R receptors are quite tolerant to variation

    Fluorescence anisotropy of diphenylhexatriene and its cationic Trimethylamino derivative in liquid dipalmitoylphosphatidylcholine liposomes: opposing responses to isoflurane

    Get PDF
    <p>Abstract</p> <p>Background</p> <p>The mechanism of action of volatile general anesthetics has not yet been resolved. In order to identify the effects of isoflurane on the membrane, we measured the steady-state anisotropy of two fluorescent probes that reside at different depths. Incorporation of anesthetic was confirmed by shifting of the main phase transition temperature.</p> <p>Results</p> <p>In liquid crystalline dipalmitoylphosphatidylcholine liposomes, isoflurane (7-25 mM in the bath) increases trimethylammonium-diphenylhexatriene fluorescence anisotropy by ~0.02 units and decreases diphenylhexatriene anisotropy by the same amount.</p> <p>Conclusions</p> <p>The anisotropy data suggest that isoflurane decreases non-axial dye mobility in the headgroup region, while increasing it in the tail region. We propose that these results reflect changes in the lateral pressure profile of the membrane.</p
    • ā€¦
    corecore