Fossil-Fuel-Fired Power Plant

A power plant includes a boiler, a stream turbine generator, a post combustion processing system, a feed water regeneration processing system and a heat exchanger. Heat from the heat exchanger is used to regenerate (a) a reagent that absorbs carbon dioxide from flue gas and (b) a water-lean desiccant used to increase plant operating efficiency

Contaminant-Tolerant Solvent and Stripping Chemical and Process for Using Same for Carbon Capture from Combustion Gases

A contaminant-tolerant hybrid scrubbing solvent is provided for post-combustion CO2 capture and removal, the scrubbing solvent including an amine and a low fraction of ammonia. A stripping carrier having a low latent energy is included for solvent regeneration. In one embodiment, the amine is MEA and the stripping chemical having low latent energy is pentane or an isomer thereof. Processes and apparatus for CO2 removal from post-combustion gases and for solvent regeneration are described

Method for Removing CO\u3csub\u3e2\u3c/sub\u3e from Coal-Fired Power Plant Flue Gas Using Ammonia as the Scrubbing Solution, with a Chemical Additive for Reducing NH\u3csub\u3e3\u3c/sub\u3e Losses, Coupled with a Membrane for Concentrating the CO\u3csub\u3e2\u3c/sub\u3e Stream to the Gas Stripper

A method for removing and capturing carbon dioxide from a fluid stream includes the steps of exposing the fluid stream to an aqueous scrubbing solution that removes and holds carbon dioxide from the fluid stream, passing the aqueous scrubbing solution through a membrane in order to separate excess water from the scrubbing solution and increase the concentration of carbon dioxide in the scrubbing solution, heating the scrubbing solution having an increased concentration of carbon dioxide so as to release carbon dioxide gas and recycling the scrubbing solution. A carbon dioxide capture apparatus includes a carbon dioxide scrubber, a membrane downstream from the scrubber for separating water and concentrating carbon dioxide in a scrubbing solution and a stripper vessel

Apparatus and Method for Triboelectrostatic Separation

A triboelectrostatic separation apparatus includes a separator with an inlet, a separation chamber, first and second electrodes, a variable voltage source for applying respective positive and negative voltage potentials to the electrodes, a pair of separated particle outlets and a curtain gas flow generation system. The curtain gas flow generation system includes a source of curtain gas at positive pressure, a metering valve for matching curtain gas flow velocity to particle flow velocity and flow straighteners for eliminating eddy currents. A method for separating electrostatically charged particles is also described

Particle Separation System Using Parallel Multistage Electrostatic Separators

An electrostatic separation apparatus includes of a plurality of separators is provided for separating a particle mixture into two constituent species. Each separator includes one and preferably a plurality of modular separation stages. Each stage of the separator includes a pair of separation subchambers each having an electric field zone for drawing selected charged particles from the particle mixture. A curtain gas flow is provided for each subchamber to entrain and carry the selected charged particles drawn from the particle mixture in the electric field zone to a collector associated with each subchamber for recovery. The inlets for the particle mixture and curtain gas flows are adapted to straighten and smooth the respective flows to reduce turbulence in the separation subchambers and improve separation efficiency. The particle flow remaining after the first separation stage passes through an outlet to a second stage, a recycle line, or if further separation is deemed unnecessary, to a collection device for recovery. The apparatus may include a plurality of single or multistage separators arranged in parallel such that simultaneous operation is possible. Further, the apparatus may be included as part of an overall separation system

Triboelectric Separator with Mixing Chamber and Pre-Separator

A triboelectrostatic separation apparatus includes a mixing chamber having opposed first and second charging ports, a separator having a separation chamber, first and second electrodes, and a variable voltage source for applying respective positive and negative voltage potentials to the electrodes. First and second particle streams are delivered through the first and second charging ports resulting in the impingement of the particle streams upon each other within the mixing chamber, thus enhancing the electrostatic charging of the particles contained within the particle streams. The apparatus may also include a pre-separator having a pre-separation chamber, a charged particle collection chamber and a plurality of feed passageways providing fluid communication between the pre-separation and the charged particle collection chambers. As a result of imparting electrical charges upon the particles, an electric field exists within the pre-separator allowing certain particles to be repelled/drawn through the passageways into the charged particle collection chamber. A method for separating electrostatically charged particles is also described

Separation of Fischer-Tropsch Wax Products from Ultrafine Iron Catalyst Particles

A fundamental filtration study was started to investigate the separation of Fischer-Tropsch Synthesis (FTS) liquids from iron-based catalyst particles. Slurry-phase FTS in slurry bubble column reactor systems is the preferred mode of operation since the reaction is highly exothermic. Consequently, heavy wax products in one approach may be separated from catalyst particles before being removed from the reactor system. Achieving an efficient wax product separation from iron-based catalysts is one of the most challenging technical problems associated with slurry-phase iron-based FTS and is a key factor for optimizing operating costs. The separation problem is further compounded by attrition of iron catalyst particles and the formation of ultra-fine particles

Electrostatic Particle Separation System, Apparatus, and Related Method

An electrostatic separation apparatus or system is provided for separating a particle mixture into two constituent species. The system includes a distributor for differentially tribocharging the particle species forming the mixture and supplying the charged mixture to a plurality of electrostatic separation cells. Each cell includes at least one separator having an inlet, a separation chamber having an electric field zone for drawing selected charged particles from the particle mixture, a collector, and a transition outlet. The length of the electric field zone is selectively adjustable for varying the charged particle drawing action. A curtain gas flow introduced into the separation chamber carries the selected charged particles drawn from the particle mixture in the electric field zone to the collector. Flow vanes or straighteners are provided for both the particle mixture flow and the curtain gas flow to reduce turbulence in the separation chamber and improve separation efficiency. The collector includes a discharge outlet for discharging the selected charged particles to a first collection bin. The transition outlet receives the remaining particle flow and delivers it to a second collection bin for recovery or to a second separator to collect any remaining selected charged particles. The transition outlet reforms the flow to create turbulence to further tribocharge the particles prior to entering the second separator. A related method of particle separation is also disclosed

Separation of Fischer-Tropsch Wax Products from Ultrafine Iron Catalyst Particles

In this reporting period, a study of ultra-fine iron catalyst filtration was initiated to study the behavior of ultra-fine particles during the separation of Fischer-Tropsch Synthesis (FTS) liquids filtration. The overall focus of the program is with slurry-phase FTS in slurry bubble column reactor systems. Hydrocarbon products must be separated from catalyst particles before being removed from the reactor system. An efficient wax product/catalyst separation system is a key factor for optimizing operating costs for iron-based slurry-phase FTS. Previous work has focused on catalyst particle attrition and the formation of ultra-fine iron carbide and/or carbon particles. With the current study, we are investigating how the filtration properties are affected by these chemical and physical changes of the catalyst slurry during activation/synthesis. The change of particle size during the slurry-phase FTS has monitored by withdrawing catalyst sample at different TOS. The measurement of dimension of the HRTEM images of samples showed a tremendous growth of the particles. Carbon rims of thickness 3-6 nm around the particles were observed. This growth in particle size was not due to carbon deposition on the catalyst. A conceptual design and operating philosophy was developed for an integrated wax filtration system for a 4 liter slurry bubble column reactor to be used in Phase II of this research program. The system will utilize a primary inertial hydroclone followed by a Pall Accusep cross-flow membrane. Provisions for cleaned permeate back-pulsing will be included to as a flux maintenance measure

SEPARATION OF FISCHER-TROPSCH WAX PRODUCTS FROM ULTRAFINE IRON CATALYST PARTICLES

In this reporting period, a fundamental filtration study was started to investigate the separation of Fischer-Tropsch Synthesis (FTS) liquids from iron-based catalyst particles. Slurry-phase FTS in slurry bubble column reactor systems is the preferred mode of production since the reaction is highly exothermic. Consequently, heavy wax products must be separated from catalyst particles before being removed from the reactor system. Achieving an efficient wax product separation from iron-based catalysts is one of the most challenging technical problems associated with slurry-phase FTS. The separation problem is further compounded by catalyst particle attrition and the formation of ultra-fine iron carbide and/or carbon particles. Existing pilot-scale equipment was modified to include a filtration test apparatus. After undergoing an extensive plant shakedown period, filtration tests with cross-flow filter modules using simulant FTS wax slurry were conducted. The focus of these early tests was to find adequate mixtures of polyethylene wax to simulate FTS wax. Catalyst particle size analysis techniques were also developed. Initial analyses of the slurry and filter permeate particles will be used by the research team to design improved filter media and cleaning strategies