Comparative Review on Information and Communication Technology Issues in Education Sector of Developed and Developing Countries: A Case Study About Pakistan

The use of information and communication technology is very beneficial in the education sector because it can enhance the quality of education. However, the implementation of ICT in the education sector of developed and developing countries is a challenging task. This paper explains the comparative study of ICT issues in the education sector of developed and developing countries. In particular, we compare issues between Pakistan and high-tech countries. Our study reveals the fact that the education sector is facing numerous ICT problems that are based on culture, finance, management, infrastructure, lack of training, lack of equipment, teacher’s refusal, and ethical issues. At the end of this paper, various issues faced by the implementation of ICT in the education sector of Pakistan have been categorized into various types, namely, infrastructure, lack of IT professionals, lack of high-speed internet and equipment. Our research is based on five key research questions related to ICT issues. We used a mixed approach where the results of this study can be used as a set of guidelines to help make the learning environment technology-oriented, fast, planned, and productive. Future directions are also given at the end of this paper

A study to assess knowledge and attitude of infertile Kashmiri couples

Background: Infertility is defined as the inability to conceive naturally after one year of regular unprotected sexual intercourse. The chance to conceive depends on multiple factors like the length of sexual intercourse, frequency of coitus and age of couples. This could be due to male as well as female factors and deficiencies.Methods: This is a cross sectional observational study conducted on infertility patients. A fertility questionnaire was designed for both the partners with questions covering knowledge and attitude towards infertility.Results: A total 100 couples were selected in which prevalence of primary and secondary infertility was 72% and 28% respectively. The mean duration of infertility was 3 years. On scoring their level of knowledge, 52% had inadequate knowledge, 44% had moderate knowledge and 4% had adequate knowledge. There was no statistically significant difference in the knowledge in relation to their educational qualification and type of infertility among participants.Conclusions: Infertility is common problem affecting 10-15% of the population. The knowledge about infertility and its risk factors is generally limited among the participants, in spite of their educational status

Validity of intracerebral haemorrhge score in predicting prognosis of hemorrhagic stroke

Stroke is a common neurological disorder, leading cause of death and disability worldwide. Intra cerebral hemorrhage comprises of 10-15% of all strokes but associated with high risk of morbidity and mortality than cerebral infraction .The ICH Score is a good prognostic tool calculated very easily, when it is used to predict 30 day morality. Objective:To determine the validity of Intracerebral hemorrhagic score in predicting prognosis (adverse outcome or death) in patients of hemorrhagic stroke.Material&Methods:This case series study was carried out at department of medicine Liaquat medical University Hospital Jamshoro and Hyderabad from June 16th 2012 to December 15th 2012.Eighty nine 89 patients were enrolled in the study, non-probability consecutive sampling technique was applied and data was collected after inclusion and exclusion criteria and structured proforma were designed for study.Results: Out of 89 patients 56 (62.9%) were male and mean age of the patients in our study was 65.14 years .In 32(36%) patients ICH score was ≥ 3 while 57 (64%) patients had ICH score was \u3c 3. Out of total 32 patients who had ICH score ≥ 3, Adverse outcome i.e. death occurred in 25 (78.12%) patients and males were 16(80%) and 9(75%) were female patients.Conclusion: Frequency of adverse outcome (death) was found in 28.1% while ICH score predicted adverse outcome (death) in 36.1%. ICH score correctly predicted 77.77% adverse outcome, therefore we can conclude that ICH score is useful scale to predict mortality in patients suffering from intracerebral hemorrhage

Clinicopathological pattern and risk factors of carcinoma breast in younger age group

Worldwide, breast cancer is the most frequently diagnosed life-threatening cancer and the leading cause of cancer death among women. Approximately 7% of all breast cancers are diagnosed in women <40 years of age. Young age at diagnosis influences prognosis negatively as they present with more advanced disease at diagnosis and a poorer 5-year survival than older patients. The present study includes breast cancer patients in the age group of 18 to 40 years to enrich our knowledge about clinical presentation and pathological characteristics of breast cancer. To find out the clinical presentation and pathological characteristics of breast cancer among the young age group.  This cross-sectional study was done over 100 cases of histopathologically proven breast cancer from structured Questionnaire was used as data collection tool. Mean age was 33.89 years. Among the respondents 88% are married. Among the total studied population 61 respondents had the history of oral contraceptive pill use. Family history of cancer presents in 13.0% respondents and absent in 87.0% respondents. Among the respondents 95% patients presented with lump in the breast. 97.0% had invasive carcinoma 90% were invasive ductal carcinoma in which 46.0% were moderately differentiated. 51.0% patients were in the stage IIa and stage IIb

The Contrasting Character of Early and Late Transition Metal Fluorides as Hydrogen Bond Acceptors

The association constants and enthalpies for the binding of hydrogen bond donors to group 10 transition metal complexes featuring a single fluoride ligand (trans-[Ni(F)(2-C5NF4)(PR3)2], R = Et 1a, Cy 1b, trans-[Pd(F)(4-C5NF4)(PCy3)2] 2, trans-[Pt(F){2-C5NF2H(CF3)}(PCy3)2] 3 and of group 4 difluorides (Cp2MF2, M = Ti 4a, Zr 5a, Hf 6a; Cp2MF2, M = Ti 4b, Zr 5b, Hf 6b) are reported. These measurements allow placement of these fluoride ligands on the scales of organic H-bond acceptor strength. The H-bond acceptor capability β (Hunter scale) for the group 10 metal fluorides is far greater (1a 12.1, 1b 9.7, 2 11.6, 3 11.0) than that for group 4 metal fluorides (4a 5.8, 5a 4.7, 6a 4.7, 4b 6.9, 5b 5.6, 6b 5.4), demonstrating that the group 10 fluorides are comparable to the strongest organic H-bond acceptors, such as Me3NO, whereas group 4 fluorides fall in the same range as N-bases aniline through pyridine. Additionally, the measurement of the binding enthalpy of 4-fluorophenol to 1a in carbon tetrachloride (?23.5 ± 0.3 kJ mol-1) interlocks our study with Laurence's scale of H-bond basicity of organic molecules. The much greater polarity of group 10 metal fluorides than that of the group 4 metal fluorides is consistent with the importance of p?-d? bonding in the latter. The polarity of the group 10 metal fluorides indicates their potential as building blocks for hydrogen-bonded assemblies. The synthesis of trans-[Ni(F){2-C5NF3(NH2)}(PEt3)2], which exhibits an extended chain structure assembled by hydrogen bonds between the amine and metal-fluoride groups, confirms this hypothesis

The Contrasting Character of Early and Late Transition Metal Fluorides as Hydrogen Bond Acceptors

The association constants and enthalpies for the binding of hydrogen bond donors to group 10 transition metal complexes featuring a single fluoride ligand (trans-[Ni(F)(2-C5NF4)(PR3)2], R = Et 1a, Cy 1b, trans-[Pd(F)(4-C5NF4)(PCy3)2] 2, trans-[Pt(F){2-C5NF2H(CF3)}(PCy3)2] 3 and of group 4 difluorides (Cp2MF2, M = Ti 4a, Zr 5a, Hf 6a; Cp*2MF2, M = Ti 4b, Zr 5b, Hf 6b) are reported. These measurements allow placement of these fluoride ligands on the scales of organic H-bond acceptor strength. The H-bond acceptor capability β (Hunter scale) for the group 10 metal fluorides is far greater (1a 12.1, 1b 9.7, 2 11.6, 3 11.0) than that for group 4 metal fluorides (4a 5.8, 5a 4.7, 6a 4.7, 4b 6.9, 5b 5.6, 6b 5.4), demonstrating that the group 10 fluorides are comparable to the strongest organic H-bond acceptors, such as Me3NO, whereas group 4 fluorides fall in the same range as N-bases aniline through pyridine. Additionally, the measurement of the binding enthalpy of 4-fluorophenol to 1a in carbon tetrachloride (−23.5 ± 0.3 kJ mol–1) interlocks our study with Laurence’s scale of H-bond basicity of organic molecules. The much greater polarity of group 10 metal fluorides than that of the group 4 metal fluorides is consistent with the importance of pπ–dπ bonding in the latter. The polarity of the group 10 metal fluorides indicates their potential as building blocks for hydrogen-bonded assemblies. The synthesis of trans-[Ni(F){2-C5NF3(NH2)}(PEt3)2], which exhibits an extended chain structure assembled by hydrogen bonds between the amine and metal-fluoride groups, confirms this hypothesis

Adsorption Thermodynamics, Modeling, and Kinetics Studies for the Removal of Lead Ions Using ZnO Nanorods

In the present investigation, zinc oxide nanorods (ZnO-NR) were synthesized via the hydrothermal method using ZnCl$_2$ as a zinc ion precursor in the presence of cetyltrimethylammonium bromide. Synthesized ZnO-NR was featured using advanced techniques including XRD, PL, SEM, and UV-visible spectroscopy. The role of these assynthesized ZnO-NR was evaluated for the sequestration of lead ions in batch mode. The elimination of lead ions was achieved at pH 6-7 using a 0.06 g adsorbent dose, 25 min contact time, 25 mg/L initial lead ion concentration, 323 K temperature, and 200 rpm agitation speed. A thermodynamic study revealed the endothermic nature of lead ion sequestration onto ZnO-NR. The lead ion sequestration followed kinetic (pseudo-second-order) and isotherm (Langmuir) models. The lead ions were eliminated up to 142 mg/g at the optimum level of affecting variables. The ZnO-NR might be a potential adsorbent for lead ion removal from industrial effluents

Comparison of dosimetric parameters between intensity modulated and three-dimensional conformal radiotherapy planning for adjuvant therapy of gastric cancer

Background: Adjuvant chemoradiotherapy is the standard treatment for gastric carcinoma, but the optimal radiation modality remains uncertain. This study aimed to compare intensity-modulated radiotherapy (IMRT) and three-dimensional conformal radiotherapy (3D-CRT) in terms of dosimetry for adjuvant gastric cancer treatment. Methods: 21 patients with stage IIB-IIIC gastric cancer, treated between January and June 2021, underwent surgery followed by adjuvant chemoradiation with both IMRT and 3D-CRT plans. Dosimetric parameters were calculated for the planned target volume (PTV) and organs at risk (OAR). Results: Both IMRT and 3D-CRT provided comparable PTV coverage. However, IMRT significantly improved kidney sparing, reducing the mean V20 value by 23% (p=0.01) for the right kidney and 26% (p=0.02) for the left kidney compared to 3D-CRT. IMRT also decreased the mean irradiated volume for both kidneys and the liver, as well as the V30 value for the liver, although these differences were not statistically significant. The dosimetric parameters for the spinal cord were comparable between IMRT and 3D-CRT plans. Conclusions: IMRT demonstrated better kidney sparing compared to 3D-CRT in adjuvant radiotherapy for gastric cancer, while PTV coverage was similar. Long-term follow-up is necessary to assess clinical outcomes and local recurrence rates for both treatment plans