1,605 research outputs found
Superfluidity in a Doped Helium Droplet
Path Integral Monte Carlo calculations of the superfluid density throughout
^4He droplets doped with linear impurities (HCN)_n are presented. After
deriving a local estimator for the superfluid density distribution, we find a
decreased superfluid response in the first solvation layer. This effective
normal fluid exhibits temperature dependence similar to that of a
two-dimensional helium system.Comment: 4 pages, 6 figure
Helium nanodroplet isolation ro-vibrational spectroscopy: methods and recent results
In this article, recent developments in HElium NanoDroplet Isolation (HENDI)
spectroscopy are reviewed, with an emphasis on the infrared region of the
spectrum. Topics discussed include experimental details, comparison of
radiation sources, symmetry issues of the helium solvation structure, sources
of line broadening, changes in spectroscopic constants upon solvation, and
applications including formation of novel chemical structures.Comment: 24 pages, 8 figures, 3 tables; to be published in the Journal of
Chemical Physic
A superfluid hydrodynamic model for the enhanced moments of inertia of molecules in liquid 4He
We present a superfluid hydrodynamic model for the increase in moment of
inertia, , of molecules rotating in liquid He. The static
inhomogeneous He density around each molecule (calculated using the Orsay-Paris
liquid He density functional) is assumed to adiabatically follow the
rotation of the molecule. We find that the values created by the
viscousless and irrotational flow are in good agreement with the observed
increases for several molecules [ OCS, (HCN), HCCCN, and HCCCH ]. For
HCN and HCCH, our model substantially overestimates . This is likely
to result from a (partial) breakdown of the adiabatic following approximation.Comment: 4 pages, 1 eps figure, corrected version of published paper. Erratum
has been submitted for change
Traveling-wave deceleration of SrF molecules
We report on the production, deceleration and detection of a SrF molecular
beam. The molecules are captured from a supersonic expansion and are
decelerated in the X state. We demonstrate the removal
of up to 40% of the kinetic energy with a 2 meter long modular traveling-wave
decelerator. Our results demonstrate a crucial step towards the preparation of
ultracold gases of heavy diatomic molecules for precision spectroscopy
The dynamics of CO production from the photolysis of acetone across the whole S <inf>1</inf>← S <inf>0</inf>absorption spectrum: Roaming and triple fragmentation pathways
The unimolecular photodissociation dynamics of acetone spanning the entire S1 ← S0 absorption spectrum have been reinvestigated, with a focus on mechanisms that produce CO. At excitation wavelengths of λ > 305.8 nm, all photoproducts are formed on the S0 state after internal conversion. A roaming mechanism forming C2H6 + CO is active in the window λ = 311.2-305.8 nm. From λ = 305.8 to 262 nm, little or no CO is produced with the photochemistry dominated by the Norrish-type I C-C bond cleavage on the lowest excited triplet state, T1. At higher energy (λ < 262 nm), an increasing fraction of CH3CO radicals from the primary reaction have sufficient internal energy to spontaneously decompose to CH3 + CO. A new model is presented to account for the kinetic energy distribution of the secondary CH3 radical, allowing us to determine the height of the energetic barrier to CH3CO decomposition as 68 ± 4 kJ mol-1, which lies midway between previous measurements. The fraction of CO from triple fragmentation rises smoothly from 260 to 248 nm. We see no evidence of the return of roaming, or any other S0 reaction, in this higher energy region of the first electronic absorption band
The Structure and Management of Conflict: Fighting or Defending the Status Quo
Although conflict and negotiation studies have examined symmetrical structures in which both parties want change, or asymmetrical structures in which one party wants change and the other to maintain the status quo, no research provided a direct comparison of both structures. Two experiments were conducted to fill this void. Results show that in asymmetrical structures challengers engage in more problem solving and more contending, have less of a loss frame and perceive less control than defendants, and are perceived be less successful. In symmetrical structures, behavior and attitudes of parties are more alike and there is more reciprocation of problem solving and yielding. Furthermore, findings reveal that challengers see their defendant as less friendly and more dominant than defendants see their challengers. Finally, no evidence was obtained that social value orientation moderates these effects. Implications for conflict theory and research, and for third party interventions in symmetrical versus asymmetrical conflicts, are discussed
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