Thermally induced behavior of the K-exchanged erionite. A further step in understanding the structural modifications of the erionite group upon heating

Fibrous erionite is a naturally occurring zeolite considered to be highly carcinogenic upon inhalation, even more than crocidolite. Since no iron is typically present in erionite, its toxicity has been attributed to ion-exchanged Fe participating in Fenton chemistry. Recently, a study aimed at investigating possible fiber inactivation routes surprisingly showed that, despite having completely occluded all available pores with K ions, the erionite-Na sample preserved the property to upload Fe (II) within the structure. In this work, the thermal behavior of the K-exchanged erionite-Na was investigated by TG/ DSC and in situ XRPD analyses in order to provide relevant information for modeling the thermally induced behavior of the erionite group. Rietveld refinement results evidenced a general trend of cell parameters and volume with temperature similar to that observed for erionite-K from Rome (Oregon, USA). However, the dependence of Tdehydrand Tbreakfrom Si/Si+Al ratio observed in zeolites (high Si content favours a lower Tdehydrand a higher Tbreak) is not observed, possibly due to the effect of the relevant amount of large K ions dispersed within the erionite cage, acting as reinforcing blocks for the framework. Heating produces a progressive emptying of the Ca sites, common effect previously observed in erionite samples showing different chemistry. In addition, K1 s.s. remains unchanged evidencing the absence of any “internal ion exchange” process, whereas s.s. at K2 increases in the range 438-573 K and then slowly decreases in the range 700-1218 K. Both Rietveld and DSC data suggest the motion of K ions from OW sites toward the walls of the erionite cavity during dehydration

Identifying Unconventional E6_{\bf 6} Models at e+e−e^+ e^- Colliders

Recently it was shown that, in the framework of superstring inspired \E models, the presence of generation dependent discrete symmetries allows us to construct a phenomenologically viable class of models in which the three generations of fermions do not have the same embedding within the fundamental {\bf 27} dimensional representation of E$_6$. In this scenario, these different embeddings of the conventional fermions imply that the left-handed charged leptons and the right-handed $d$-type quarks are coupled in a non--universal way to the new neutral gauge bosons $(Z_\theta)$ present in these models. It was also shown that a unique signature for this scenario, would be a deviation from unity for the ratio of cross sections for the production of two different lepton species in $e^+e^-$ annihilation. However, several different scenarios are possible, depending on the particular assignment chosen for $e_L$, $\mu_L$ and $\tau_L$ and for the right-handed $d$-type quarks, as well as on the type of $Z_\theta$ boson. Such scenarios can not be disentangled from one another by means of cross section measurements alone. In this paper we examine the possibility of identifying the pattern of embeddings through measurements of polarized and unpolarized asymmetries for fermion pair-production at the 500 GeV $e^+e^-$ Next Linear Collider (NLC). We show that it will be possible to identify the different patterns of unconventional assignments for the left-handed leptons and for the $b_R$ quark, for $Z_\theta$ masses as large as $\sim 1.5$ TeV.Comment: Plain Tex, 15 pages, + 9 figure available upon request ([email protected] or [email protected]), UM-TH 93--1

Supersymmetric Leptogenesis

We study leptogenesis in the supersymmetric standard model plus the seesaw. We identify important qualitative differences that characterize supersymmetric leptogenesis with respect to the non-supersymmetric case. The lepton number asymmetries in fermions and scalars do not equilibrate, and are related via a non-vanishing gaugino chemical potential. Due to the presence of new anomalous symmetries, electroweak sphalerons couple to winos and higgsinos, and QCD sphalerons couple to gluinos, thus modifying the corresponding chemical equilibrium conditions. A new constraint on particles chemical potentials corresponding to an exactly conserved $R$-charge, that also involves the number density asymmetry of the heavy sneutrinos, appears. These new ingredients determine the $3\times 4$ matrices that mix up the density asymmetries of the lepton flavours and of the heavy sneutrinos. We explain why in all temperature ranges the particle thermodynamic system is characterized by the same number of independent quantities. Numerical differences with respect to usual treatment remain at the ${\cal O}(1)$ level.Comment: 30 pages, 2 figures. Typos corrected, one reference added. Version published in JCA

Factors affecting the vaccination choices of pregnant women for their children. A systematic review of the literature

In recent years, an increase in vaccine hesitancy has led to a decrease in vaccination coverage in several countries. We conducted a systematic review of studies that assessed knowledge of and attitudes toward pediatric vaccinations, and the vaccination choices and their determinants among pregnant women. A total of 6,277 records were retrieved, and 16 full texts were included in the narrative synthesis. The published literature on the topic shows that, overall, pregnant women believe that vaccines are important for the protection of their children and the community, but various concerns and misunderstandings persist around vaccine safety and efficacy, which reduce the trust of expectant mothers in immunization. Nevertheless, such attitudes and choices vary depending on the vaccine being considered and the corresponding determinants should therefore be studied in the context of each specific vaccination. Further research on this topic is needed, particularly in non-western countries

CP violation in scatterings, three body processes and the Boltzmann equations for leptogenesis

We obtain the Boltzmann equations for leptogenesis including decay and scattering processes with two and three body initial or final states. We present an explicit computation of the CP violating scattering asymmetries. We analyze their possible impact in leptogenesis, and we discuss the validity of their approximate expressions in terms of the decay asymmetry. In scenarios in which the initial heavy neutrino density vanishes, the inclusion of CP asymmetries in scatterings can enforce a cancellation between the lepton asymmetry generated at early times and the asymmetry produced at later times. We argue that a sizeable amount of washout is crucial for spoiling this cancellation, and we show that in the regimes in which the washouts are particularly weak, the inclusion of CP violation in scatterings yields a reduction in the final value of the lepton asymmetry. In the strong washout regimes the inclusion of CP violation in scatterings still leads to a significant enhancement of the lepton asymmetry at high temperatures; however, due to the independence from the early conditions that is characteristic of these regimes, the final value of the lepton asymmetry remains approximately unchanged.Comment: 24 pages, 6 figures. One appendix added. Some numerical results and corresponding figures (mainly fig. 3) corrected. Final version to be published in JHE

Domino: exploring mobile collaborative software adaptation

Social Proximity Applications (SPAs) are a promising new area for ubicomp software that exploits the everyday changes in the proximity of mobile users. While a number of applications facilitate simple file sharing between co–present users, this paper explores opportunities for recommending and sharing software between users. We describe an architecture that allows the recommendation of new system components from systems with similar histories of use. Software components and usage histories are exchanged between mobile users who are in proximity with each other. We apply this architecture in a mobile strategy game in which players adapt and upgrade their game using components from other players, progressing through the game through sharing tools and history. More broadly, we discuss the general application of this technique as well as the security and privacy challenges to such an approach

The unbinding transition of mixed fluid membranes

A phenomenological model for the unbinding transition of multi-component fluid membranes is proposed, where the unbinding transition is described using a theory analogous to Flory-Huggins theory for polymers. The coupling between the lateral phase separation of inclusion molecules and the membrane-substrate distance explains the phase coexistence between two unbound phases as observed in recent experiments by Marx et al. [Phys. Rev. Lett. 88, 138102 (2002)]. Bellow a critical end-point temperature, we find that the unbinding transition becomes first-order for multi-component membranes.Comment: 7 pages, 3 eps figure

R_b and New Physics: A Comprehensive Analysis

We survey the implications for new physics of the discrepancy between the LEP measurement of $R_b$ and its Standard Model prediction. Two broad classes of models are considered: ($i$) those in which new Z\bbar b couplings arise at tree level, through $Z$ or $b$-quark mixing with new particles, and ($ii$) those in which new scalars and fermions alter the Z \bbar b vertex at one loop. We keep our analysis as general as possible in order to systematically determine what kinds of features can produce corrections to $R_b$ of the right sign and magnitude. We are able to identify several successful mechanisms, which include most of those which have been recently been proposed in the literature, as well as some earlier proposals (\eg\ supersymmetric models). By seeing how such models appear as special cases of our general treatment we are able to shed light on the reason for, and the robustness of, their ability to explain $R_b$.Comment: 60 pages, 8 figures, plain tex, uses epsf. Final version to appear in Phys. Rev. D; propgating sign error corrected in eqs. 78, 87, 88, 89, 98, and 107; results unchange

Signals of Unconventional E6_6 Models at e+e−e^+e^- Colliders

Generation dependent discrete symmetries often appear in models derived from superstring theories. In particular, in the framework of E$_6$ models the presence of such symmetries is required in order to allow for the radiative generation of naturally small neutrino masses. Recently it was shown that by imposing suitable generation dependent discrete symmetries, a class of models can be consistently constructed in which the three sets of known fermions in each generation do not have the same assignments with respect to the {\bf 27} representation of E$_6$. In this scenario, the different embedding in the gauge group of the three generations implies in particular that the known charged leptons couple in a non--universal way to the new neutral gauge bosons $(Z_\beta)$ present in these models. We exploit this fact to study the signature of this class of models at present and future $e^+e^-$ colliders. We show that some signals of deviation from lepton universality as well as some other discrepancies with the standard model predictions which have been observed at the TRISTAN collider in the production rate of $\mu$ and $\tau$, can be accounted for if the $Z_\beta$ mass is not much heavier than 300 GeV. We also study the discovery limits for lepton universality violation of this type at LEP-2 and at the 500 GeV $e^+e^-$ Next Linear Collider (NLC). We show that models predicting unconventional assignments for the leptons will give an unmistakable signature, when the $Z_\beta$ mass is as heavy as $\sim 800$ GeV (LEP-2) and $\sim 2$ TeV (NLC).Comment: Plain Tex, 20 pages. 4 PostScript figures (uses `epsf.tex'). Modified file-format. No changes in the tex