Biodegradable and compostable alternatives to conventional plastics

This article is available open access through the publisher’s website at the link below. Copyright @ 2009 The Royal Society.Packaging waste forms a significant part of municipal solid waste and has caused increasing environmental concerns, resulting in a strengthening of various regulations aimed at reducing the amounts generated. Among other materials, a wide range of oil-based polymers is currently used in packaging applications. These are virtually all non-biodegradable, and some are difficult to recycle or reuse due to being complex composites having varying levels of contamination. Recently, significant progress has been made in the development of biodegradable plastics, largely from renewable natural resources, to produce biodegradable materials with similar functionality to that of oil-based polymers. The expansion in these bio-based materials has several potential benefits for greenhouse gas balances and other environmental impacts over whole life cycles and in the use of renewable, rather than finite resources. It is intended that use of biodegradable materials will contribute to sustainability and reduction in the environmental impact associated with disposal of oil-based polymers. The diversity of biodegradable materials and their varying properties makes it difficult to make simple, generic assessments such as biodegradable products are all ‘good’ or petrochemical-based products are all ‘bad’. This paper discusses the potential impacts of biodegradable packaging materials and their waste management, particularly via composting. It presents the key issues that inform judgements of the benefits these materials have in relation to conventional, petrochemical-based counterparts. Specific examples are given from new research on biodegradability in simulated ‘home’ composting systems. It is the view of the authors that biodegradable packaging materials are most suitable for single-use disposable applications where the post-consumer waste can be locally composted.EPSR

Observational Prospects for Afterglows of Short Duration Gamma-ray Bursts

If the efficiency for producing $\gamma$-rays is the same in short duration (\siml 2 s) Gamma-Ray Bursts (GRBs) as in long duration GRBs, then the average kinetic energy of short GRBs must be $\sim 20$ times less than that of long GRBs. Assuming further that the relativistic shocks in short and long duration GRBs have similar parameters, we show that the afterglows of short GRBs will be on average 10--40 times dimmer than those of long GRBs. We find that the afterglow of a typical short GRB will be below the detection limit (\siml 10 \microJy) of searches at radio frequencies. The afterglow would be difficult to observe also in the optical, where we predict R \simg 23 a few hours after the burst. The radio and optical afterglow would be even fainter if short GRBs occur in a low-density medium, as expected in NS-NS and NS-BH merger models. The best prospects for detecting short-GRB afterglows are with early (\siml 1 day) observations in X-rays.Comment: 5 pages, 2 figures, submitted to ApJ lette

Where are all the gravastars? Limits upon the gravastar model from accreting black holes

The gravastar model, which postulates a strongly correlated thin shell of anisotropic matter surrounding a region of anti-de Sitter space, has been proposed as an alternative to black holes. We discuss constraints that present-day observations of well-known black hole candidates place on this model. We focus upon two black hole candidates known to have extraordinarily low luminosities: the supermassive black hole in the Galactic Center, Sagittarius A*, and the stellar-mass black hole, XTE J1118+480. We find that the length scale for modifications of the type discussed in Chapline et al. (2003) must be sub-Planckian.Comment: 11 pages, 4 figure

Anger without Agency: Exploring the Experiences of Stress in Adolescent Girls

Although a great deal of research has measured stressful life events and stress-related symptoms in adolescents, little research has qualitatively examined the experience of stress in teens. The purpose of this study was to utilize thematic analysis to explore how teen girls described their experiences of stress. Thirty-one girls, ages 14–18, were recruited for a study examining stress and stress-related symptoms. As part of this study, they participated in an open-ended, qualitative interview about their personal experiences of stress. Themes included the mind of stress, emotionally shutting out others, and “growing out of it.” The overarching finding was that all teen girls described anger in relation to stress. Most concerning was the predominant theme of a lack of agency in relation to affecting change or management of stress in their lives

Gravitational waves from the Papaloizou-Pringle instability in black hole-torus systems

Black hole (BH)--torus systems are promising candidates for the central engine of gamma-ray bursts (GRBs), and also possible outcomes of the collapse of supermassive stars to supermassive black holes (SMBHs). By three-dimensional general relativistic numerical simulations, we show that an $m=1$ nonaxisymmetric instability grows for a wide range of self-gravitating tori orbiting BHs. The resulting nonaxisymmetric structure persists for a timescale much longer than the dynamical one, becoming a strong emitter of large amplitude, quasiperiodic gravitational waves. Our results indicate that both, the central engine of GRBs and newly formed SMBHs, can be strong gravitational wave sources observable by forthcoming ground-based and spacecraft detectors.Comment: 4 pages, 4 figure, to be published in PR

Onset of Propagation of Planar Cracks in Heterogeneous Media

The dynamics of planar crack fronts in hetergeneous media near the critical load for onset of crack motion are investigated both analytically and by numerical simulations. Elasticity of the solid leads to long range stress transfer along the crack front which is non-monotonic in time due to the elastic waves in the medium. In the quasistatic limit with instantaneous stress transfer, the crack front exhibits dynamic critical phenomenon, with a second order like transition from a pinned to a moving phase as the applied load is increased through a critical value. At criticality, the crack-front is self-affine, with a roughness exponent $\zeta =0.34\pm 0.02$. The dynamic exponent $z$ is found to be equal to $0.74\pm 0.03$ and the correlation length exponent $\nu =1.52\pm 0.02$. These results are in good agreement with those obtained from an epsilon expansion. Sound-travel time delays in the stress transfer do not change the static exponents but the dynamic exponent $z$ becomes exactly one. Real elastic waves, however, lead to overshoots in the stresses above their eventual static value when one part of the crack front moves forward. Simplified models of these stress overshoots are used to show that overshoots are relevant at the depinning transition leading to a decrease in the critical load and an apparent jump in the velocity of the crack front directly to a non-zero value. In finite systems, the velocity also shows hysteretic behaviour as a function of the loading. These results suggest a first order like transition. Possible implications for real tensile cracks are discussed.Comment: 51 pages + 20 figur

Marginal Release Under Local Differential Privacy

Many analysis and machine learning tasks require the availability of marginal statistics on multidimensional datasets while providing strong privacy guarantees for the data subjects. Applications for these statistics range from finding correlations in the data to fitting sophisticated prediction models. In this paper, we provide a set of algorithms for materializing marginal statistics under the strong model of local differential privacy. We prove the first tight theoretical bounds on the accuracy of marginals compiled under each approach, perform empirical evaluation to confirm these bounds, and evaluate them for tasks such as modeling and correlation testing. Our results show that releasing information based on (local) Fourier transformations of the input is preferable to alternatives based directly on (local) marginals

Nickel in Non-ferrous General Engineering Alloys

ALTHOUGH nickel in its wrought forms has important applications as an engineering material, particularly in the chemical and electronic industries, the major usage of the metal, in both ferrous and non-ferrous metallurgy, is as an alloying element. Nickel-base alloys can be broadly divided into the nickel-chromium -base " Superalloys" for high-temperature service , and materials , such as nickel-copper and nickel-chromium- iron alloys, which are used for more general engineering purposes, particularly where resist-ance to corrosion is involved. The technology of the former type of material tends to be rather specialized, since it is concerned very largely with high-temperature properties, and it is not proposed to discuss these high-temperature alloys in this paper but to describe some recent developments in the nickel-base alloys of general engineering interest and in the nickel-containing copper-base and aluminiumbase alloys