A robust seeding technique for the growth of single grain (RE)BCO and (RE)BCO-Ag bulk superconductors

Bulk, single grains of RE-Ba-Cu-O [(RE)BCO] high temperature superconductors have significant potential for a wide range of applications, including trapped field magnets, energy storage flywheels, superconducting mixers and magnetic separators. One of the main challenges in the production of these materials by the so-called top-seeded melt growth (TSMG) technique is the reliable seeding of large, single grains, which are required for high field applications. A chemically aggressive liquid phase comprising of BaCuO2 and CuO is generated during the single grain growth process, which comes into direct contact with the seed crystal either instantaneously or via infiltration through a buffer pellet, if employed in the process. This can cause either partial or complete melting of the seed, leading subsequently to growth failure. Here, the underlying mechanisms of seed crystal melting and the role of seed porosity in the single grain growth process are investigated. We identify seed porosity as a key limitation in the reliable and successful fabrication of large grain (RE)BCO bulk superconductors for the first time, and propose the use of Mg-doped NdBCO generic seeds fabricated via the infiltration growth (IG) technique to reduce the effects of seed porosity on the melt growth process. Finally, we demonstrate that the use of such seeds leads to better resistance to melting during the single grain growth process, and therefore to a more reliable fabrication technique

The processing and properties of bulk (RE)BCO high temperature superconductors: Current status and future perspectives

Funder: Engineering and Physical Sciences Research Council; doi: http://dx.doi.org/10.13039/501100000266Funder: King Abdulaziz City for Science and Technology; doi: http://dx.doi.org/10.13039/501100004919Bulk (RE)‒Ba‒Cu‒O [(RE)BCO] cuprate high temperature superconductors (HTS) have been developed steadily towards a wide range of sustainable engineering and technological applications since their discovery in 1986 based primarily on their unique potential to trap very large magnetic fields (> 5 T) at temperatures that are accessible potentially by thermo-electric cooling techniques. This paper reviews the current state of the art of the processing of large, single grain (RE)BCO bulk superconductors required to trap fields of this magnitude, and specifically via two advanced fabrication approaches; the traditional top-seeded melt growth (TSMG) process and the more recently developed top-seeded infiltration growth (TSIG) technique. The focus of the review is on optimising the critical processing parameters to achieve high-quality, high performance single grain (RE)BCO bulk superconductors specifically for high-field applications. The review also summarises recent advances in processing, such as the integration of the so-called buffer technique into the TSMG and TSIG processing methodologies to achieve improved reliability in single grain growth with a success rate exceeding 90%, the development of a Mg-doped NdBCO generic seed crystal for the successful growth of all rare-earth and light-rare earth based bulk superconductors [(RE)BCO and (LRE)BCO] and the introduction of nano-size stable, non-superconducting phase(s) to the bulk microstructure to improve the intrinsic flux pinning strength of the material, and hence trapped magnetic field. Details of the 2-step buffer-aided TSIG technique developed recently that yields dense, near-net shaped, high performance (RE)BCO bulk superconductors with improved superconducting and mechanical properties are also presented. Suitable sample-seed configurations for effective multi-seeding are discussed, which enables the production of high aspect ratio, bar-shaped (RE)BCO quasi-single grains that exhibit improved levitation forces required in Maglev-based applications, for example, are discussed. The electrical, mechanical, microstructural and magnetic properties (including those achieved from a pulsed-field magnetisation approach) of the different (RE)BCO systems are presented and the relevant correlation in properties and performance highlighted, accordingly. Finally, a brief summary of existing applications and prospects for near-future exploitation of these remarkable, technologically important materials, and particularly in the medical and pharma-industries, is provided.KACS

A Reliable Method for Recycling (RE)-Ba-Cu-O (RE: Sm, Gd, Y) Bulk Superconductors

Single grain (RE)-Ba-Cu-O (RE: Sm, Gd, Y) high temperature superconductors are able to generate high magnetic fields. However, the relatively high cost of the raw materials and the low yield of the manufacturing process have impeded the development of practical applications of these materials to date. This article describes a simple, reliable and economical method of recycling failed bulk (RE)-Ba-Cu-O (RE: Sm, Gd, Y) samples. Sixty-four failed bulk samples, with diameters up to 31 mm, were recycled with a yield of 90%. The key innovation in this recycling process involves reintroducing the liquid phase into the melt process, which is normally lost during the primary peritectic processing of these materials. This enables the direct re-growth of failed samples from solid form without the need for re-grinding into powder. We also demonstrate that the superconducting performance and microstructure of the recycled samples is similar to that of the primary grown samples.We acknowledge the Engineering and Physical Sciences Research Council (EPSRC grant ref.EP/K02910X/1) for financial support.This is the final version. It first appeared at http://dx.doi.org/10.1111/jace.1368

Design Optimization of a Hybrid Trapped Field Magnet Lens (HTFML)

The concept of a hybrid trapped field magnet lens (HTFML) was recently proposed by the authors, which consists of a trapped field magnet (TFM) cylinder exploiting the “vortex pinning effect,” combined with a superconducting bulk magnetic lens exploiting the “diamagnetic shielding effect.” This HTFML can generate, within its bore, a magnetic field higher than the applied magnetic field, even after external field decreases to zero. In this paper, a design optimization of the inner GdBaCuO magnetic lens within the GdBaCuO TFM cylinder was carried out using numerical simulations based on the finite element method, in order to maximize the concentrated magnetic field. The HTFML with an optimized shape and size achieved a concentrated magnetic field of Bc = 5.6 and 12.8 T at the center of the lens for applied magnetic fields of Bapp = 3 and 10 T, respectively. A maximum tensile stress of +135 MPa exists in the outer GdBaCuO TFM cylinder during the magnetizing process for Bapp = 10 T, which exceeds the fracture strength of the bulk. This result suggests that mechanical reinforcement is necessary to avoid mechanical fracture under such high magnetic field conditions

Multiple seeding for the growth of bulk GdBCO-Ag superconductors with single grain behaviour

Rare earth–barium–copper oxide bulk superconductors fabricated in large or complicated geometries are required for a variety of engineering applications. Initiating crystal growth from multiple seeds reduces the time taken to melt-process individual samples and can reduce the problem of poor crystal texture away from the seed. Grain boundaries between regions of independent crystal growth can reduce significantly the flow of current due to crystallographic misalignment and the agglomeration of impurity phases. Enhanced supercurrent flow at such boundaries has been achieved by minimising the depth of the boundary between $\small \textit{A}$ growth sectors generated during the melt growth process by reducing second phase agglomerations and by a new technique for initiating crystal growth that minimises the misalignment between different growth regions. The trapped magnetic fields measured for the resulting samples exhibit a single trapped field peak indicating they are equivalent to conventional single grains.The authors acknowledge support from the Engineering and Physical Sciences Research Council EP/K02910X/1.This is the final version of the article. It first appeared from the Institute of Physics via 10.1088/0953-2048/30/1/01500

Trapped magnetic field distribution above two magnetized bulk superconductors close to each other

Bulk large-grain superconductors can be used as high-field permanent magnets. Although the properties of such individual trapped field magnets are well documented, much less is known concerning their behaviour when two are brought together. In this work, the interaction between two cylindrical bulk YBa2Cu3O7 (YBCO) superconductors is described. Two sets of experiments were carried out. The first involved the simultaneous magnetization of two bulk superconductors placed a short distance apart. Here, the applied magnetic field was aligned parallel to the c-axis of one bulk, while the other was oriented with its c-axis offset . For a centre-to-centre distance equal to twice the sample height, the presence of the second sample is found not to alter the current distribution inside the first. Consequently, the contribution of both samples simply sums, thus increasing the magnetic flux density between them. In the second set of experiments, the translational approach of the superconductors with parallel c-axes was investigated. The following configurations were considered: (i) face to face approach (with anti-parallel trapped field orientation) and (ii) sideways approach (with parallel trapped field orientation). An irreversible decrease of the trapped field was measured on separation . Repeated approach cycles showed that the irreversible loss of trapped field is largest for the first approach.Henry Royce Institute (Equipment grant ref. EP/P024947/1) We thank the University of Liege for equipment and travel grants. Michel Houbart is recipient of a FRS-FNRS Research Fellow gran

Processing and Properties of Bar-Shaped Single-Seeded and Multi-Seeded YBCO Bulk Superconductors by a Top-Seeded Melt Growth Technique

© 2016 The Author(s)The fabrication of (RE)-Ba-Cu-O bulk superconductors, where RE is a rare-earth element such as Y, Gd and Sm, is both time consuming and expensive due to the complexity of the melt process and the slow growth rate of large, single grains. In this study, different approaches to the fabrication of bar-shaped, bulk YBCO superconductors are investigated and compared using single- and multiple-seeding techniques via top-seeded melt growth (TSMG). Both the microstructural and superconducting properties of the bulk samples are investigated, including trapped field, critical current density, critical temperature and levitation force. The results of this study indicate that, in general, the superconducting properties of YBCO fabricated by a single-seeded process are significantly better than those of samples fabricated by a four-seeded process for non-bridge seeds. The differences between the samples are less pronounced in the levitation force measurements, however. In this paper, we attempt to explain the reasons for the similarities and differences observed between bulk samples fabricated by the different single- and multi-seeded processes.This work was supported by the King Abdulaziz City for Science and Technology (KACST)

Pulsed Field Magnetization of Single-Grain Bulk YBCO Processed from Graded Precursor Powders

Large, single-grain bulk high-temperature superconducting materials can trap high magnetic fields in comparison with conventional permanent magnets, making them ideal candidates to develop more compact and efficient devices, such as actuators, magnetic levitation systems, flywheel energy storage systems and electric machines. However, macrosegregation of Y-211 inclusions in melt-processed Y-Ba-Cu-O (YBCO) limits the macroscopic critical current density of such bulk superconductors, and hence, the potential trapped field. A new fabrication technique using graded precursor powders has recently been developed by our research group, which results in a more uniform distribution of Y-211 particles, in order to further improve the superconducting properties and trapped field capability of such materials. Large, single-grain bulk high-temperature superconducting materials can trap high magnetic fields in comparison with conventional permanent magnets, making them ideal candidates to develop more compact and efficient devices, such as actuators, magnetic levitation systems, flywheel energy storage systems and electric machines. However, macrosegregation of Y-211 inclusions in melt-processed Y-Ba-Cu-O (YBCO) limits the macroscopic critical current density of such bulk superconductors, and hence, the potential trapped field. A new fabrication technique using graded precursor powders has recently been developed by our research group, which results in a more uniform distribution of Y-211 particles, in order to further improve the superconducting properties and trapped field capability of such materials.M. D. Ainslie would like to acknowledge financial support from a Royal Academy of Engineering Research Fellowship. This work was also supported by a Royal Society International Exchanges Scheme Grant, IE131084. J. Zou would like to acknowledge financial support from Churchill College, the China Scholarship Council and the Cambridge Commonwealth, European and International Trust.This is the author accepted manuscript. The final version is available from IEEE via http://dx.doi.org/10.1109/TASC.2015.250916

Factors Affecting the Growth of Multiseeded Superconducting Single Grains

© 2016 American Chemical Society.Single grain, rare earth-barium-copper oxide [(RE)BCO] bulk superconductors, fabricated either individually or assembled in large or complicated geometries, have a significant potential for a variety of potential engineering applications. Unfortunately, (RE)BCO single grains have intrinsically very low growth rates, which limits the sample size that may be achieved in a practical, top seeded melt growth process. As a result, a melt process based on the use of two or more seeds (so-called multiseeding) to control the nucleation and subsequent growth of bulk (RE)BCO superconductors has been developed to fabricate larger samples and to reduce the time taken for the melt process. However, the formation of regions that contain non-superconducting phases at grain boundaries has emerged as an unavoidable consequence of this process. This leads to the multiseeded sample behaving as if it is composed of multiple, singly seeded regions. In this work we have examined the factors that lead to the accumulation of non-superconducting phases at grain boundaries in multiseeded (RE)BCO bulk samples. We have studied the microstructure and superconducting properties of a number of samples fabricated by the multiseeded process to explore how the severity of this problem can be reduced significantly, if not eliminated completely. We conclude that, by employing the techniques described, multiseeding is a practical approach to the processing of large high performance superconducting bulk samples for engineering applications.Engineering and Physical Sciences Research Council (Grant ID: EP/K02910X/1

Composite stacks for reliable > 17 T trapped fields in bulk superconductor magnets

Trapped fields of over 20 T are, in principle, achievable in bulk, single-grain high temperature cuprate superconductors. The principle barriers to realizing such performance are, firstly, the large tensile stresses that develop during the magnetization of such trapped-field magnets as a result of the Lorentz force, which lead to brittle fracture of these ceramic-like materials at high fields and, secondly, catastrophic thermal instabilities as a result of flux movement during magnetization. Moreover, for a batch of samples nominally fabricated identically, the statistical nature of the failure mechanism means the best performance (i.e. trapped fields of over 17 T) cannot be attained reliably. The magnetization process, particularly to higher fields, also often damages the samples such that they cannot repeatedly trap high fields following subsequent magnetization. In this study, we report the sequential trapping of magnetic fields of ~ 17 T, achieving 16.8 T at 26 K initially and 17.6 T at 22.5 K subsequently, in a stack of two Ag-doped GdBa2Cu3O7-{\delta} bulk superconductor composites of diameter 24 mm reinforced with (1) stainless-steel laminations, and (2) shrink-fit stainless steel rings. A trapped field of 17.6 T is, in fact, comparable with the highest trapped fields reported to date for bulk superconducting magnets of any mechanical and chemical composition, and this was achieved using the first composite stack to be fabricated by this technique