Cyclo­hexane-1,2-diammonium bis­(pyridine-2-carboxyl­ate)

In the dication of the title salt, C6H16N2 2+·2C6H4NO2 −, the two ammonium groups are in the equatorial positions of the chair-shaped cyclo­hexyl ring. In the crystal, the cations and anions are linked by N—H⋯O and N—H⋯N hydrogen bonds, forming a layer network parallel to the ac plane. Weak π–π inter­actions between adjacent pyridine rings with a centroid–centroid distance of 3.589 (2) Å are also present

Bis(2,2′-bipyridine-κ2 N,N′)dichlorido­platinum(IV) dichloride monohydrate

In the title complex, [PtCl2(C10H8N2)2]Cl2·H2O, the Pt4+ ion is six-coordinated in a distorted octa­hedral environment by four N atoms from the two 2,2′-bipyridine ligands and two Cl atoms. As a result of the different trans influences of the N and Cl atoms, the Pt—N bonds trans to the Cl atom are slightly longer than those trans to the N atom. The compound displays inter­molecular hydrogen bonding between the water mol­ecule and the Cl anions. There are inter­molecular π–π inter­actions between adjacent pyridine rings, with a centroid–centroid distance of 3.962 Å

catena-Poly[hemi(hexane-1,6-diammonium) [[aqua­dibromido­manganese(II)]-μ-pyridine-2-carboxyl­ato]]

The asymmetric unit of the title compound, {(C6H18N2)0.5[MnBr2(C6H4NO2)(H2O)]}n, contains the repeat unit of the complex anion and one-half of a hexane-1,6-diammonium cation that is located on a twofold rotation axis. In the anionic polymer, the Mn2+ ions are bridged by the pyridine­carboxyl­ate (pic) anion ligand, forming a chain structure along the c axis. The Mn2+ ion is six-coordinated in a distorted octa­hedral environment by one N atom of the pyridine ring, two O atoms of the two carboxyl­ate groups, one O atom of the water mol­ecule and two Br atoms. The compound displays inter­molecular N—H⋯O, N—H⋯Br, O—H⋯Br and O—H⋯O hydrogen bonding. There may also be inter­molecular π–π inter­actions between adjacent pyridine rings, with a centroid–centroid distance of 3.992 (4) Å

Tetra­chlorido(1,10-phenanthroline-κ2 N,N′)platinum(IV) monohydrate

In the title complex, [PtCl4(C12H8N2)]·H2O, the Pt4+ ion is six-coordinated in a distorted octa­hedral environment by two N atoms of a 1,10-phenanthroline ligand and by four Cl atoms. As a result of the different trans effects of the N and Cl atoms, the Pt—Cl bonds trans to the N atom are slightly shorter than those trans to the Cl atom. The compound displays inter­molecular π–π inter­actions between the six-membered rings, with a centroid–centroid distance of 3.834 Å. There are also weak intra­molecular C—H⋯Cl hydrogen bonds. According to the IR spectrum, solvent water was present in the crystal, but owing to the high thermal motion of the uncoordinated O atom, the H atoms could not be detected

Tetra­chlorido(1,10-phenanthroline-κ2 N,N′)platinum(IV) acetonitrile hemisolvate

The asymmetric unit of the title compound, [PtCl4(C12H8N2)]·0.5CH3CN, contains two crystallographically independent PtIV complexes with very similar geometry and one solvent mol­ecule. In the complexes, each PtIV ion is six-coordinated in a distorted octa­hedral environment by two N atoms of the 1,10-phenanthroline ligand and four Cl atoms. Because of the different trans effects of the N and Cl atoms, the Pt—Cl bonds trans to the N atom are slightly shorter than those trans to the Cl atom. The compound displays numerous inter­molecular π–π inter­actions between six-membered rings, with a shortest centroid-to-centroid distance of 3.654 Å. There are also weak intra- and inter­molecular C—H⋯Cl hydrogen bonds